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TechniquesGives useful information on IR and Fourier transform IR (FT IR) spectroscopy ATR (attenuated total reflectance )- IR spectroscopy Measurement.

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Presentation on theme: "TechniquesGives useful information on IR and Fourier transform IR (FT IR) spectroscopy ATR (attenuated total reflectance )- IR spectroscopy Measurement."— Presentation transcript:

1 TechniquesGives useful information on IR and Fourier transform IR (FT IR) spectroscopy ATR (attenuated total reflectance )- IR spectroscopy Measurement of carbonyl absorption to determine photooxidation; determination of induction period, assesment of the effectiveness and buildup of hydroperoxides, chmeical composition of degradation products Diseappearance of bands at 3400 and 1700 Cm -1, new bands at 2100 and 1640 cm -1 Translation into Chemistry: -NH-CO- bonds are converted to –NH-CO-NH and –N=C=N-

2 Carbonyl Index-Impact strength Carbonyl group can be readily monitored by IR Spec. (1710-35 cm -1 )

3 UV spectroscopy Weathering effects on plastics in the form of chemical changes, discoloration, and darkening.

4 ESCA (electron spectroscopy for chemical analysis)

5 ESR (electron spin resonance spectroscopy) Formation and rate growth of free radicals NMR (nuclear magnetic resonance) Measurement of degradation induced changes in functional groups

6 Gas Chromatography-mass spectrometry(GC-MS) Separation and identification of volatile degradation products in trace amount

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8 DTA (differential thermal analysis) and DSC (differential scanning calorimetry) Measurement of oxidation induction times to study a stabilizer’s effectiveness and its diffusion within the solid

9 Thermal behavior of polymers give useful information for the mechanism of Polymer degradation

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