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Electromagnetic waves. Electronic transitions Vibrational fine structure.

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Presentation on theme: "Electromagnetic waves. Electronic transitions Vibrational fine structure."— Presentation transcript:

1 Electromagnetic waves

2 Electronic transitions

3 Vibrational fine structure

4 Stretching and bending vibrational modes for a CH 2 group http://en.wikipedia.org/wiki/Infrared_spectroscopy

5 Normal vibrational modes http://upload.wikimedia.org/wikipedia/commons/9/9b/1D_normal_modes_%28280_kB%29.gif H2OH2O CO 2

6 Part of the rotational-vibrational spectrum of HCl Gas, showing the presence of P- and R- branches. Frequency is on the x-axis, and transmittance on the y-axis.HCl

7 Kinetic techniques

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9 Determination of Concentration by Spectroscopic Methods Beer’s Law I o = Intensity of incident light I = Intensity of transmitted light  = molar extinction coefficient l = path length of cell c = concentration of sample

10 Quantitative aspect

11 When  X =  Y and [X] + [Y] is constant, Isosbestic points occur

12 Morse energy curve for a diatomic molecule

13 Morse curve

14 Anharmonic Oscillator Model for a Diatomic Molecule

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