1. Copyright © 2008 Pearson Education, Inc., publishing as Pearson Benjamin Cummings PowerPoint ® Lecture Presentations for Biology Eighth Edition Neil Campbell and Jane Reece Lectures by Chris Romero, updated by Erin Barley with contributions from Joan Sharp Chapter 3 Water and the Fitness of the Environment

2. Overview: The Molecule That Supports All of Life Water is biological medium on Earth All organisms require water more than any other substance Most cells surrounded by water, cells themselves ~70–95% water Abundance of water is main reason Earth is habitable Water molecule is polar: opposite ends have opposite charges Polarity allows water molecules to form hydrogen bonds w/ each other 2

3. 4 Emergent Properties of Water Contribute to Earth’s Fitness for Life 4 properties of water allow life: – Cohesive/Adhesive behavior – Ability to moderate temperature (high Specific Heat) – Expansion upon freezing (solid less dense than liquid) – Versatility as a Solvent HINT: Life “CASHES” in on the properties of water 3

4. Cohesion and Adhesion Cohesion: collectively, hydrogen bonds hold water molecules together Adhesion: attraction between different substances – EXAMPLE: between water and plant cell walls Cohesion and adhesion help transport of water against gravity in plants – Transpiration-Cohesion Theory 4

5. Surface tension: measure of difficulty to break surface of a liquid Surface tension is related to cohesion 5

6. Moderation of Temperature Water absorbs heat from warmer air, releases stored heat to cooler air Water can absorb or release large amount of heat with only a slight change in its own temperature San Diego 72° Pacific Ocean 70s (°F ) 80s 90s 100s Santa Barbara 73° Los Angeles (Airport) 75° Burbank 90° San Bernardino 100° Riverside 96° Santa Ana 84° Palm Springs 106° 6

7. Water’s High Specific Heat Specific heat: amount of heat that must be absorbed or lost for 1 g of substance to change temperature by 1ºC Specific heat of water is 1 cal/g/ºC Water resists changing its temperature b/c of its high specific heat Water’s high specific heat can be traced to hydrogen bonding – Hydrogen bonds must absorb heat to break, and they release heat when they form The high specific heat of water minimizes temperature fluctuations to within limits that permit life 7

8. Evaporative Cooling Evaporation: transformation from liquid to gas Heat of vaporization: heat a liquid must absorb for 1 g to be converted to gas As a liquid evaporates, its remaining surface cools, a process called evaporative cooling Evaporative cooling of water helps stabilize temperatures in organisms and bodies of water 8

9. Insulation of Bodies of Water by Floating Ice Ice floats b/c hydrogen bonds in ice are more “ordered,” making it less dense Water at 0 o C (least dense) becomes locked in crystalline lattice w/ each molecule bonded to maximum of four partners Water reaches greatest density at 4°C If ice sank, all bodies of water would eventually freeze solid, making life impossible on Earth 9

10. Comprehension Check In a lake, mineral nutrients accumulate at the bottom while dissolved oxygen is greater near the surface. These nutrients can be mixed during water turnover that occurs with annual temperature changes. Which one of the following properties of water explains this turnover? A. Individual water molecules move less vigorously as water cools. B. Hydrogen bonds among water molecules form a crystal lattice at 0°C. C. The density of water is greatest at 4°C. D. Water changes from liquid to solid at 0°C. E. The distance between water molecules is greater in ice than in liquid form. 10

11. Comprehension Check Water has an unusually high specific heat. This is directly related to which one of the following? A. At its boiling point, water changes from liquid to vapor. B. More heat is required to raise the temperature of water. C. Ice floats in liquid water. D. Salt water freezes at a lower temperature than pure water. E. Floating ice can insulate bodies of water. 11

12. Solvent of Life Solution: liquid that is a homogeneous mixture of substances Solvent: dissolving agent of a solution Solute: substance that is dissolved Aqueous solution: water is the solvent Water is versatile solvent due to its polarity, which allows it to form hydrogen bonds easily When an ionic compound is dissolved in water, each ion is surrounded by a sphere of water molecules called a hydration shell 12

13. Water can also dissolve compounds made of nonionic polar molecules Even large polar molecules such as proteins can dissolve in water if they have ionic and polar regions (a) Lysozyme molecule in a nonaqueous environment (b) Lysozyme molecule (purple) in an aqueous environment (c) Ionic and polar regions on the protein’s surface attract water molecules. 13

