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Natural Gas Analyzer A Solution for IP 345.

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Presentation on theme: "Natural Gas Analyzer A Solution for IP 345."— Presentation transcript:

1 Natural Gas Analyzer A Solution for IP 345

2 Natural Gas A Product Value Proposition Competitive Positioning
Sales Tools How to Order Step by Step & Demonstrated Analysis

3 Natural Gas A

4 Analyzer Purpose BTU/Calorific Value  Product value $$
Points of measurement Transport Quality Control

5 Analyzer Scope Component Anaytical Range Precision (%)
O2, N2, CO2, CH4 100 ppm – 100% <1% Ethane, Propane, Butane, Iso-butane, Neopentane, Pentane, Iso-pentane C6+ as a composite peak YES H2S NO O2/N2 Separation YES* He/H2 Separation No Max carbon# speciated C6 LPG Yes** DeMethanized NGL Analysis time 30 min * Option; Requires Liquid N2/CO2 oven cooling ** Option; requires additional LSV to be installed

6 Analyzer Scope Compliant to IP345
Reporting acc. ASTM D1945, ISO6974/6976, GOST Designed for analysis up to C9, or C6+ Regroup TCD/FID in series. TCD for permanent gases & C2, FID for C3-C5 HC 3 modes: No O2/N2 separation with C6+ backflush No O2/N2 separation, hydrocarbons up to C9 O2/N2 separation, HC up to C9 (req. N2/CO2 cryo) No He/H2 Separation

7 Configuration

8 NatGas A – Value Proposition

9 Value Proposition NatGas A
Dedicated Solution Designed, Built, Tested & Documented to method Flexible 3 channel platform still allows adding on extra channels Accuracy - Trusted data! Proven Results Sample Integrity Solutions Software for automation, calculus, reporting Better ROI / Lower Cost of Ownership Fast cycle times Low maintenance due to superior build quality Compliancy to Method GPA 2172, ASTM 1945, ISO 6976, GOST-22667

10 Natural Gas A - Options

11 Sampling Options Pressure Station
Inject Sample as Liquid, no premature evaporation and discrimination Constant P and T for LNG Mounts On top of GC Maximum Pressure: 2500 kPa / 360 psi Requires Inert gas Supply max 2500 kPa SAMPLE OUT TO VENT SAMPLE IN Carrier Gas HIGH GAS PRESSURE IN TESCOM REGULATOR RESTRICTION BUMB PR

12 Sampling Options Gasifier Inject sample as Pressure Controlled Gas
Constant Pressure and Temperature Adjustable Temperature (max. 175°C), Maximum sample inlet pressure: 1000 psi / 7000 kPa / 7 bars Integrated in GC Flush vent To GC nv Heated pressure regulator Sample inlet Outlet Pr

13 Sampling Options Liquid Sampling Valve Sampling Valves in Hasteloy C
4-port LSV for LPG samples, unheated Sampling Valves in Hasteloy C Maximum inertness

14 Sampling Options HT/HP On/Off Valve For samples up to 6000 psi / 300°C
Ideal for liquid or supercritical fluids. Controlled & Automated by GC Mounted directly into Large Valve oven Easy switch between high- & low- pressure samples 1/16” connection, 0.75 mm bore, low int. volume (< 2 µl)

15 Sampling Options Low Pressure Sampling Pump Kit
For samples with low pressures 0-10 Psi Tedlar Bags Controlled & Automated by GC Mounted under top GC cover Automated switching between high- & low-pressure samples

16 Software Options CompassCDS Hydrocarbon Reporting Dry Gas Calculations
Component Mol %, Normalized Component Mol %, GPM (Gallons per 1000 ft3) Fraction Molecular Weight, Specific Gravity, Compressibility Ideal Relative Gas Density, Ideal Gas Density Real Relative Gas Density, Real Gas Density Heating Value kJ.mol-1 (Superior), Heating Value kJ.mol-1(Inferior) Heating Value MJ.kg-1 (Superior), Heating Value MJ.kg-1 (Inferior) Heating Value MJ.m3 (Superior), Heating Value Mj.m3 (Inferior), Gross Heating Value BTU/ft3 (Ideal) Dry Gas Calculations Net Heating Value BTU/ft3 (Real) Dry Gas, Gross Heating Value BTU/ft3 (Ideal) Saturated gas Net Heating Value BTU/ft3 (Real) Saturated gas, GPM C2+, GPM C3+, GPM C4+ Wobbe Index, Research Octane Number (RON) Motor Octane Number (MON), Carbon Number.

