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Refinery Gas Analyzer Solution for Refinery Gas Streams

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1 Refinery Gas Analyzer Solution for Refinery Gas Streams
Company Confidential © 2009 Scion Instruments. All Rights Reserved

2 Refinery Gas Analyzer (RGA)
Product Value Proposition Competitive Positioning Sales Tools How to Order Step by Step & Demonstrated Analysis Company Confidential © 2009 Scion Instruments. All Rights Reserved

3 Refinery Gas Analyzer (RGA)
Company Confidential © 2009 Scion Instruments. All Rights Reserved

4 Analyzer Purpose Product value $$
Points of measurement, Transport Quality Control Impurities, Product suitability Quality for next production step e.g PolyEthylene & PolyPropylene Company Confidential © 2009 Scion Instruments. All Rights Reserved

5 Analyzer Scope Component Analytical Range Precision (%)
C1 up to C5 plus composite of C6+ 0.01*– 100% <1% Carbon dioxide, Ethylene, Ethane, Acetylene, Oxygen, Nitrogen, Methane, Carbon monoxide 0.01 % – 100% Hydrogen sulfide 0.05%* – 100% Hydrogen 0.01% Acid Gas ** YES Possible Refinery Gases / Natural Gas /Reformer Gas Excellent C2/C2= C3/C3= LPG Good Analysis time 25 min Acid GAS? * Lower LOD possible with bigger sample loop: ppm for H2S, 0.5 ppm for C1-C5 Hydrocarbons ** Max 45% H2S Company Confidential © 2009 Scion Instruments. All Rights Reserved

6 Analyzer Scope Programmed for Refinery Streams C1-C5
Widest Analytical Scope: C1-C5 Hydrocarbons Permanent gases (H2, He, O2, N2, CO, CO2). H2S Compliant to Key methods ASTM D1946, D2504, D2163, D2593, D4424, IP 405, ISO 7941, EN27941,DIN 51666, EN 15984, UOP539, GOST 31371 UOP 373 Composition of C2 through C5 Hydrocarbon Mixtures by GC UOP 899 Trace Hydrocarbons in Hydrogen, Hydrocarbon Gases, or LPG by GC. UOP 980 C5 and Lower Boiling Dienes, Olefins, and Paraffins in Naphthas by GC. Company Confidential © 2009 Scion Instruments. All Rights Reserved

7 Permanent gases channel Light Hydrocarbon channel
Configuration Hydrogen channel Permanent gases channel Light Hydrocarbon channel Company Confidential © 2009 Scion Instruments. All Rights Reserved

8 Configuration Hydrogen Channel LDL H2 0.01%
8port valve, Hayesep/Molsieve Packed Columns with Pressure Point Backflush to TCD LDL H % Company Confidential © 2009 Scion Instruments. All Rights Reserved

9 Configuration Permanent Gases channel
10port valve, Hayesep/Molsieve Packed Columns and series/bypass valve on TCD Oxygen, Nitrogen, Methane, Carbon Monoxide, Carbon Dioxide, Ethane, Ethylene, Acetylene and Hydrogen sulfide. LDL Permanent Gases: <0.01% LDL Hydrogen sulfide: <0.05%* * ppm possible with bigger sample loop Company Confidential © 2009 Scion Instruments. All Rights Reserved

10 Configuration Light Hydrocarbons channel
10port valve, Alumina/apolar column, FID All Hydrocarbons up to C6. Pressure Point backflush of C6+ composite LDL 0.01% (<0.5 ppm with bigger sample loop) Company Confidential © 2009 Scion Instruments. All Rights Reserved

11 RGA – Value Proposition
Company Confidential © 2009 Scion Instruments. All Rights Reserved

12 Value Proposition RGA Dedicated Solution Accuracy - Trusted data!
Designed, Built, Tested & Documented to method Flexible 3 channel platform – no side mounted 3rd detectors Accuracy - Trusted data! Proven Results Sample Integrity Solutions Software for automation, calculus, reporting Better ROI / Lower Cost of Ownership Fast cycle times Low maintenance due to superior build quality Compliancy to key Gas Methods: Company Confidential © 2009 Scion Instruments. All Rights Reserved

13 RGA - Options Company Confidential
© 2009 Scion Instruments. All Rights Reserved

14 Sampling Options Pressure Station
Inject Sample as Liquid, no premature evaporation and discrimination Constant P and T for LNG Mounts On top of GC Maximum Pressure: 2500 kPa / 360 psi Requires Inert gas Supply 2500 kPa SAMPLE OUT TO VENT SAMPLE IN Carrier Gas HIGH GAS PRESSURE IN TESCOM REGULATOR RESTRICTION BUMB PR Company Confidential © 2009 Scion Instruments. All Rights Reserved

