1. Abstract The Mississippi Lime, a primary target for oil exploration in Central Kansas and Oklahoma, is a difficult, altered lime reservoir with significant secondary porosity. Production generally has a very high water cut. A full core was taken and an analysis of the basic porosity and permeability was conducted. The release of the data coincides with the enhanced interest in this reservoir and the search for useful log information to determine the best position for horizontal drilling to minimize the water production and maximize the oil production. Advancements in the physics of measurement and details of analysis have generated great confidence in the basic measurements of nuclear magnetic resonance (NMR) logs. The measurement of total porosity is capably determined by this technology with virtually no massaging of data. A conclusion of effective porosity, while not as easily determined, is still less subject to the whims of an analyst than any other method currently employed in the oil and gas business. Permeability calculated from the NMR measurements is less straightforward. Historically, this calculation requires knowledge of the particular reservoir involved, with adjustments to the calculation made as the analyst detects changes in the rock structure. Any ability to remove subjective inputs from analysis is a desirable objective. In this study, we will compare the results of porosity, effective porosity, and permeability from NMR to these same values as determined by lab work on the cores. For porosity, T 2 (relaxation) characterizations will be considered. For permeability, the Bray-Smith permeability will be presented and compared to the core results.. Introduction The Mississippian formation is an extensive lime reservoir that extends throughout Kansas and much of Oklahoma. The matrix formation is a very dense lime and demonstrates little primary porosity. The rock is altered after deposition by fluid flow events and other processes that can create vugs in the reservoir. When these are connected, significant permeability can result. There are also areas of the formation that include natural fractures. Every enhancement created by these alterations can contribute significantly to the value of the reservoir. This formation requires secondary alteration of the carbonate reservoir in order to be commercially productive. The evaluation of the formation is difficult due to the inconsistency of the development of these secondary features. Some areas of the reservoir have extensive alteration and other areas are virtually unaltered. This creates a great variation in the permeability in the reservoir. Image logs are capable of identifying these secondary features. They cannot identify the connectivity of the features nor can they characterize the change in permeability as a result of these alterations. NMR logs were added to the logging program to evaluate permeability for production. The hope was that the NMR tool could properly evaluate not only the volume but the quality of the secondary porosity and the contribution to permeability by this reservoir enhancement. Permeability Model The resolution of the problem has several different components. The first issue was permeability. Low porosity in this reservoir that has secondary porosity development can have permeability in the millidarcy range. These secondary porosity events can be adjacent to areas with no alteration. These areas have permeability that is non-existent. Many attempts were made to correlate these alteration events to measurements from standard logs with very poor results, but accurate permeability is critical to define portions of the reservoir that would be productive. NMR logs were added to the logging suite to provide an additional investigative assessment of the porosity. Permeability was determined to be the most important reservoir characteristic. Low porosity in many cases did not correlate to low permeability. The pore sizes in the formation dictated the productivity of the formation. This is described by this graph of T 2 of relaxation time versus pore size. General Relationship Between NMR T 2 Time and Pore Size This reservoir did not have consistent development of secondary porosity. Alterations of the fabric of the rock could be observed as bin characterizations of the NMR T 2. Since the basic carbonate matrix is fairly consistent, the observed changes could be attributed directly to secondary alteration. This secondary alteration contributes to permeability. Close observation of these alterations in texture could be significant in determining the potential of this reservoir. Characterization of this texture and fabric are the desired result of the NMR logs. The Bray-Smith permeability equation from nuclear magnetic resonance (NMR) logs was introduced to the industry several years ago as a technique that could forecast permeability in a fairly accurate manner in any reservoir without the need for external data from cores or other sources. This equation takes the form: Where MPHI = NMR porosity, wf = weight factor, T2Bphi = segmented bin porosity, BVI = bulk volume irreducible and p and s are constants derived from core and empirical studies. Permeability can be determined from this application in the absence of any core or reservoir studies. The permeability characterized is generally within +/- 20% of laboratory permeability. This permeability can be used to target portions of the reservoir that have greater capability to produce. Challenge The image on the left is a massive carbonate. The image on the right shows a significant amount of secondary enhancement features. Every change in the rock that is not depositional in nature is an alteration that must be accounted for in order to understand the effective productive capability of the rock. Micro fractures as well as vug development can be observed when the reservoir is examined on a microscopic basis. The fractures are small enough and not a significant portion of total porosity so that they are not apparent on any type of standard porosity device. The matrix rock in this formation is extremely dense, yielding a very low porosity response from any device. The cumulative effect on the density and neutron porosity calculations is an extremely tight reservoir. Apparent porosity is in the 3-5% range. This is generally not considered to be enough porosity to provide permeability and definitely not enough storage capability to provide a significant reserve calculation. Some technology that can resolve this difficult issue is required. Recent developments in NMR analysis provide a technique that can effectively evaluate the alterations within the reservoir and accurately establish permeability exclusive of any other log measurement. Full-Core Porosity and Permeability Comparison to Nuclear Magnetic Resonance Results in Mississippi Lime Charles H Smith and Lynda Ziane, Halliburton Energy Services 210 Park Avenue, Suite 2000 Oklahoma City, OK 73102 (405) 203-6247 Massive Lime Outcrop and Microscopic Alteration of Lime © 2013 Halliburton. All Rights Reserved.

