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Leading Technology for AMOLED Backplane and Encapsulation
Eric Sun Technical Marketing Director CTO Office AKT Display Group Applied Materials, Inc. Display Innovation China 2014/Beijing Date: Oct. 15, 2014
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Display Technology Trend and Challenges
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Display Growing Visual Demand The eyes have it!
EMOTION IMMERSION CONSUMPTION INTERACTION GROWING DEMAND NEW TECHNOLOGIES 3
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Display Technology Transitions
TRANSISTOR DISPLAY TODAY TV 55” 65” >70” LCD OR OLED SIZE a-Si Phone 5” 5.x” <7” TV FHD 4K 8K RES. Phone >400ppi >600ppi >700ppi LTPS OR MOx FLEX OLED Form Factor 4
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AKT solutions_PVD
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AKT PiVot® : Rotary PVD System for Array Backplane
Chinese Capacity Meter² of “. . . rotary targets are leveraging higher productivity and film quality to win a significant portion of new fab business.” - DisplaySearch, July 2014
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Rotary Cathode Array Enabling improved uniformity and defect control
Open (Spacious) Architecture Al Cu Mo ITO IGZO Planar Rotary Programmable Magnet Wobble Obstructed Uniform Gas Flow Defect Control Rotating Target Planar Rotary Full-surface erosion “Self-Cleaning” New 56 % 67 % 72 % Minimum Nodules and Re-Deposition with Rotary Clean Target Erosion over Life 7
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Enhancing PVD Processes for LTPS
Optimize thickness & Rs unif. for better design rules; Reduce defects for Yield Leverage rotary target & directional magnet control to increase step coverage Ion bombardment & process tuning to minimize intrinsic film stress Utilizing rotary target technology to decouple directional grain growth
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ITO Optimization with H2 + O2 Process
Adjust H2 to control amorphous crystal ratio, etch rate & residues Adjust O2 to control Rs & Rs uniformity Providing next generation capability for Advanced LTPS
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Optimizing IGZO Uniformity
Two routes towards more uniform reflectivity profiles Ion Bombardment Control Energetic oxygen ion bombardment locally increasing microwave reflectivity Magnet movement improving as depo non-uniformities PiVot can eliminate target imprints IGZO Post Annealing As depo non uniformities in µPCR can be reduced by annealing µPCR 4.8% after annealing Lonke: Wobble improve µPCD signal, but not annealed Rechts: correlation µPCR signal with THK, after anneal 4.7% THK uniformity
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Addressing Uniform MOx Electronic Properties
IGZO Layer (µPCD) IGZO TFT Structures Unif. ≈ 40% No Magnet Wobble 4 TFTs for each position Unif. < 5% Optimized Wobble No Vth difference between or in front of targets Rotary Target Technology Mitigates Mura Effects for IGZO Backplanes
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AKT solutions_PECVD & TFE for OLED
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Gen6 PECVD Solution for High Resolution Display
Substrate size 1500x1850 mm2 System architecture Single Substrate Operation System at Cluster Tool : Max. 5 PC (High Temperature Process Chamber) : Annealing Chamber (Option) : DSSL (Dual Single Slot Load Lock) : Transfer Chamber : High Temperature Dual Arm Vacuum Robot High Temperature Process Chamber (Max.5) Annealing Chamber (Option) Transfer Chamber w/Dual Arm Vacuum Robot Key Advantages Uniformity Particle Control High System Reliability DSSL (Dual Single Slot Loadlock)
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CVD Advantages : Uniformity and Low Defect
IEEE Innovation Award Patent Protected CVD Advantages : Uniformity and Low Defect Diffuser with HCG (Hollow Cathode Gradient) Top-Down RPSC (Remote Plasma Source Clean) Plasma Uniformity Control The AKT55KS system for Metal oxide PECVD applications provides advantages for both uniformity and low defects. The hollow cathode gradient diffuser provides superior plasma uniformity across the entire generation 8.5 substrate. The top down remote plasma source clean based on NF3 plasma cleaning provides an efficient chamber clean resulting in fewer defect particles and disassociation of green house gasses. AKT continues to demonstrate our superior capability to scale up PECVD processes while maintaining uniformity across large substrates up to Gen 10 which was recognized this year with the IEEE Innovation award for Applied Materials AKT PECVD group. AKT-55KSは、均一性が高く、欠陥の少ない酸化物半導体用プラズマCVD膜を提供します。ホローカソードグラディエントディフューザーにより、第8.5世代の基板前面に非常に均一にプラズマを発生することができます。トップダウン式のリモートプラズマソースクリーニング装置によるエヌエフスリーベースのプラズマクリーニングにより、パーティクルを最小限にし、地球温暖化ガスの発生を最小限にしています。アプライド マテリアルズAKTのCVD装置は、均一性を維持しつつ、第10世代までの大型基板までスケールアップしてきました。今年の1月には、IEEEイノベーションアワードを受賞しました。 Uniform and Efficient Chamber Clean Demonstrated Uniformity up to Gen10