15 Sampling Options Gasifier Inject sample as Pressure Controlled Gas
Constant Pressure and Temperature Adjustable Temperature (max. 175°C), Maximum sample inlet pressure: 1000 psi / 7000 kPa / 7 bars Integrated in GC Flush vent To GC nv Heated pressure regulator Sample inlet Outlet Pr Company Confidential © 2009 Scion Instruments. All Rights Reserved

16 Sampling Options Liquid Sampling Valve Sampling Valves in Hasteloy C
4-port LSV for LPG samples, unheated 8-port dual LSV for LPG samples, unheated Sampling Valves in Hasteloy C Maximum inertness Company Confidential © 2009 Scion Instruments. All Rights Reserved

17 Sampling Options HT/HP On/Off Valve For samples up to 6000 psi / 300°C
Ideal for liquid or supercritical fluids. Controlled & Automated by GC Mounted directly into Large Valve oven Easy switch between high- & low- pressure samples 1/16” connection, 0.75 mm bore, low int. volume (< 2 µl) Company Confidential © 2009 Scion Instruments. All Rights Reserved

18 Sampling Options Low Pressure Sampling Pump Kit
For samples with low pressures 0-10 Psi Tedlar Bags Controlled & Automated by GC Mounted under top GC cover Automated switching between high- & low-pressure samples Company Confidential © 2009 Scion Instruments. All Rights Reserved

19 Software Options CompassCDS Hydrocarbon Reporting Dry Gas Calculations
Component Mol %, Normalized Component Mol %, GPM (Gallons per 1000 ft3) Fraction Molecular Weight, Specific Gravity, Compressibility Ideal Relative Gas Density, Ideal Gas Density Real Relative Gas Density, Real Gas Density Heating Value kJ.mol-1 (Superior), Heating Value kJ.mol-1(Inferior) Heating Value MJ.kg-1 (Superior), Heating Value MJ.kg-1 (Inferior) Heating Value MJ.m3 (Superior), Heating Value Mj.m3 (Inferior), Gross Heating Value BTU/ft3 (Ideal) Dry Gas Calculations Net Heating Value BTU/ft3 (Real) Dry Gas, Gross Heating Value BTU/ft3 (Ideal) Saturated gas Net Heating Value BTU/ft3 (Real) Saturated gas, GPM C2+, GPM C3+, GPM C4+ Wobbe Index, Research Octane Number (RON) Motor Octane Number (MON), Carbon Number. Company Confidential © 2009 Scion Instruments. All Rights Reserved

20 Software Options Standard Reporting Template
Customizable for Logo & Headers Compound Table Advanced Calculus and Ext. Reporting Company Confidential © 2009 Scion Instruments. All Rights Reserved

21 Software Options Standard Reporting Template
Customizable for Logo & Headers Compound Table Advanced Calculus and Ext. Reporting No Excel required Exclude errors in manual calculus Embedded/automated in Compass (w/o Eclipse) Company Confidential © 2009 Scion Instruments. All Rights Reserved

22 Software Options Eclipse Gas Reporter Customizable for Logo & Headers
Compound Table Advanced Calculus and Ext. Reporting No Excel required Exclude errors in manual calculus Embedded/automated in Compass Company Confidential © 2009 Scion Instruments. All Rights Reserved

23 Software Options Eclipse Gas Reporter Customizable for Logo & Headers
Compound Table Advanced Calculus and Ext. Reporting No Excel required Exclude errors in manual calculus Embedded/automated in Compass Company Confidential © 2009 Scion Instruments. All Rights Reserved

24 Compliancy ASTM D1945, D2163, D2504, D2593, D4424 DIN 51666
IP194, IP405, ISO7941, EN27941, EN15984 UOP373, UOP539 GOST31371 Company Confidential © 2009 Scion Instruments. All Rights Reserved

25 Method Compliance for Refinery Gas Analyzers
Compliance to Method RGA Rapid RGA ASTM D1945 ASTM D1946 ASTM D2163 ASTM D2504 ASTM D2505 ASTM D2593 ASTM 2597 ASTM D2598 (Calculation only) ASTM D4424 ASTM D7833 DIN 51666 DIN 51872 IP 194 (= ASTM D2593) IP 405 (=ISO27941, EN27941) ISO7941 (=ISO27941) EN27941(= ISO7941) EN15984 UOP373 UOP539 UOP603 UOP709 UOP899 GOST 31371 Company Confidential © 2009 Scion Instruments. All Rights Reserved

