1. Heterobetainas 2013-14 ALGUNAS REFERENCIAS RECIENTES……

2. Heterobetainas 2013-14 Palladium-Catalyzed Reductive Carboxylation of Aryl Halides Professor Manabe and co-workers of University of Shizuoka (Japan) Angew. Chem., Int. Ed. 2013, 52, 8611−8615) Sintesis a)Oxidacion de alcoholes b)Reduccion de acidos carboxilicos o derivados c)Formilacion de arenos –Wilsmeier- d)Formilacion de haloarenos –Li, DMF-

3. Heterobetainas 2013-14 Palladium-Catalyzed Reductive Carboxylation of Aryl Halides Professor Manabe and co-workers of University of Shizuoka (Japan) Angew. Chem., Int. Ed. 2013, 52, 8611−8615) CONDICIONES SUAVES, MAXIMA TOLERANCIA CON DIFERENTES R

4. Heterobetainas 2013-14 P. Knochel and co-workers in Munich, Germany Angew. Chem., Int. Ed. 2013, 52, 9495−9499 CONDICIONES NEGISHI POR LA VIA CONVENCIONAL, SE REQUIEREN IODUROS –CAROS- Y BAJAS TEMPERATURAS Alkenylzinc Reagents and Their Reactions with Electrophiles

5. Heterobetainas 2013-14 Prof. Fu, (China) J. Am. Chem. Soc. 2013, 135, 10630−10633 Synthesis of Aromatic Nitriles via Rhodium-Catalyzed ortho C–H Cyanation of Arenes with N-Cyano-N-Phenyl-p-Toluenesulfonamide NCTS Reactivos habituales: CuCN, KCN

6. Heterobetainas 2013-14 Prof. Fu, (China) J. Am. Chem. Soc. 2013, 135, 10630−10633 Synthesis of Aromatic Nitriles via Rhodium-Catalyzed ortho C–H Cyanation of Arenes with N-Cyano-N-Phenyl-p-Toluenesulfonamide NCTS Estable, no toxico

7. Heterobetainas 2013-14 Synthesis of Cyclopropane-Fused Heterocycles Prof. Aggarwal y col. (Univ. Bristol, UK) Chem. Eur. J. 2013, 10827−10831

8. Heterobetainas 2013-14 Synthesis of Cyclopropane-Fused Heterocycles Prof. Aggarwal y col. (Univ. Bristol, UK) Chem. Eur. J. 2013, 10827−10831

9. Heterobetainas 2013-14 Synthesis of Cyclopropane-Fused Heterocycles Prof. Aggarwal y col. (Univ. Bristol, UK) Chem. Eur. J. 2013, 10827−10831

10. Heterobetainas 2013-14 Direct Construction of Quaternary Centers from Tertiary Alcohols via Photoredox Catalysis J. Am. Chem. Soc. 2013, 135, 15342−15345) L. Overman, (L.A. USA)

11. Heterobetainas 2013-14 An Efficient Synthesis of Oxindoles via Cu-Catalyzed Trifluoromethylation/ Desulfonylation/ Aryl Migration/ Cyclization C. Nevado y col. Univ. Zurich (CH) J. Am. Chem. Soc. 2013, 135, 14480

12. Heterobetainas 2013-14 An Efficient Synthesis of Oxindoles via Cu-Catalyzed Trifluoromethylation/ Desulfonylation/ Aryl Migration/ Cyclization J. Am. Chem. Soc. 2013, 135, 14480

13. Heterobetainas 2013-14 An Efficient Synthesis of Oxindoles via Cu-Catalyzed Trifluoromethylation/ Desulfonylation/ Aryl Migration/ Cyclization J. Am. Chem. Soc. 2013, 135, 14480

14. Heterobetainas 2013-14 An Efficient Synthesis of Oxindoles via Cu-Catalyzed Trifluoromethylation/ Desulfonylation/ Aryl Migration/ Cyclization J. Am. Chem. Soc. 2013, 135, 14480

15. Heterobetainas 2013-14 An Efficient Synthesis of Oxindoles via Cu-Catalyzed Trifluoromethylation/ Desulfonylation/ Aryl Migration/ Cyclization J. Am. Chem. Soc. 2013, 135, 14480