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ex 12.4) Heat of formation of LiCl (1mole) in 12mole of H2O at 25℃

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Presentation on theme: "ex 12.4) Heat of formation of LiCl (1mole) in 12mole of H2O at 25℃"— Presentation transcript:

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2 ex 12.4) Heat of formation of LiCl (1mole) in 12mole of H2O at 25℃
hydration

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4 ex 12-5) 1.25kg of superheated steam at 132℃ , 1atm feed at 25℃
evaporator 2 kg of 15% LiCl 0.75kg 40% LiCl solution at 132℃ Q=? 2 kg feed at 25℃ 0.3kg LiCl and 1.70kg H2O ⓐ separation 0.30kg LiCl at 25℃ 1.70kg H2O at 25 ℃ ⓓ heating 1.25kg water at 25℃ to 132℃ steam at 1atm ⓑ mixing of 0.30kg LiCl with 0.45kg H2O at 25 ℃ 1.25kg of superheated steam at 132 ℃, 1atm 0.75kg 40% LiCl at 25℃ ⓒHeating to 132℃ 0.75kg 40% LiCl at 132℃

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6 Enthalpy / concentration (Hx) diagram
Enthalpy of pure water Enthalpy of pure H2SO4 Endothermic : ∆H >0 , Q <0 Exothermic : ∆H <0 , Q >0 H H

7 binary solution a binary solution b binary solution adiabatic mixing

8 Solubility limit of NaOH in H2O


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