26 Competitive Positioning
Company Confidential © 2009 Scion Instruments. All Rights Reserved

27 Competitive Landscape
Scion USP: True 3 channel platform, no additional side mounted Detectors. 3 Independent Ovens (LVO, GC oven, SVO (Single, Dual or Triple) Accurate Temp controls  accurate Retention Times Superior Build quality HT/HP sampling Valve (Top mounted!) up to 6000 PSI/300° Simplifies quick switch low/high pressure samples High Quality SS Sample connections standard Low pressure Sampling Option for Tedlar bags GC Language Localization (if applicable for area) Software: CompassCDS with Hydrocarbon Reporting or Eclipse Scalable, C/S, and dedicated for Gas Analysis! Company Confidential © 2009 Scion Instruments. All Rights Reserved

28 RGA vs Rapid RGA Components measured RGA Rapid RGA
C1 up to C5 plus composite of C6+ 0.01 %* – 100% 0.01 % – 100% Carbon dioxide, Ethylene, Ethane, Acetylene, Oxygen, Nitrogen, Methane, Carbon monoxide Hydrogen sulfide 0.05%* – 100% Hydrogen 0.01% Columns Packed Micropacked + Cap. Lower Reporting Limit & Range 100 ppm - 100% Precision (Repeatability % RSD, n=20) <1.0 Analysis Time (minutes) 25 5 (6 with H2S) Sample Scope Acid Gas ** Good Refinery Gases / Natural Gas Excellent C2/C2= C3/C3= LPG * ppm possible with bigger sample loop ** Max 45% H2S Company Confidential © 2009 Scion Instruments. All Rights Reserved

29 Sales Tools Company Confidential
© 2009 Scion Instruments. All Rights Reserved

30 Sales Tools PPT RGA & Rapid RGA App Notes Poster Board
Customer Value How to order Competitive App Notes Poster Board Demonstrated Analysis Hydrocarbons Ebook Company Confidential © 2009 Scion Instruments. All Rights Reserved

31 How to Order Company Confidential
© 2009 Scion Instruments. All Rights Reserved

32 How to Order - System P/N DESCRIPTION 4569939733
Refinery Gas Analyzer, 120V Refinery Gas Analyzer, 230V The Refinery Gas Analyzer is based on the 456-GC with dual independent TCD's, FID and electronic flow control. The Analyzer is suited for all types of refinery gases, including stack gases, flame gases and reformer gases. By using highly advanced columns the analyzer separates all saturated and unsaturated hydrocarbons up to C5 plus the composite of C6+, and all permanent gases, including hydrogen, nitrogen, oxygen, carbon monoxide, carbon dioxide and hydrogen sulfide. A Micro-Gasifier or a liquid sampling valve is optional. Contact the custom solution office for more details . Company Confidential © 2009 Scion Instruments. All Rights Reserved

33 How to Order - Options P/N DESCRIPTION VLACI8UW1-60P Automated, Unheated 8 Port Dual Liquid Sampling Valve for injection of LPG type samples. Factory installed and functionally tested VLA4CI4UW1P Automated, Unheated 4 Port Liquid Sampling Valve for injection of LPG type samples. Single loop valve. Injects into the Hydrogen channel. Factory installed and functionally tested. CP739647 Pressure Station for LPG Samples CP740531 Integrated 456-GC Micro-Gasifier. For all Voltages. Factory installed. Requires a gas injection valve and a Valve oven. CP740021 Sampling Valve Upgrade to Hasteloy C Upgrades 1 valve to Hasteloy C CP740267 Sample path per channel in Inert Steel treated material Includes Inert Steel treated sample loop and sample in/out connections. VLASFVOLHTP High Temp / High Pressure On/Off Valve Max pressure 6,000 psi, max Temp 300°C, 1/16” connection, 0.75 mm bore, 1” stand off Low Pressure Sampling Pump Kit For low pressure samples Company Confidential © 2009 Scion Instruments. All Rights Reserved

34 How to Order - Software P/N DESCRIPTION BR502030
CompassCDS Hydrocarbon Reporting Tool. Includes reporting for GPA/ISO/ASTM methods. Requires CompassCDS Base License Software (BR502002) to already be installed on the computer. Company Confidential © 2009 Scion Instruments. All Rights Reserved

