1. P RE V IEW T O GAS LAWS

2. BOYLE’S LAW How are the Pressure and Volume of a gas related? COPYRIGHT © PEARSON EDUCATION, INC., OR ITS AFFILIATES. ALL RIGHTS RESERVED. Boyle’s Law Click on the link below to watch the video or continue with the power point: www.youtube.com/watch?v=Xto88gMmDzw

3. BOYLE’S LAW If the temperature is constant, as the pressure of a gas increases, the volume decreases. COPYRIGHT © PEARSON EDUCATION, INC., OR ITS AFFILIATES. ALL RIGHTS RESERVED. And, as the pressure decreases, the volume increases.

4. BOYLE’S LAW COPYRIGHT © PEARSON EDUCATION, INC., OR ITS AFFILIATES. ALL RIGHTS RESERVED. Robert Boyle was the first person to study this pressure-volume relationship in a systematic way.

5. COPYRIGHT © PEARSON EDUCATION, INC., OR ITS AFFILIATES. ALL RIGHTS RESERVED. Interpret Graphs As the volume decreases from 1.0 L to 0.5 L, the pressure increases from 100 kPa to 200 kPa.

6. BOYLE’S LAW COPYRIGHT © PEARSON EDUCATION, INC., OR ITS AFFILIATES. ALL RIGHTS RESERVED. P 1  V 1 = P 2  V 2 Boyle’s law states that for a given mass of gas at constant temperature, the volume of the gas varies inversely with pressure. So, mathematically:

7. Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved. Sample Problem 14.1 Using Boyle’s Law A balloon contains 30.0 L of helium gas at 103 kPa. What is the volume of the helium when the balloon rises to an altitude where the pressure is only 187.9 mmHg? (Assume that the temperature remains constant.)

8. Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved. Sample Problem 14.1 Use Boyle’s law (P 1  V 1 = P 2  V 2 ) to calculate the unknown volume (V 2 ). KNOWNS P 1 = 103 kPa V 1 = 30.0 L P 2 = 187.9 mmHg UNKNOWN V 2 = ? L Analyze List the knowns and the unknown. 1

9. Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved. Sample Problem 14.1 Start with Boyle’s law. Calculate Solve for the unknown. 2 P 1  V 1 = P 2  V 2

10. Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved. Sample Problem 14.1 Rearrange the equation to isolate V 2. Calculate Solve for the unknown. 2 V 2 = P2P2 V1  P1V1  P1 Isolate V 2 by dividing both sides by P 2 : P 1  V 1 = P 2  V 2 P2P2 P2P2

11. Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved. Sample Problem 14.1 Because the initial pressure is given in kPa and the final pressure is given in mmHg, you must convert one so that both have the same units. In this case, you can decide which conversion you want to use (either will give the same answer). Calculate Solve for the unknown. 2 187.9 mmHg X 101.3 kPa = 25.0 kPa 760 mmHg

12. Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved. Sample Problem 14.1 Substitute the known values for P 1, V 1, and P 2 into the equation and solve. Calculate Solve for the unknown. 2 V 2 = 25.0 kPa 30.0 L  103 kPa V 2 = 124 L

13. CHARLES’S LAW How are the temperature and volume of a gas related? COPYRIGHT © PEARSON EDUCATION, INC., OR ITS AFFILIATES. ALL RIGHTS RESERVED. Charles’s Law Click on the link below to watch the video or continue with the power point: https://www.youtube.com/watch?v=7ZpuMBkf1Ss

14. CHARLES’S LAW COPYRIGHT © PEARSON EDUCATION, INC., OR ITS AFFILIATES. ALL RIGHTS RESERVED. When an inflated balloon is dipped into a beaker of liquid nitrogen, the air inside rapidly cools, and the balloon shrinks.

15. CHARLES’S LAW As the temperature of an enclosed gas increases, the volume increases, if the pressure is constant. COPYRIGHT © PEARSON EDUCATION, INC., OR ITS AFFILIATES. ALL RIGHTS RESERVED.

16. Interpret Graphs The graph shows how the volume changes as the temperature of the gas changes.

17. CHARLES’S LAW COPYRIGHT © PEARSON EDUCATION, INC., OR ITS AFFILIATES. ALL RIGHTS RESERVED. V1V1 V2V2 T1T1 T2T2 = Charles’s law states that the volume of a fixed mass of gas is directly proportional to its Kelvin temperature if the pressure is kept constant. So, mathematically:

18. Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved. Sample Problem 14.2 Using Charles’s Law A balloon inflated in a room at 24 o C has a volume of 4.00 L. The balloon is then heated to a temperature of 58 o C. What is the new volume if the pressure remains constant?

19. Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved. Sample Problem 14.2 Use Charles’s law (V 1 /T 1 = V 2 / T 2 ) to calculate the unknown volume (V 2 ). KNOWNS V 1 = 4.00 L T 1 = 24 o C T 2 = 58 o C UNKNOWN V 2 = ? L Analyze List the knowns and the unknown. 1

20. Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved. Sample Problem 14.2 Because you will use a gas law, start by expressing the temperatures in kelvins. Calculate Solve for the unknown. 2 T 1 = 24 o C + 273 = 297 K T 2 = 58 o C + 273 = 331 K

21. Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved. Sample Problem 14.2 Write the equation for Charles’s law. Calculate Solve for the unknown. 2 V 1 V 2 = T 1 T 2

22. Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved. Sample Problem 14.2 Rearrange the equation to isolate V 2. Calculate Solve for the unknown. 2 V 2 = T1T1 V1  T2V1  T2 Isolate V 2 by multiplying both sides by T 2 : V1V1 T2T2 V2V2 T1T1 T2T2 T2T2 =  V 1 V 2 = T 1 T 2

23. Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved. Sample Problem 14.2 Substitute the known values for T 1, V 1, and T 2 into the equation and solve. Calculate Solve for the unknown. 2 V 2 = 297 K 4.00 L  331 K V 2 = 4.46 L

24. A hot air balloon contains a propane burner onboard to heat the air inside the balloon. What happens to the volume of the balloon as the air is heated? COPYRIGHT © PEARSON EDUCATION, INC., OR ITS AFFILIATES. ALL RIGHTS RESERVED. CHEMISTRY & YOU

25. COPYRIGHT © PEARSON EDUCATION, INC., OR ITS AFFILIATES. ALL RIGHTS RESERVED. CHEMISTRY & YOU According to Charles’s law, as the temperature of the air increases, the volume of the balloon also increases. A hot air balloon contains a propane burner onboard to heat the air inside the balloon. What happens to the volume of the balloon as the air is heated?

26. GAY-LUSSAC’S LAW COPYRIGHT © PEARSON EDUCATION, INC., OR ITS AFFILIATES. ALL RIGHTS RESERVED. How are the pressure and temperature of a gas related? Gay-Lussac’s Law Click on the link below to watch the video or continue with the power point: www.youtube.com/watch?v=0Oq7bCSDPxE

27. GAY-LUSSAC’S LAW As the temperature of an enclosed gas increases, the pressure increases, if the volume is constant. COPYRIGHT © PEARSON EDUCATION, INC., OR ITS AFFILIATES. ALL RIGHTS RESERVED.

28. GAY-LUSSAC’S LAW As the temperature of an enclosed gas increases, the pressure increases, if the volume is constant. COPYRIGHT © PEARSON EDUCATION, INC., OR ITS AFFILIATES. ALL RIGHTS RESERVED.

29. GAY-LUSSAC’S LAW Gay-Lussac’s law states that the pressure of a gas is directly proportional to the Kelvin temperature if the volume remains constant. So, mathematically: COPYRIGHT © PEARSON EDUCATION, INC., OR ITS AFFILIATES. ALL RIGHTS RESERVED. P1P1 P2P2 T1T1 T2T2 =

30. Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved. Sample Problem 14.3 Using Gay-Lussac’s Law Aerosol cans carry labels warning not to incinerate (burn) the cans or store them above a certain temperature. This problem will show why it is dangerous to dispose of aerosol cans in a fire. The gas in a used aerosol can is at a pressure of 103 kPa at 25 o C. If the can is thrown onto a fire, what will the pressure be when the temperature reaches 928 o C?

31. Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved. Sample Problem 14.3 Use Gay Lussac’s law (P 1 /T 1 = P 2 / T 2 ) to calculate the unknown pressure (P 2 ). KNOWNS P 1 = 103 kPa T 1 = 25 o C T 2 = 928 o C UNKNOWN P 2 = ? kPa Analyze List the knowns and the unknown. 1

32. Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved. Sample Problem 14.3 Remember, because this problem involves temperatures and a gas law, the temperatures must be expressed in kelvins. Calculate Solve for the unknown. 2 T 1 = 25 o C + 273 = 298 K T 2 = 928 o C + 273 = 1201 K

33. Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved. Sample Problem 14.3 Write the equation for Gay Lussac’s law. Calculate Solve for the unknown. 2 P 1 P 2 = T 1 T 2

34. Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved. Sample Problem 14.3 Rearrange the equation to isolate P 2. Calculate Solve for the unknown. 2 P 2 = T1T1 P1  T2P1  T2 Isolate P 2 by multiplying both sides by T 2 : P1P1 T2T2 P2P2 T1T1 T2T2 T2T2 =  P 1 P 2 = T 1 T 2

35. Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved. Sample Problem 14.3 Substitute the known values for P 1, T 2, and T 1 into the equation and solve. Calculate Solve for the unknown. 2 P 2 = 298 K 103 kPa  1201 K P 2 = 415 kPa

36. P RE V IEW T O GAS LAWS VIDEOS Boyle’s Law http://www.youtube.com/watch?v=ZoGtVVu3ymQ Charles’ Law http://www.youtube.com/watch?v=oIfFoiwRCVE Gay Lussac’s Law (practice problems) http://www.youtube.com/watch?v=wHD-32rUHkE http://www.youtube.com/watch?v=lJzHzEnkXJE