1. Refinery Gas Analyzer Solution for Refinery Gas Streams
Company Confidential
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2. Refinery Gas Analyzer (RGA)
Product
Value Proposition
Competitive Positioning
Sales Tools
How to Order
Step by Step & Demonstrated Analysis
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3. Refinery Gas Analyzer (RGA)
Company Confidential
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4. Analyzer Purpose Product value $$
Points of measurement, Transport Quality Control
Impurities, Product suitability
Quality for next production step
e.g PolyEthylene & PolyPropylene
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5. Analyzer Scope Component Analytical Range Precision (%)
C1 up to C5 plus composite of C6+
0.01*– 100%
<1%
Carbon dioxide, Ethylene, Ethane, Acetylene, Oxygen, Nitrogen, Methane, Carbon monoxide
0.01 % – 100%
Hydrogen sulfide
0.05%* – 100%
Hydrogen
0.01%
Acid Gas **
YES
Possible
Refinery Gases / Natural Gas /Reformer Gas
Excellent
C2/C2=
C3/C3=
LPG
Good
Analysis time
25 min
Acid GAS?
* Lower LOD possible with bigger sample loop: ppm for H2S, 0.5 ppm for C1-C5 Hydrocarbons
** Max 45% H2S
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6. Analyzer Scope Programmed for Refinery Streams C1-C5
Widest Analytical Scope:
C1-C5 Hydrocarbons
Permanent gases (H2, He, O2, N2, CO, CO2).
H2S
Compliant to Key methods
ASTM D1946, D2504, D2163, D2593, D4424,
IP 405, ISO 7941, EN27941,DIN 51666, EN 15984,
UOP539, GOST 31371
UOP 373 Composition of C2 through C5 Hydrocarbon Mixtures by GC
UOP 899 Trace Hydrocarbons in Hydrogen, Hydrocarbon Gases, or LPG by GC.
UOP 980 C5 and Lower Boiling Dienes, Olefins, and Paraffins in Naphthas by GC.
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7. Permanent gases channel Light Hydrocarbon channel
Configuration
Hydrogen channel
Permanent gases channel
Light Hydrocarbon channel
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8. Configuration Hydrogen Channel LDL H2 0.01%
8port valve, Hayesep/Molsieve Packed Columns with Pressure Point Backflush to TCD
LDL H %
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9. Configuration Permanent Gases channel
10port valve, Hayesep/Molsieve Packed Columns and series/bypass valve on TCD
Oxygen, Nitrogen, Methane, Carbon Monoxide, Carbon Dioxide, Ethane, Ethylene, Acetylene and Hydrogen sulfide.
LDL Permanent Gases: <0.01%
LDL Hydrogen sulfide: <0.05%*
* ppm possible with bigger sample loop
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10. Configuration Light Hydrocarbons channel
10port valve, Alumina/apolar column, FID
All Hydrocarbons up to C6.
Pressure Point backflush of C6+ composite
LDL 0.01% (<0.5 ppm with bigger sample loop)
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11. RGA – Value Proposition
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12. Value Proposition RGA Dedicated Solution Accuracy - Trusted data!
Designed, Built, Tested & Documented to method
Flexible 3 channel platform – no side mounted 3rd detectors
Accuracy - Trusted data!
Proven Results
Sample Integrity Solutions
Software for automation, calculus, reporting
Better ROI / Lower Cost of Ownership
Fast cycle times
Low maintenance due to superior build quality
Compliancy to key Gas Methods:
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13. RGA - Options Company Confidential
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14. Sampling Options Pressure Station
Inject Sample as Liquid, no premature evaporation and discrimination
Constant P and T for LNG
Mounts On top of GC
Maximum Pressure: 2500 kPa / 360 psi
Requires Inert gas Supply 2500 kPa
SAMPLE OUT
TO VENT
SAMPLE IN
Carrier
Gas
HIGH GAS
PRESSURE IN
TESCOM
REGULATOR
RESTRICTION
BUMB PR
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15. Sampling Options Gasifier Inject sample as Pressure Controlled Gas
Constant Pressure and Temperature
Adjustable Temperature (max. 175°C),
Maximum sample inlet pressure: 1000 psi / 7000 kPa / 7 bars
Integrated in GC
Flush vent
To GC nv
Heated pressure regulator
Sample
inlet
Outlet Pr
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16. Sampling Options Liquid Sampling Valve Sampling Valves in Hasteloy C
4-port LSV for LPG samples, unheated
8-port dual LSV for LPG samples, unheated
Sampling Valves in Hasteloy C
Maximum inertness
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17. Sampling Options HT/HP On/Off Valve For samples up to 6000 psi / 300°C
Ideal for liquid or supercritical fluids.