35 How to Order – Spare/Consumables Kits
P/N DESCRIPTION Consumable Kit : RGA Includes all consumables for the system to operate. All columns are included (1 pce each) Spare Kit : RGA Includes typical spare parts for the system (such as valves, ferrules, connections etc) Main system components and/or voltage dependent parts/modules (such as PWA, EFC/DEFC, Inlets and Detectors are not included!). Company Confidential © 2009 Scion Instruments. All Rights Reserved

36 How to Order - Spares P/N DESCRIPTION CP745238
Fuse F-15A/250V, 5x20mm, Glass (24V DC,3AG) BR746381 Fuse transformer 120V F-10A 250V 6.2x32mm BR746382 Fuse transformer 230V F-8A 250V 6.2x32mm Fuse F-15A / 24V (3AG) CP745239 Fuse T- 10A/250V, 5x20mm, Glass HBC (Heaters) CP745240 Fuse T- 15A/250V, 5x20mm, Glass (Column Heater) BR746360 Chassis Fan Column Oven Motor, 120V Column Oven Motor, 230V Vent Door Stepping Motor Column Oven Heater, 120V Column Oven Heater, 230V CP741079 Bulkhead assy NG-EFC 436-GC BR746195 Carriergas inlet manifold 456-GC Carriergas+ Make up Tee connection CP742210 Duo bed Molsieve/Charcoal filter, silver color CP742211 Charcoal filter, gold color FERRULE, 1/16"ID VITON; PK/10 Company Confidential © 2009 Scion Instruments. All Rights Reserved

37 How to Order - Spares P/N DESCRIPTION 550013F
Electronic Detector Flowcontrol, type 13 (DEFC-13), Reference flow only 550014F Electronic Detector Flowcontrol, type 14 (DEFC-14) Reference + Make-up TCD, PWA 4x6-GC (= Electrometer) CP745207 Detector interface board; 436/456-GC TCD HEATER/PROBE ASSEMBLY, 120V 4x6 TCD HEATER/PROBE ASSEMBLY, 230V 4x6 TCD Make up adaptor for DEFC Capillary column nut, 0.9 mm Brass, SWSS100R2 Reducer, 1/8" x 1/16" SST CR213104 FERRULE, Graphite/Vespel, 1/16" to 0.4mm ID, 10/PK, for 0.25 mm ID Columns CR213105 FERRULE, Graphite/Vespel, 1/16" to 0.5mm ID, 10/PK, for 0.32 mm ID Columns CR213108 FERRULE, Graphite/Vespel, 1/16" to 0.8mm ID, 10/PK, for 0.53 mm ID Columns Company Confidential © 2009 Scion Instruments. All Rights Reserved

38 How to Order - Spares P/N DESCRIPTION VLA4C8WE
Automated 8-port Valve, WE, 220 °C, with Air actuator VLSSAC8WE Spare rotor for 8-port valve CP Needle valve VLSL500CUWUM Sample loop 500 µL, Inert Steel VLA4C10WE Automated 10-port Valve, WE, 220 °C, with Air actuator VLA4C6WE Automated 6-port Valve, WE, 220 °C, with Air actuator VLSSAC6WE Spare rotor for 6-port valve VLSSAC10WE Spare rotor for 10-port valve VLSL1KCUWUM Sample loop 1 mL, Inert Steel CP401097 Needle valve, SST, Series/bypass VLSL10CUWUM Sample loop 10 µL, Inert Steel VLZT5 Valco Tee union, 1/32" SST VLFS55 fused silica adaptor 1/32", 0.50mm, 5pk CP738499 Fused silica adaptor 1/32", 0.75mm, 1EA CP742683 Twin hole ferrule 1/8" x mm, 10EA Company Confidential © 2009 Scion Instruments. All Rights Reserved

39 How to Order - Spares P/N DESCRIPTION 550024F
Electronic flow-/Pressure control, Field kit Air solenoid valve for actuator CP Sample solenoid valve, SST, 24Vdc CP4007 Tubing, 1/16" x 0.75mm, SST, per meter CP6535 Tubing, Inert Steel, 1/16"x 0.75mm, per 2 meter! CP86517 Bulkhead union 1/8" x 1/16", Inert Steel CP86518 Bulkhead union 1/16" x 1/32", Inert Steel Company Confidential © 2009 Scion Instruments. All Rights Reserved

