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Lecture 20 Thursday 3/20/08 Multiple Reactions with Heat Effects.

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Presentation on theme: "Lecture 20 Thursday 3/20/08 Multiple Reactions with Heat Effects."— Presentation transcript:

1 Lecture 20 Thursday 3/20/08 Multiple Reactions with Heat Effects

2 User Friendly Equations Relate T and X or F i

3 Heat Exchange Elementary gas phase reaction carried out in a PBR The feed consists of both inerts I and Species A with the ratio of inerts to the species A being 2 to 1. (a)Adiabatic. Plot X, X e, T and the rate of disappearance as a function of V up to V = 40 dm 3. (b)Constant T a. Plot X, X e, T, T a and Rate of disappearance of A when there is a heat loss to the coolant and the coolant temperature is constant at 300 K for V = 40 dm 3. How do these curves differ from the adiabatic case? (c)Variable T a Co-Current. Plot X, X e, T, T a and Rate of disappearance of A when there is a heat loss to the coolant and the coolant temperature varies along the length of the reactor for V = 40 dm 3. The coolant enters at 300 K. How do these curves differ from those in the adiabatic case and part (a) and (b)? (d)Variable T a Counter Current. Plot X, X e, T, T a and Rate of disappearance of A when there is a heat loss to the coolant and the coolant temperature varies along the length of the reactor for V = 20 dm 3. The coolant enters at 300 K. How do these curves differ from those in the adiabatic case and part (a) and (b)?

4 Mole Balance(1) Rate Law(2) (3) (4)

5 Stoichiometry(5) (6) Parameters(7) – (15)

6 Energy Balance Adiabatic and  C P = 0 (16A) Additional Parameters (17A) & (17B) Heat Exchange (16B)

7 A. Constant T a (17B) T a = 300 Additional Parameters (18B – (20B): T a,, Ua, B. Variable T a Co-Current (17C) C. Variable T a Counter Current (18C) Guess T a at V = 0 to match T a = T ao at exit, i.e., V = V f

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13 User Friendly Equations Relate T and X or F i

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22 Heat Exchange Elementary liquid phase reaction carried out in a PFR The feed consists of both inerts I and Species A with the ratio of inerts to the species A being 2 to 1.

23 Multiple reactions with heat effects Multiple Rxns Mole balances – every species (no conversion!) Rates – rate laws net/relative rates Stoichiometry – Heat effects –

24 Rate is given for 2C, but ΔH R is given for 2A! Make sure it is in respect to A; A needs a coefficient of 1!!!!!!! 1) Mole balance:

25 2) Rate laws: 3) Stoich: 4) Heat effects: Parameters:


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