1. HCl, f 2 triplet state: Morse pot. 240108 Agust,heima,...HCl-Triplet states.xls Agust,heima,...HCl-Triplet states.pxp Agust,www,...HCl-Triplet states.ppt and Agust,heima,...HCl-Potentials-240108ak.pxp

2. X(HCl) f( 3  2 ) E( 1  ) C( 1  ) F( 1   ) hv for f(v=0) <-<-X(v´=0) resonance excitation V( 1  ) In Agust,heima,...HCl-Potentials-240108ak.pxp:

3. f( 3  2 ) E( 1  ) C( 1  ) F( 1   ) hv for f(v=0) <-<-X(v´=0) resonance excitation V( 1  ) In Agust,heima,...HCl-Potentials-240108ak.pxp: Close up figure:

4. Morse potential for : f( 3  2 ) U f (r A ) = 80725.35 + 41188(1-exp(-1.543419421(r A -1.254323846))) 2 /cm-1 r A in Angström Notice tha B´> B´´ hence r´< r´´ i.e. Be´= 10.94 cm-1 (see above) Be´´= 10.59341 cm-1 (NIST) -hence the spectrum (see Q line) is degraded to blue (see next figure): This is opposide of what is found for the singlet states where: B´ r´´ and spectra are degraded to red.

5. hv(LASER)

6. HCl, f2 statecm-1ref: nju0(v=0)82014.6GreenGreen, page 343 we2599Green, page 344 wexe41Green, page 345 De41188Green, page 346 B010.915Green, page 347 B110.87Green, page 348 B210.4Green, page 349 h6.6262E-27erg s c29979200000.0000cm s-1 NA6.0221E+23mol-1 m0.9796g mol-1 Be110.9380cm-1 Be211.1150cm-1 re11.254323846A T080725.35cm-1 beta1.543419421A-1 From: Agust,heima,...HCl-Triplet states.xls:

7. Coefficient values ± one standard deviation a = 11.115 ± 0.21 b = -0.2575 ± 0.123 Bv V+1/2 = Be1 B e evaluations from Greens data:

8. Coefficient values ± one standard deviation a = 10.938 ± inf b = -0.045 ± inf Bv V+1/2 = Be1