Controlled & Automated by GC
Mounted directly into Large Valve oven
Easy switch between high- & low- pressure samples
1/16” connection, 0.75 mm bore,
low int. volume (< 2 µl)
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18. Sampling Options Low Pressure Sampling Pump Kit
For samples with low pressures
0-10 Psi
Tedlar Bags
Controlled & Automated by GC
Mounted under top GC cover
Automated switching between high- & low-pressure samples
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19. Software Options CompassCDS Hydrocarbon Reporting Dry Gas Calculations
Component Mol %,
Normalized Component Mol %,
GPM (Gallons per 1000 ft3)
Fraction Molecular Weight,
Specific Gravity,
Compressibility
Ideal Relative Gas Density, Ideal Gas Density
Real Relative Gas Density, Real Gas Density
Heating Value kJ.mol-1 (Superior), Heating Value kJ.mol-1(Inferior)
Heating Value MJ.kg-1 (Superior), Heating Value MJ.kg-1 (Inferior)
Heating Value MJ.m3 (Superior), Heating Value Mj.m3 (Inferior),
Gross Heating Value BTU/ft3 (Ideal)
Dry Gas Calculations
Net Heating Value BTU/ft3 (Real) Dry Gas,
Gross Heating Value BTU/ft3 (Ideal) Saturated gas
Net Heating Value BTU/ft3 (Real) Saturated gas,
GPM C2+, GPM C3+, GPM C4+
Wobbe Index, Research Octane Number (RON)
Motor Octane Number (MON), Carbon Number.
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20. Software Options Standard Reporting Template
Customizable for Logo & Headers
Compound Table
Advanced Calculus and Ext. Reporting
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21. Software Options Standard Reporting Template
Customizable for Logo & Headers
Compound Table
Advanced Calculus and Ext. Reporting
No Excel required
Exclude errors in manual calculus
Embedded/automated in Compass
(w/o Eclipse)
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22. Software Options Eclipse Gas Reporter Customizable for Logo & Headers
Compound Table
Advanced Calculus and Ext. Reporting
No Excel required
Exclude errors in manual calculus
Embedded/automated in Compass
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23. Software Options Eclipse Gas Reporter Customizable for Logo & Headers
Compound Table
Advanced Calculus and Ext. Reporting
No Excel required
Exclude errors in manual calculus
Embedded/automated in Compass
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24. Compliancy ASTM D1945, D2163, D2504, D2593, D4424 DIN 51666
IP194, IP405,
ISO7941, EN27941, EN15984
UOP373, UOP539
GOST31371
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25. Method Compliance for Refinery Gas Analyzers
Compliance to Method
RGA
Rapid RGA
ASTM D1945 √
ASTM D1946
ASTM D2163
ASTM D2504
ASTM D2505
ASTM D2593
ASTM 2597
ASTM D2598 (Calculation only)
ASTM D4424
ASTM D7833
DIN 51666
DIN 51872
IP 194 (= ASTM D2593)
IP 405 (=ISO27941, EN27941)
ISO7941 (=ISO27941)
EN27941(= ISO7941)
EN15984
UOP373
UOP539
UOP603
UOP709
UOP899
GOST 31371
Company Confidential
© 2009 Scion Instruments. All Rights Reserved

26. Competitive Positioning
Company Confidential
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27. Competitive Landscape
Scion USP:
True 3 channel platform, no additional side mounted Detectors.