17 Software Options CompassCDS Hydrocarbon Reporting Plug-in Methods
IS * Natural Gas – Calculation of calorific values, density, relative density and Wobbe index from composition GPA Table of Physical Properties for Hydrocarbons and Other Compounds of Interest to the Natural Gas Industry GPA ** Calculation of Gross Heating Value, Relative Density, Compressibility and Theoretical Hydrocarbon Liquid Content for Natural Gas Mixtures for Custody Transfer GPA ** Tentative Method of Extended Analysis for Natural Gas and Similar Gaseous Mixtures by Temperature Programmed Gas Chromatography GPA ** Method for the Extended Analysis of Hydrocarbon Liquid Mixtures Containing Nitrogen and Carbon Dioxide by Temperature Programmable Gas Chromatography GPA ** Analysis for Natural Gas and Similar Gaseous Mixtures by Gas Chromatography ASTM D Standard Practice for Calculating Heating Value, Compressibility Factor, and Relative Density of Gaseous Fuels * ISO-6976 reporting at combustion & metering Temperatures: 0°/0°, 15°/0°, 25°/0°, 15°/15°, 20°/20° or 25°/20° C kPa ** GPA 2172, 2186, 2286 and 2261 at psia, psia and psia at 60ºF and 76ºF for Dry, with options for Wet and Saturated calculations. ASTM D psia at 60ºF

18 Software Options Standard Reporting Template
Customizable for Logo & Headers Compound Table Advanced Calculus and Ext. Reporting

19 Software Options Standard Reporting Template
Customizable for Logo & Headers Compound Table Advanced Calculus and Ext. Reporting No Excel required Exclude errors in manual calculus Embedded/automated in Compass

20 Other Options Additional channels Channel for He/H2 separation
Inert Sulphur Channel with PFPD (D6228) Inert Sulphur Channel with SCD (D5504) Peak ID Compound Name 1 H2S 2 COS 3 MethylMercaptan

21 Compliancy IP 345 (obsolete 2000), GPA 2172 ASTM D5504* ASTM D6228*
ISO 6976 GOST-22667 * Option; Requires extra channel with SCD or PFPD Detector

22 Other Solutions/Methods for Natural Gas
Components measured Natural Gas A Natural Gas B Natural Gas C Oxygen, Nitrogen, Carbondioxide, Methane Yes Ethane, Propane, Butane, Isobutane, Neopentane, Pentane, Isopentane (all speciated) H2S C6+ (as composite) C7+ (as composite) O2/N2 separation Yes1 He/H2 separation No Yes2 Max Hydrocarbon number speciated C6 C7 C16 Lower Reporting Limit & Range 100 ppm - 100% Precision (Repeatabiity % RSD, n=20) <1.0 Analysis Time (minutes) 30 14 15-205 Sample Scope LPG Yes3 Demethanized Natural Gas / NGL 1 Requires liquid nitrogen or liquid CO2 oven cooling (optional) 2 Requires additional channel for H2/He separation (optional) 3 Requires LSV (optional) 4 Requires Additional Channel with PFPD (optional) 5 20 mins In GPA-2286 Extended mode (app A) 6 Requires Additional Channel with SCD (optional)

23 Other Solutions/Methods for Natural Gas
Compliance to Method Natural Gas A Natural Gas B Natural Gas C IP-345 Method Withdrawn GPA 2165 GPA 2172 Yes GPA 2177 No GPA 2261 GPA 2286 GPA 2186 Yes, except Extended ASTM D1945 ASTM D5504 Yes6 ASTM D6228 Yes4 ISO ISO /2 are universal and only refer to guidelines and calculations of uncertainties. Therefore not applicable to a GC system and Quantification per se. ISO ISO ISO ISO ISO ISO 6975 ISO 6976 GOST-22667 1 Requires liquid nitrogen or liquid CO2 oven cooling (optional) 2 Requires additional channel for H2/He separation (optional) 3 Requires LSV (optional) 4 Requires Additional Channel with PFPD (optional) 5 20 mins In GPA-2286 Extended mode (app A) 6 Requires Additional Channel with SCD (optional)

24 NatGas A – Value Proposition

25 Value Proposition NatGas A
Dedicated Solution Proven Results Designed, Built, Tested & Documented to Purpose. Accuracy Superior Accuracy  most accurate determination of Product Value Best ROI / Lower Cost of Ownership Reliable, low maintenance. Compliant to Method GPA 2261, GPA2165, D1945

26 Competitive Positioning

27 Competitive Landscape
Scion USP: 3 Independent Ovens (LVO, GC oven, SVO (Single, Dual or Triple) More accurate Temp controls, more accurate Retention Times Superior Build quality HT/HP sampling Valve (Top mounted!) up to 6000 PSI/300° Simplifies quick switch low/high pressure samples High Quality SS Sample connections standard Low pressure Sampling Option for Tedlar bags 456: true 3 channel platform, allowing 3rd and 4th (MS) channel GC Language Localization (if applicable for area) Software: CompassCDS with Hydrocarbon Reporting Scalable, C/S, and dedicated for Natural gas!

28 Sales Tools

29 Sales Tools PPT NatGas A, B & C App Notes Poster Board
Customer Value How to order Competitive App Notes Poster Board Demonstrated Analysis Hydrocarbons Ebook

30 How to Order

31 How to Order - System P/N DESCRIPTION 4569973201
Natural Gas Analyzer A, 120V Natural Gas Analyzer A, 230V Based on a 456-GC with TCD/FID in series. The TCD is used for the determination of O2, N2, CH4, CO2, and C2 and C3 hydrocarbons. The FID is automatically switched to determine hydrocarbons in low concentrations, i.e. C4 through C9, either individually or as a backflush group. Three modes of operation are available: separation of air and hydrocarbons with backflush at C6+, separation of O2, N2, and hydrocarbons with backflush at C6+, separation of O2/N2 (requires oven cryo option), and individual hydrocarbons through C9. Electronic flow control is implemented.

