1. CH3Br, 231009 C atomic line assignments Agust, heima,....Sep09/CH3Br 16500_20005-231009vhw.pxp Agust, www,....Sept09/PPT-231009ak.ppt

2. hv(Laser) Agust, heima,....Sep09/CH3Br 16500_20005-231009vhw.pxp:

3. C atomic lines: 1hv(Laser)2hv 19255.8127677023.25 19287.717577150.87

4. Configuration Term J Level (cm -1 ) 2s22p2 2s22p2 3 P 0 0 1 16.40 2 43.40 2s22p2 2s22p2 1 D 2 10 192.63 2s22p2 2s22p2 1 S 0 21 648.01 Configuration Ter m J Level (cm -1 ) 2s 2 2p( 2 P°)6p 1 D 2 87 218.26 2s 2 2p( 2 P°)6p 1 S 0 87 341.04 2s 2 2p( 2 P°)6d 1 D° 2 87 633.75 2s 2 2p( 2 P°)6d 3 F° 2 87 708.21 3 87 713.38 4 87 760.61 http://physics.nist.gov/cgi-bin/ASD/energy1.plhttp://physics.nist.gov/cgi-bin/ASD/energy1.pl: :::::: :::::: i.e. 2s 2 2p 2 ( 1 D 2 ) ->-> 2s 2 2p6p( 1 D 2 ): 77025.63 2s 2 2p 2 ( 1 D 2 ) ->-> 2s 2 2p6p( 1 S 0 ): 77148.41 ll LL SS JJ 0000 0-20

5. 77023.25 cm -1 38511.625 CH 3 Br 10k 40k 70k 72301.6 CH 3 Br* C*( 1 D 2 )+H 2 +HBr 0 1 2 C**( 1 D 2 )+H 2 +HBr J’’ 149324.85 130k 150k C + +H 2 +HBr+e - 152926.9 Thus for example:

6. i.d. Data indicates that C* + H 2 + HBr is formed!!!!!!