Presentation on theme: "Separation processes Dr"— Presentation transcript:
1 Separation processes Dr Separation processes Dr. Hassan Sawalha Chemical Engineering Department An-Najah National University
2 Two words: permselective and evaporation PervaporationTwo words: permselective and evaporationTwo phase systemLiquid feed and vapor permeate.Asymmetric composite membraneSelective for species ASpecies B usually has some finite permeability.The dense film is in contact with the liquid sideVacuumvaporization
5 Applications dehydration of ethanol Pervaporation is best applied when the feed solution is dilute in the main permeantdehydration of ethanoldehydration of other organic alcohols, ketones, and esters(3) removal of organics from water.(4) separation of organic mixtures, e.g., benzene-cyclohexane, is receiving much attention.
6 Hybrid process distillation-pervaporation for removal of water from ethanol. (retentate)Pervaporation unit95.6 % ethanol25 % ethanol (permeate)60 % ethanol40% waterThe distillate purity is limited because of the 95.6 wt% ethanol in water azeotrope.
7 Transport equations in pervaporation Because phase change and nonideal-solution effects in the liquid feedSimple equations i.e. for dialys is do not apply to pervaporation.A particularly convenient PV model is that of Wijmans and BakerThey express the driving force for permeation in terms of a partial-vapor-pressure difference.Because pressures on the both sides of the membrane are low, the gas phase follows the ideal-gas law.
8 Therefore, at the upstream membrane surface (I), permeant activity for component i is expressed as:
13 Gas Permeation the feed gas at high pressure PI, contains some low-molecular-weight species (MW < 50)higher-molecular-weight species.Usually a sweep gas is not used,permeate side of the membrane is maintained at a much lower pressure, P2,often near-ambient pressure.The membrane is often densepermselective for certain of the low-molecular-weight species.
14 Applications (1) separation of hydrogen from methane; (2) adjustment of H2-to-CO ratio in synthesis gas(3) O2 enrichment of air(4) N2 enrichment of air;(5) removal of C02;(6) drying of natural gas and air
15 Transport equation In dense membranes species absorbed at the surface then transported through the membrane by one or more mechanisms.Permselectivity depends on both membrane absorption and the membrane transport rate.Usually all mechanisms are formulated in terms of a partial-pressure
25 Process Configurations An ultrafiltration process is commonly conducted in one of four configurations or combinations:(1) batch ultrafiltration,(2) continuous bleed-and-feed ultrafiltration,(3) batch diafiltration(4) continuous bleed-and-feeddiafiltration.
32 Continuous Feed-and-Bleed Ultrafiltration A large fraction of the retentate is recycled at steady stateBleed is that portion of the retentate that is not recycled, but is withdrawn as product retentateAt startup the entire retentate is recycledUntil the desired retentate concentration is achieved,At which time bleed is initiated
33 The advantages and disadvantages of feed-and-bleed operation The single-pass mode is usually unsuitable for ultrafiltrationbecause the main product is the concentrate rather than the permeate (as in reverse osmosis)High yields of permeate are required in order to adequately concentrate solutes in the retentatea single-pass ultrafiltration requires a very long membrane path or a very large membrane area
34 The advantages and disadvantages of feed-and-bleed operation with the high recycle ratio,the concentration of solutes on the retentate side is highresulting in the lowest flux,Larger membrane area
35 Solution: Multistage continuous feed-and-bleed ultrafiltration where the retentate (bleed) from each stage is sent to the next stage,while the permeates from the stages are collected into a final composite permeatethe final and highest concentration is only present in the final stage.
36 DiafiltrationInvolves the addition of solvent (usually water) to the retentate,followed by filtration.Additional solvent dilutes the retentate so as to increase the flux.Thus ultrafiltration is employed to a certain limiting concentration of solutes,followed by diafiltration to further enhance solute separation.The final retentate may not be very concentrated in retained solutes,but it contains a smaller fraction of permeable solutes
37 MICROFILTRATIONmicrofiltration is a pressure-driven, microporous membrane processused to retain matter commonly of microns.the matter may include large colloids, small and solid particles, blood cells, yeast, bacteria and other microbial cells, and very large and soluble macromolecules
38 Membrane structures for microfiltration screen filters that collect retained matter on the surfacedepth filters that trap particles at constrictions within the membrane
39 depth filters include: relatively thick, high-porosity (80-85%) castcellulose-ester membranes having an open, tortuous, sponge-like structure;thin, low-porosity (nominal 10%) polyester or polycarbonate track-etch membranes of a sieve-like structure with narrow distribution of straight through,cylindrical pores.The latter have a much sharper cutoff, resulting in enhanced separation factors
41 Transport equationsEquations for computing TFF microfiltration are those developed for ultrafiltration. This includes batch, continuous feed-and-bleed, and diafiltration operation modes.Equations for DEF microfiltration are those for conventional, batch, solid-liquid, slurry filtration, frequently referred to as cake filtration.
46 improvements in yield by a combined operation in which: Constant-flux operation is employed in Stage 1 up to a limiting pressure drop, followed by(2) Constant-pressure operation in Stage 2 until a minimum flux is reached