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Nuclear Chemistry
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Nuclear Chemistry Remember that an element is defined by the number of protons in the nucleus. If I say the Oxygen-18 Isotope, I am referring to the Atomic Mass as 18. This can be written as 18O. Remember, the Atomic Mass is the number of protons and neutrons.
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Nuclear Chemistry Many Isotopes are radioactive.
Radioactivity is the spontaneous decomposition of nuclei. Spontaneous means they do it alone, with no required input of energy from us.
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Alpha Decay Alpha particle (4He) is ejected.
Only happens when Z > 83 222Ra 4He + 218Rn + (γ rays) The sums of nucleons is conserved!
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What isotope is formed from the Alpha decay of Bi-211?
iRespond Question F Multiple Choice A.) Tl-207 B.) Tl-215 C.) At-207 D.) At-215 E.)
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Beta Decays Three major types of beta decay: Negatron Positron
Megatron (just kidding!) Electron Capture
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Negatron Decay Changes a neutron into a proton
Produces a negatron and antineutrino Occurs when n/p ratio is too high 24Na 24Mg + β- + ν-
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What isotope will be formed from the negatron decay of Ag-116?
iRespond Question F Multiple Choice A.) Pd-117 B.) Pd-115 C.) Ag-115 D.) Cd-116 E.)
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Positron Decay Changes a proton into a neutron
Produces a positron, neutrino, and occasionally a gamma ray Occurs when n/p ratio is too low 45Ti 45Sc + β+ + ν + (γ rays)*
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What isotope will be formed from the positron decay of Na-22?
iRespond Question F Multiple Choice A.) Ne-21 B.) Ne-22 C.) Mg-21 D.) Mg-22 E.)
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Positronium When a positron is ejected from the nucleus it can encounter an electron. Since they have opposite charges, they attract and form Positronium (Ps). Lasts from 1.25 x s to 1.1 x 10-9 s until annihilation
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Annihilation Eventually (like really quickly) the two particles collide. This is the collision of a particle with its antiparticle which turns matter into energy. This is where the γ rays come from
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201Hg + -1e 201Ag + γ + ν + (X-Ray or Auger electron)
Electron Capture Occurs when n/p ratio is too low. Steals an orbital electron, collides with a proton turning it into a neutron. 201Hg + -1e 201Ag + γ + ν + (X-Ray or Auger electron)
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What isotope will be formed from the electron capture decay of As-73?
iRespond Question F Multiple Choice A.) Se-74 B.) Se-73 C.) Ge-73 D.) Ge-74 E.)
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Gamma Decay Atoms at a higher energy level can release that energy via a gamma ray. 110mAg 110Ag + γ M = metastable state, a somewhat stable equilibrium at a higher energy level.
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Predicting Decay Method
Alpha: BIG (Z>83) Atoms! Negatron: n/p ratio too high Positron: n/p ratio too low Gamma: Metastable state.
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Predict the decay method that the Si-27 isotope undergo.
iRespond Question F Multiple Choice A.) Alpha B.) Negatron C.) Positron D.) Gamma E.)
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Predict the decay method that the C-14 isotope undergo.
iRespond Question F Multiple Choice A.) Alpha B.) Negatron C.) Positron D.) Gamma E.)
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Predict the decay method that the Fr-223 isotope undergo.
iRespond Question F Multiple Choice A.) Alpha B.) Negatron C.) Positron D.) Gamma E.)
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Predict the decay method that the O-18 isotope undergo.
iRespond Question F Multiple Choice A.) Alpha B.) Negatron C.) Positron D.) Gamma E.)
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