14. Comprehension Check Which of the following explains what is happening when sodium chloride dissolves in water? A. More hydrogen bonds are forming between water molecules. B. Sodium and chloride atoms are separating from one another. C. Hydration shells are forming around the sodium and chloride ions. D. Covalent bonds are breaking and re-forming. E. Nonpolar substances are mixing with polar substances. 14

15. Hydrophilic and Hydrophobic Substances Hydrophilic: substance with affinity for water Hydrophobic: substance with no affinity for water – Oil molecules are hydrophobic b/c they have relatively nonpolar bonds Colloid: stable suspension of fine particles in another substance (usually water) – Milk – Fog 15

16. Solute Concentration in Aqueous Solutions Most biochemical reactions occur in water Chemical reactions depend on collisions of molecules and therefore on concentration of solutes in an aqueous solution Molecular mass: sum of masses of all atoms in molecule Numbers of molecules are usually measured in moles, where 1 mole (mol) = 6.02 x 10 23 molecules Avogadro’s number and the unit dalton were defined such that 6.02 x 10 23 daltons = 1 g Molarity (M): number of moles of solute per liter of solution 16

17. Comprehension Check Predict how life on earth would be different if water were less polar. Which one of the following would result if organisms lived in and consisted of a less polar medium than water? A. Heavier insects than water striders would be able to walk on the surface of a pond. B. Increased cohesion would contribute to increased upward water transport in plants. C. The water temperature of ponds and pools would increase more slowly when in sunlight. D. Sweating would be a less effective means of keeping cool. E. More salts would go into the solution in blood and body fluids. 17

18. Acidic and Basic Conditions Affect Living Organisms A hydrogen atom in a hydrogen bond between two water molecules can shift from one to the other: – The hydrogen atom leaves its electron behind and is transferred as a proton, or hydrogen ion (H + ) – The molecule with the extra proton is now a hydronium ion (H 3 O + ), though often represented as H + – The molecule that lost the proton is now a hydroxide ion (OH – ) 18

19. Effects of Changes in pH Concentrations of H + and OH – are equal in pure water Adding certain solutes, acids and bases, modifies concentrations of H + and OH – Biologists use pH scale to describe whether a solution is acidic or basic Acid: increases H + concentration of a solution Base: reduces H + concentration of a solution 19

20. The pH Scale In any aqueous solution at 25°C the product of H + and OH – is constant and can be written as: [H + ][OH – ] = 10 –14 The pH (potential hydrogen) of a solution is defined by the negative logarithm of H + concentration, written as: pH = –log [H + ] For a neutral aqueous solution: [H + ] is 10 –7 = –(–7) = 7 Acidic solutions have pH values less than 7 Basic solutions have pH values greater than 7 Most biological fluids have pH values in the range of 6 to 8 20

21. Comprehension Check In humans, blood pH is around 7.4, and a decrease in blood pH to 6.4 would be fatal. A drop by 1 pH unit represents which of these? A. 1/10 as many H + ions in the solution B. 1/7 as many H + ions in the solution C. 1/2 as many H + ions in the solution D. twice as many H + ions in the solution E. ten times as many H + ions in the solution 21

22. Buffers Internal pH of most living cells must remain close to pH 7 Buffers: substances that minimize changes in concentrations of H + and OH – in solution Most buffers consist of an acid-base pair that reversibly combines with H + – Carbonic acid/Bicarbonate System: http://www.mhhe.com/physsci/chemistry/essentialchemistry/flash/buffer12.swf 22

23. Threats to Water Quality on Earth Acid precipitation: rain, snow, or fog with pH lower than 5.6 – caused mainly by mixing of pollutants with water in air, can fall some distance from source of pollutants – can damage life in lakes and streams – effects on soil chemistry are contributing to the decline of some forests Human activities such as burning fossil fuels threaten water quality CO 2 is released by fossil fuel combustion and contributes to: – warming of earth called the “global warming” – acidification of the oceans; this leads to a decrease in the ability of corals to form calcified reefs 23

24. Comprehension Check Scientists are concerned about increased concentrations of atmospheric carbon dioxide due to increased fossil fuel combustion and deforestation. In addition to major effects on global temperatures, increased levels of CO 2 can threaten aquatic organisms in which way? A. forming more carbonic acid in a solution that raises the pH of seawater B. forming more carbonic acid that decreases the concentration of carbonate in seawater C. increasing photosynthesis rates in aquatic plants and algae D. decreasing the oxygen available for cellular respiration in aquatic organisms E. increasing the levels of harmful sulfur oxides and nitrous oxides 24