40 How to Order - Consumables
P/N DESCRIPTION SC15895 1m X 1/8” X 2.0mm Inert Steel Hayesep Q mesh SC15883 1m X 1/8” X 2.0mm Inert Steel Molsieve 5A mesh SC15894 0.5m X 1/8” Inert Steel Hayesep T mesh SC15885 0.5m X 1/8” Inert Steel Hayesep Q mesh SC15884 1.5m X 1/8” Inert Steel Molsieve 13X mesh SC30101 SCION m x 0.32mm x 1.20um (5" cage) SC35302 SCION-Al2O3/Na2SO4 50m x 0.53mm x 10um SC30083 SCION-Methyl Deact. FS 5m x 0.32mm CP742210 Carrier gas Duo-bed Pencil filter50%Charcoal/50%Molsieve Ferrules included CP742211 Company Confidential © 2009 Scion Instruments. All Rights Reserved

41 Demonstrated Analysis
Company Confidential © 2009 Scion Instruments. All Rights Reserved

42 Step by Step – H2 Channel Company Confidential
© 2009 Scion Instruments. All Rights Reserved

43 Step by Step – H2 Channel - Inject
Company Confidential © 2009 Scion Instruments. All Rights Reserved

44 Step by Step – H2 Channel - Backflush
Company Confidential © 2009 Scion Instruments. All Rights Reserved

45 Step by Step – LHA Channel - Fill
Company Confidential © 2009 Scion Instruments. All Rights Reserved

46 Step by Step – LHA Channel - Inject
Company Confidential © 2009 Scion Instruments. All Rights Reserved

47 Step by Step – LHA Channel - Backflush
Company Confidential © 2009 Scion Instruments. All Rights Reserved

48 Step by Step – Perm. Gases - Fill
Company Confidential © 2009 Scion Instruments. All Rights Reserved

49 Step by Step – Perm. Gases - Inject
Company Confidential © 2009 Scion Instruments. All Rights Reserved

50 Step by Step – Perm. Gases - Backflush
Company Confidential © 2009 Scion Instruments. All Rights Reserved

51 RGA - Hydrogen Channel Peak ID Compound Name 1 Hydrogen
Company Confidential © 2009 Scion Instruments. All Rights Reserved

52 RGA - Permanent Gases Channel
Peak ID Compound Name 1 CO2 2 Ethene 3 Ethane 4 Ethyn 5 Hydrogen Sulfide 6 Oxygen 7 Nitrogen 8 Methane 9 Carbon Monoxide Company Confidential © 2009 Scion Instruments. All Rights Reserved

53 RGA - Light Hydrocarbons Channel
Peak ID Compound Name 1 C6+ 2 Methane 3 Ethane 4 Ethylene 5 Propane 6 Cyclo Propane 7 Propylene 8 i-Butane 9 n-Butane 10 Propadiene 11 Acetylene 12 t-2-Butene 13 1-Butene 14 i-Butene 15 cis-2-Butene 16 i-Pentane 17 n-Pentane 18 1,3-Butadiene 19 Propyne 20 Butyne Company Confidential © 2009 Scion Instruments. All Rights Reserved

54 RGA Sample – NatGas Mix – LHA
Peak ID Compound Name 1 C6+ 2 Methane 3 Ethane 4 Ethylene 5 Propane 6 Cyclo Propane 7 Propylene 8 i-Butane 9 n-Butane 10 Propadiene 11 Acetylene 12 t-2-Butene 13 1-Butene 14 i-Butene 15 cis-2-Butene 16 i-Pentane 17 n-Pentane 18 1,3-Butadiene 19 Propyne 20 Butyne Company Confidential © 2009 Scion Instruments. All Rights Reserved

55 Thank you Company Confidential
© 2009 Scion Instruments. All Rights Reserved

56 Pre-Install Requirements
Carrier gas Helium, Nitrogen > %, with Moisture and Oxygen filter Supply pressure 80 psi (5.3 bar) Detector gases FID Hydrogen (>99.999%, 40 psi / 2.6 bar) Air (moisture & oil free, 60 psi / 4 bar) Helium (>99.999%, 80 psi / 5.3 bar). TCD Helium (>99.999%, 80 psi / 5.3 bar) Charcoal filters for Helium, Hydrogen and Air are required. Company Confidential © 2009 Scion Instruments. All Rights Reserved

57 Pre-Install requirements
Compressed Air (Valves) Minimum supply pressure 60 psi / 4 bar Connections 1/8” Swagelok. Gas Filters P/N Description #Required BRB1024B8 Filter kit for TCD incl. 2 filters (1/8” tube) 1 BRB1040S8 Filter kit for FID incl. 4 filters (1/8” tube) BRB0010B8 Connecting unit for 1 filter (1/8” tube) BRF0103 Hydrocarbon filter Company Confidential © 2009 Scion Instruments. All Rights Reserved

58 Recommended Gas Standards
Company Confidential © 2009 Scion Instruments. All Rights Reserved


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