3 Independent Ovens (LVO, GC oven, SVO (Single, Dual or Triple)
Accurate Temp controls  accurate Retention Times
Superior Build quality
HT/HP sampling Valve (Top mounted!)
up to 6000 PSI/300°
Simplifies quick switch low/high pressure samples
High Quality SS Sample connections standard
Low pressure Sampling Option for Tedlar bags
GC Language Localization (if applicable for area)
Software: CompassCDS with Hydrocarbon Reporting or Eclipse
Scalable, C/S, and dedicated for Gas Analysis!
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28. RGA vs Rapid RGA Components measured RGA Rapid RGA
C1 up to C5 plus composite of C6+
0.01 %* – 100%
0.01 % – 100%
Carbon dioxide, Ethylene, Ethane, Acetylene, Oxygen, Nitrogen, Methane, Carbon monoxide
Hydrogen sulfide
0.05%* – 100%
Hydrogen
0.01%
Columns
Packed
Micropacked + Cap.
Lower Reporting Limit & Range
100 ppm - 100%
Precision (Repeatability % RSD, n=20)
<1.0
Analysis Time (minutes) 25
5 (6 with H2S)
Sample Scope
Acid Gas **
Good
Refinery Gases / Natural Gas
Excellent
C2/C2=
C3/C3=
LPG
* ppm possible with bigger sample loop
** Max 45% H2S
Company Confidential
© 2009 Scion Instruments. All Rights Reserved

29. Sales Tools Company Confidential
© 2009 Scion Instruments. All Rights Reserved

30. Sales Tools PPT RGA & Rapid RGA App Notes Poster Board
Customer Value
How to order
Competitive
App Notes
Poster Board
Demonstrated Analysis
Hydrocarbons Ebook
Company Confidential
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31. How to Order Company Confidential
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32. How to Order - System P/N DESCRIPTION 4569939733
Refinery Gas Analyzer, 120V
Refinery Gas Analyzer, 230V
The Refinery Gas Analyzer is based on the 456-GC with dual independent TCD's, FID and electronic flow control. The Analyzer is suited for all types of refinery gases, including stack gases, flame gases and reformer gases. By using highly advanced columns the analyzer separates all saturated and unsaturated hydrocarbons up to C5 plus the composite of C6+, and all permanent gases, including hydrogen, nitrogen, oxygen, carbon monoxide, carbon dioxide and hydrogen sulfide. A Micro-Gasifier or a liquid sampling valve is optional. Contact the custom solution office for more details .
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33. How to Order - Options
P/N
DESCRIPTION
VLACI8UW1-60P
Automated, Unheated 8 Port Dual Liquid Sampling Valve
for injection of LPG type samples. Factory installed and functionally tested
VLA4CI4UW1P
Automated, Unheated 4 Port Liquid Sampling Valve
for injection of LPG type samples. Single loop valve. Injects into the Hydrogen channel. Factory installed and functionally tested.
CP739647
Pressure Station for LPG Samples
CP740531
Integrated 456-GC Micro-Gasifier.
For all Voltages. Factory installed. Requires a gas injection valve and a Valve oven.
CP740021
Sampling Valve Upgrade to Hasteloy C
Upgrades 1 valve to Hasteloy C
CP740267
Sample path per channel in Inert Steel treated material Includes Inert Steel treated sample loop and sample in/out connections.
VLASFVOLHTP
High Temp / High Pressure On/Off Valve
Max pressure 6,000 psi, max Temp 300°C, 1/16” connection, 0.75 mm bore, 1” stand off
Low Pressure Sampling Pump Kit
For low pressure samples
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34. How to Order - Software P/N DESCRIPTION BR502030
CompassCDS Hydrocarbon Reporting Tool.
Includes reporting for GPA/ISO/ASTM methods.
Requires CompassCDS Base License Software (BR502002) to already be installed on the computer.