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Uniform gas distribution
SiH4-SiO Uniform gas distribution Pressure Simulation w/Gas Deflector Uniformity ~11% Uniformity ~4% Conventional design Enhanced diffuser assembly design for uniform gas distribution improves center dip profile on SiH4 based SiO process
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CVD Film Requirements for Reliable MO-TFT
Back channel protection, H-less Interface Passivation to protect from attacking by OH and H2O Back channel protection during process Substrate a-IGZO G S D BCE Structure ESL Structure Low defect, H- less Gate Insulator Low defect H-less Gate Insulator 1.Because of IGZO properties, it’s electrical properties are very easy affected by hydrogen and atmosphere. 2.For front and back channel we need hydrogen-less insulator. 3.We also need passivation to prevent IGZO from the damage of outer atmosphere. Right now most panel makers choose the ESL structure because the ESL can reduce plasma damage during the process. H-less Interface Low defect and H-less dielectric material is the requirement of gate insulator, etch stop and passivation for IGZO TFT for high reliability
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“One Cluster Solution” _ TFE
Complete All TFE process in one cluster Vacuum Connection to EV tool Flexible Sequence control by MCC software High reliability Mainframe and Vacuum robot Mask deposition with Auto Mask Exchange and Mask Stocker Concept Mask Stocker CVD Chamber 2nd Layer Example pp-HMDSO (SiCN) 3 Layer 5 Layer Upper-stream Load Lock Lower-stream Load Lock OLED EV Tool IN OUT Multiple Layer Stack 1st Layer 3rd Layer SiN SiN CVD Chamber TFE Technology for OLED mass production
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AKT OLED Solutions: Thin Film Encapsulation
Barrier: SiN Buffer: SiCN pp-HMDSO Multilayer structures with SiN layer and SiCN/pp-HMDSO buffer layer SiN/SiCN structure: For TV or Rigid Display Applications SiN/pp-HMDSO structure: For Flexible Mobile Applications Both TFE structures have passed customer device lifetime evaluation
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TFE : PECVD SiN Barrier Films
SiN WVTR : 1x10-3 g/m2·day range at 1µm single layer SiN @ 85°C/85%RH (by MOCON and Ca-test method) WVTR at 85°C/85%RH is about 2 orders higher than the ambient conditions SiN properties (80°C process) Film RI DR A/min Unif. % %T @400nm Stress MPa TFE SiN 1.85 > 2500 < 10% > 90% < 100 High optical transmittance (>90% at 400nm and above) Excellent Barrier performance High Depo. Rate
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TFE : PECVD pp-HMDSO Buffer Films
>95% Transmittance ~0 Stress 3 Layer (SiN/HMDSO) Plasma polymerized HMDSO (pp-HMDSO) N2O Hexamethylsiloxane (HMDSO) Film RI DR A/min Unif. % %T @400nm Stress MPa pp-HMDSO 1.45 > 5000 < 10% > 95% ~ 0 20
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TFE : “Flowability” of pp-HMDSO Buffer Film
The buffer film we developed has a wide range of physical properties, from flowable liquid-like to rigid glass-like, depending on the process conditions A flowable buffer film can cover a particle without leaving any voids or diffusion channel around it. 8µm x 4µm Without high Stress Hot Point (Better Particle Coverage) No Sharp Corners Observed on the particle High optical transmittance (>95% at 400nm and above) High Depo Rate Excellent Particle coverage 21
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TFE Layer Development Achievement
Step Coverage Profile Non-conformal profile – planarization of surface irregularity No high stress hot spots – minimize film cracking during bending Particle Coverage No voids around the particles – eliminate moisture permeation path No high stress hot spots and good surface planarization Stack Film Integration Stress matching by adding interfacial layer Transmittance improved to 400nm
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Summary AKT PECVD, PVD & TFE technology and system performance have been recognized by display customers and are ready for next generation LTPS TFT, MOx TFT and AMOLED application. AKT PiVot PVD system with advanced rotary target design enable high uniformity and low defect for metal & oxide film. AKT continues to innovate PECVD tool by developing differentiated, valuable and sustainable solutions to support our customers’ needs; focusing on film thickness uniformity, and ultra-low particle performance. AKT new developed TFE system with proven cluster architecture offers superior barrier/buffer layers and excellent performance for flexible AMOLED. AKT Solutions ready for next generation display with LTPS TFT, MOx TFT and AMOLED
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