2. Results Comparison of Core and NMR Porosity and Permeability The log above is a comparison of NMR porosity and permeability to core results over the same zone.This is a dense, complex carbonate with secondary porosity conditions. The porosity overlays almost exactly for core, NMR and neutron; the density porosity is less. The permeability comparison is most interesting. The high values for permeability from the core are in the 15-20 md range while the low values are reported in the 0.001 md range. Obviously, some of this rock is unaltered with major changes in other portions. The NMR permeability provides an average, presenting a 3 md calculation for this interval. When the core permeability is averaged, the same value is achieved. This implies that the vertical resolution of the NMR is not capable of accurately measuring each individual alteration event, but, in the aggregate provides a value useful for evaluation. Permeability- thickness (kh) values are the same from core or NMR. Heavily Altered Low Porosity Section This portion of the log has a core report of very low porosity in the 1-3% range. NMR porosity is somewhat higher in the 3-5% range. The issue here that requires more research is the overstatement of porosity by the NMR or the under-reporting of porosity from laboratory work on the core. It is striking that this low core porosity could have a reported permeability of up to 20 md. The alteration is apparent in the diversity of core permeability as well as the pore size description from the measured T 2 response. Again, the permeability-thickness (kh) value of the NMR permeability corresponds very well to the core kh values. This is a valid conclusion in every portion of this reservoir. Conclusions Magnetic resonance logs (NMR) can be used to accurately define permeability through application of the Bray-Smith permeability equation. Secondary porosity features such as vugs and fractures can have an identifiable effect of the T 2 bin distribution. These altered time values can be incorporated into the permeability equation to derive a useful result. These calculated values of NMR permeability, although limited by the vertical resolution characteristics of the tool, still arrive at an average permeability-thickness (kh) value that has proven to be valid in every portion of this Mississippian reservoir. The measured and calculated values for porosity and permeability are a valid qualitative characterization of reservoir parameters and are accurate enough to be utilized for economic evaluation of this and virtually every other reservoir. References Smith, et al., “A New Systematic Approach to Achieve Effective Completions in Unconventional Reservoirs”, Paper presented at the AAPG ACE Convention, Houston 2011 Warpinski, et al., “An Interpretation of M-Site Hydraulic Fracture Diagnostic Results”, SPE paper 39950 presented at the Rocky Mountain Regional/Low Permeability Reservoirs Symposium and Exhibition, Denver, CO, April 1998 Analysis This complex carbonate has significant secondary alteration features that are easily observed in core studies. These alterations appear as vugs or fractures in core samples. The image below is a section of Mississippian core that shows extensive alteration. The vugs in the image are many times larger than the primary porosity observed in the core. Image of Vugs in Mississippian Core and Textural Observations in NMR from Vugs The NMR log on the right of the image provides some insight into the way that these textural alterations can be defined from logs. The portion of the Mississippian reservoir centered on 5350 feet has very early time T 2 measurements. Most of the responses are 32 ms and less. These are shown in track 1. The color bands correspond to the time measurements. The amount of porosity measured within each of these time slices is stacked upon each other. The total of these measurements equals effective porosity. In this interval, effective porosity is 4-5%. The Bbin curve second from right is designed to be a visual tool to estimate the variability of the rock within a specific area. This curve is the percentage of all pores measured at a specific depth that measure greater than 64ms divided by total porosity measured for that depth. The result is presented as a percentage from 0 to 100 percent in the track. The intuitive conclusion is that the greater percentage of large pores that are measured at any one point, the higher permeability will be observed for that interval. The zone at 5350 has a center section with Bbin ratio of 50%. This appears to be a very localized alteration of this rock. The sections immediately above and below this stringer are very tight and have a Bbin value of less than 10%. The permeability calculated in the best of this zone is a stringer of about 0.3 md which corresponds exactly to the Bbin calculation of 50%. Bbin values that are more than 50% in this Mississippian reservoir are usually areas that have secondary porosity. In this case. The secondary porosity indications are in the center of this small zone. Other areas, with low ratios of large pores represent rock unaltered by fractures or vugs. The two zones between 5315 and 5330 feet show extensive alteration. The T 2 evaluation of porosity is still very low in the 5-6% range as observed in track 1. The Bbin description of porosity quality is very good. The lower depositional sequence has a large section of Bbin ratio of 60%. Inspection of the T 2 bin distribution at this depth reveals that 3% of this porosity is 32 ms and less. The rest of the pore structure is captured in the 512 ms time and later. There is no transition of data from 32 to 512 ms, it is represented as an abrupt jump to this later time. This is characteristic of secondary porosity events in any reservoir. The permeability calculated with Bray-Smith has a peak at 1 md, but the majority of the zone is less. The upper sequence has at least a portion that is about 90% late time measurements. Both of these should be considered secondary porosity characterizations with the upper section’s porosity composed almost entirely of the altered condition. There is less than 2% porosity measured at times of 16 ms and less. The next measured time is 512 ms. Again, this is a strong indication of secondary porosity. The permeability calculated is now in the 1 md range for the entire interval. Positive indications are reflected in the application of Bray-Smith permeability. Both of these intervals show good permeability. This result in a reservoir that has only 6% porosity at best shows that alteration in the reservoir that has only a minor contribution to porosity can have an extensive impact on the permeability. The upper section in this example is accurately measured and characterized by the NMR. The image of the core section above is very similar to the log description. The core appears quite tight with significant secondary alteration in the form or vugs. A general observation can be made that these events can be accurately reflected in the NMR logs measurement. The only caveat to that is that the entire T 2 spectrum must be collected in order to understand all of the late time events. This technique will be utilized to compare results in the wells drilled by Kansas Geological Survey. These wells had full core taken and analyzed for porosity and permeability. The results from NMR run in the same wells will be shown as well. The porosity and permeability from the Bray-Smith permeability equation will be compared to the core measurements. © 2013 Halliburton. All Rights Reserved.