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35. How to Order – Spare/Consumables Kits
P/N
DESCRIPTION
Consumable Kit : RGA
Includes all consumables for the system to operate.
All columns are included (1 pce each)
Spare Kit : RGA
Includes typical spare parts for the system (such as valves, ferrules, connections etc)
Main system components and/or voltage dependent parts/modules (such as PWA, EFC/DEFC, Inlets and Detectors are not included!).
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36. How to Order - Spares P/N DESCRIPTION CP745238
Fuse F-15A/250V, 5x20mm, Glass (24V DC,3AG)
BR746381
Fuse transformer 120V F-10A 250V 6.2x32mm
BR746382
Fuse transformer 230V F-8A 250V 6.2x32mm
Fuse F-15A / 24V (3AG)
CP745239
Fuse T- 10A/250V, 5x20mm, Glass HBC (Heaters)
CP745240
Fuse T- 15A/250V, 5x20mm, Glass (Column Heater)
BR746360
Chassis Fan
Column Oven Motor, 120V
Column Oven Motor, 230V
Vent Door Stepping Motor
Column Oven Heater, 120V
Column Oven Heater, 230V
CP741079
Bulkhead assy NG-EFC 436-GC
BR746195
Carriergas inlet manifold 456-GC
Carriergas+ Make up Tee connection
CP742210
Duo bed Molsieve/Charcoal filter, silver color
CP742211
Charcoal filter, gold color
FERRULE, 1/16"ID VITON; PK/10
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37. How to Order - Spares P/N DESCRIPTION 550013F
Electronic Detector Flowcontrol, type 13 (DEFC-13), Reference flow only
550014F
Electronic Detector Flowcontrol, type 14 (DEFC-14) Reference + Make-up
TCD, PWA 4x6-GC (= Electrometer)
CP745207
Detector interface board; 436/456-GC
TCD HEATER/PROBE ASSEMBLY, 120V 4x6
TCD HEATER/PROBE ASSEMBLY, 230V 4x6
TCD Make up adaptor for DEFC
Capillary column nut, 0.9 mm Brass,
SWSS100R2
Reducer, 1/8" x 1/16" SST
CR213104
FERRULE, Graphite/Vespel, 1/16" to 0.4mm ID, 10/PK, for 0.25 mm ID Columns
CR213105
FERRULE, Graphite/Vespel, 1/16" to 0.5mm ID, 10/PK, for 0.32 mm ID Columns
CR213108
FERRULE, Graphite/Vespel, 1/16" to 0.8mm ID, 10/PK, for 0.53 mm ID Columns
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38. How to Order - Spares P/N DESCRIPTION VLA4C8WE
Automated 8-port Valve, WE, 220 °C, with Air actuator
VLSSAC8WE
Spare rotor for 8-port valve CP
Needle valve
VLSL500CUWUM
Sample loop 500 µL, Inert Steel
VLA4C10WE
Automated 10-port Valve, WE, 220 °C, with Air actuator
VLA4C6WE
Automated 6-port Valve, WE, 220 °C, with Air actuator
VLSSAC6WE
Spare rotor for 6-port valve
VLSSAC10WE
Spare rotor for 10-port valve
VLSL1KCUWUM
Sample loop 1 mL, Inert Steel
CP401097
Needle valve, SST, Series/bypass
VLSL10CUWUM
Sample loop 10 µL, Inert Steel
VLZT5
Valco Tee union, 1/32" SST
VLFS55
fused silica adaptor 1/32", 0.50mm, 5pk
CP738499
Fused silica adaptor 1/32", 0.75mm, 1EA
CP742683
Twin hole ferrule 1/8" x mm, 10EA
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39. How to Order - Spares P/N DESCRIPTION 550024F
Electronic flow-/Pressure control, Field kit
Air solenoid valve for actuator CP
Sample solenoid valve, SST, 24Vdc
CP4007
Tubing, 1/16" x 0.75mm, SST, per meter
CP6535
Tubing, Inert Steel, 1/16"x 0.75mm, per 2 meter!
