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Ar Cl Ar Cl... Ar Cl Ar + - Cl Ar Stilben e(1)

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Presentation on theme: "Ar Cl Ar Cl... Ar Cl Ar + - Cl Ar Stilben e(1)"— Presentation transcript:

1

2 Ar Cl

3 Ar Cl...

4 Ar

5 Cl Ar + -

6 Cl Ar

7 Stilben e(1)

8 Stilbene(2)

9 = HCl Water / H 2 O = i.e.: H 3 O +..... Cl - (aq) HCl + H 2 O(l)

10 H 3 O +..... Cl - (aq) HCl + H 2 O(l) Energy +

11 = HCl(g) =  H + Cl -  (g) Energy r(HCl) HCl H + Cl  H + Cl -  H + + Cl -

12 HCl(g)  H + Cl -  (g) Energy + H 3 O +... Cl - (aq) r(HCl) HCl  H + Cl -  H + + Cl - H 3 O +... Cl - (nxH 2 O) + n x H 2 O

13 HCl(g)  H + Cl -  (g) Energy + H 3 O +... Cl - (aq) r(HCl) HCl  H + Cl -  H 3 O +... Cl - (nxH 2 O)  H + Cl -    + H 2 O ::::::::::  H + Cl -      H + Cl -    

14 út HX HX/H 2 O Spíttari Turbo Pumpa TOF rör safnlinsa MCP skynjari sveiflusjá tölva Gas Laser Lit- Laser SHG Pellin Broca prisma Stjórn- eining

15 LASER- tæki jónunarklefar TOF rör

16 Laser excitation: 86616.5 cm -1

17 Mass spectra vs. Laser excitation Laser cm -1 Ion yield

18 Fig. 3 Experimental and calculated REMPI-TOF spectra,

19 E 86616 cm -1 0 (HF)2(HF)2 (HF)2(HF)2 * * 1 2 1 2 * * K = 0K = 1  = 0  * = 0 (n  ((n+1)  p  ( 1, 2 ): (0,0) ( 1, 2 ): (0,0)? ** J J* 36 cm -1 Electronic-, vibrational- and rotational- resonance transitions in the (2+1) REMPI, 86618 cm -1 system.

20 Ab initio/ DFT Orku- lágmörkun H H FF

21 1. Laser ljósefnafræði og litrófsgreining: : Victor Huasheng Wang Gísli Hólmar Jóhannesson, Áshildur Logadóttir Benedikt G. Waage Jón Matthíasson Kristján Matthíasson Ómar Freyr Sigurbjörnsson Oddur Ingólfsson Haraldur Þórðarson Hérlendir samstarfsaðilar * *

22 2. Lögun stilben- og dioxan-afleiða: Jón K.F. Geirsson, Christopher Evans Sigríður Jónsdóttir Ásgeir Konráðsson Benedikt I. Ásgeirsson samstarfsaðilar:

23 3. Lögun Si haldandi efna (NMR o.fl.): Dr. Ingvar Árnason, Dr. Sigríður Jónsdóttir Pálmar I. Guðnason Hérlendir samstarfsaðilar:

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