CP86517
Bulkhead union 1/8" x 1/16", Inert Steel
CP86518
Bulkhead union 1/16" x 1/32", Inert Steel
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40. How to Order - Consumables
P/N
DESCRIPTION
SC15895
1m X 1/8” X 2.0mm Inert Steel Hayesep Q mesh
SC15883
1m X 1/8” X 2.0mm Inert Steel Molsieve 5A mesh
SC15894
0.5m X 1/8” Inert Steel Hayesep T mesh
SC15885
0.5m X 1/8” Inert Steel Hayesep Q mesh
SC15884
1.5m X 1/8” Inert Steel Molsieve 13X mesh
SC30101
SCION m x 0.32mm x 1.20um (5" cage)
SC35302
SCION-Al2O3/Na2SO4 50m x 0.53mm x 10um
SC30083
SCION-Methyl Deact. FS 5m x 0.32mm
CP742210
Carrier gas Duo-bed Pencil filter50%Charcoal/50%Molsieve Ferrules included
CP742211
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41. Demonstrated Analysis
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42. Step by Step – H2 Channel Company Confidential
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43. Step by Step – H2 Channel - Inject
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44. Step by Step – H2 Channel - Backflush
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45. Step by Step – LHA Channel - Fill
Company Confidential
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46. Step by Step – LHA Channel - Inject
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47. Step by Step – LHA Channel - Backflush
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48. Step by Step – Perm. Gases - Fill
Company Confidential
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49. Step by Step – Perm. Gases - Inject
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50. Step by Step – Perm. Gases - Backflush
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51. RGA - Hydrogen Channel Peak ID Compound Name 1 Hydrogen
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52. RGA - Permanent Gases Channel
Peak ID
Compound Name 1
CO2 2
Ethene 3
Ethane 4
Ethyn 5
Hydrogen Sulfide 6
Oxygen 7
Nitrogen 8
Methane 9
Carbon Monoxide
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53. RGA - Light Hydrocarbons Channel
Peak ID
Compound Name 1
C6+ 2
Methane 3
Ethane 4
Ethylene 5
Propane 6
Cyclo Propane 7
Propylene 8
i-Butane 9
n-Butane 10
Propadiene 11
Acetylene 12
t-2-Butene 13
1-Butene 14
i-Butene 15
cis-2-Butene 16
i-Pentane 17
n-Pentane 18
1,3-Butadiene 19
Propyne 20
Butyne
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54. RGA Sample – NatGas Mix – LHA
Peak ID
Compound Name 1
C6+ 2
Methane 3
Ethane 4
Ethylene 5
Propane 6
Cyclo Propane 7
Propylene 8
i-Butane 9
n-Butane 10
Propadiene 11
Acetylene 12
t-2-Butene 13
1-Butene 14
i-Butene 15
cis-2-Butene 16
i-Pentane 17
n-Pentane 18
1,3-Butadiene 19
Propyne 20
Butyne
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55. Thank you Company Confidential
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56. Pre-Install Requirements
Carrier gas
Helium, Nitrogen > %, with Moisture and Oxygen filter
Supply pressure 80 psi (5.3 bar)
Detector gases
FID
Hydrogen (>99.999%, 40 psi / 2.6 bar)
Air (moisture & oil free, 60 psi / 4 bar)
Helium (>99.999%, 80 psi / 5.3 bar).
TCD
Helium (>99.999%, 80 psi / 5.3 bar)
Charcoal filters for Helium, Hydrogen and Air are required.
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57. Pre-Install requirements
Compressed Air (Valves)
Minimum supply pressure 60 psi / 4 bar
Connections
1/8” Swagelok.
Gas Filters
P/N
Description
#Required
BRB1024B8
Filter kit for TCD incl. 2 filters (1/8” tube) 1
BRB1040S8
Filter kit for FID incl. 4 filters (1/8” tube)
BRB0010B8
Connecting unit for 1 filter (1/8” tube)
BRF0103
Hydrocarbon filter
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58. Recommended Gas Standards
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