32 How to Order – Additional Channel
P/N DESCRIPTION CSA Additional Channels : D6228 w. mini-splitter 120V CSA Additional Channels : D6228 w. mini-splitter 230V CSA Additional Channels : D6228 w. S/SL injector 120V CSA Additional Channels : D6228 w. S/SL injector 230V CSA Additional Channels : D5504 w. minisplitter 120V* CSA Additional Channels : D5504 w. minisplitter 230V* CSA Additional Channels : D5504 w. injector, 120V Additional Channels : D5504 w. injector, 230V Can be added to Natural Gas Analyzer. For LPG type sample streams, an additional cryogenics option will be required. *strictly speaking D5504 requires independent heated inlet, thus not compliant!

33 How to Order - Options P/N DESCRIPTION VLA4CI4UW1P
Automated, Unheated 4 Port Liquid Sampling Valve for injection of LPG type samples. Single loop valve. Factory installed & tested. CP739647 Pressure Station for LPG Samples CP740531 Integrated 456-GC Micro-Gasifier. For all Voltages. Factory installed. Requires a gas injection valve and a Valve oven. Column Oven Cryogenics for 450-GC/456-GC, LCO2, Factory Installed Cools column oven to -65°C. Requires LCO2 cylinder with educator (dip) tube at psig ( bar). Column Oven Cryogenics for 450-GC/456-GC, LN2, Factory Installed Cools column oven to -160°C. Requires LN2 cylinder at psig ( bar). CP740021 Sampling Valve Upgrade to Hasteloy C Upgrades 1 valve to Hasteloy C CP740267 Sample path per channel in Inert Steel treated material Includes Inert Steel treated sample loop and sample in/out connections. VLASFVOLHTP High Temp / High Pressure On/Off Valve Max pressure 6,000 psi, max Temp 300°C, 1/16” connection, 0.75 mm bore, 1” stand off Low Pressure Sampling Pump Kit For low pressure samples

34 How to Order - Software P/N DESCRIPTION BR502030
CompassCDS Hydrocarbon Reporting Tool. Includes reporting for GPA/ISO/ASTM methods. Requires CompassCDS Base License Software (BR502002) to already be installed on the computer.

35 How to Order – Spare/Consumables Kits
P/N DESCRIPTION Consumable Kit : Natural Gas A Includes all consumables for the system to operate. Al columns are included (1 pce each) Spare Kit : Natural Gas A Includes typical spare parts for the system (such as valves, ferrules, connections etc) Main system components and/or voltage dependant parts/modules (such as EFC/DEFC, Inlets and Detectors are not included!).

36 How to Order - Spares P/N DESCRIPTION 4561300401F / 402F
PWOC ON COL. EFC24 120V F / 402F TCD/TRANSF. 2CHAN. DEFC14(NON-H2) 120V 550013F DEFC 13 for 436/456-GC series F / 102F FID DEFC11 120V CP742552UM Insert 1041 for headspace injection, UM CP86517 BHU Valco 1/8"x1/16" Silco steel treated CP72486 Twin retainer 4x6 GC CP821037 WASHER M8 A2 CP742382 SCREW M4X6 I7380 TORX SST-A2 CP6545 TUBING ULTIMETAL UNC. 10X.76 EA/1000CM P SST Solenoid 3/2 way series 065 valve kit (fact.) insta OVEN DUAL HEATED VALVE 120V 456-GC VLA4C8UWEP 8 p.2-pos.vlv Air Act.4"so 225°,FI vlhwsc-pl6-20m Screw, PLMS, 6-32*1 1/4" long, SS.190 modified head VLSL250CUWUM UltiMetal Sample Loop 250ul for CUW vlv CP742806 Air valve actuator kit 1

37 How to Order - Spares P/N DESCRIPTION CP742386
SCREW M4X6 TORX SILVER COATED CP86517 BHU Valco 1/8"x1/16" Silco steel treated SWSS2021 1/8 in SS Nuts, PK/10EA SWSS200SET 1/8" SS SWAGELOK F/B FERRULE SET 10/PK

38 How to Order - Consumables
P/N DESCRIPTION SC15924 12’ X 1/8” Inert Steel Hayesep R mesh SC15918 2’ X 1/8” Inert Steel 1.5% OV-101/Chrom G HP mesh

39 Demonstrated Analysis

40 Step by Step – Fill / Backflush

41 Step by Step - Inject

42 Results FID w. backflush C6+
Peak ID Compound Name 1 Methane 2 Ethane 3 Propane 4 i-Butane 5 n-Butane 6 neoPentane 7 i-Pentane 8 n-Pentane 9 C6+ 10

43 Thank you

44 Pre-Install Requirements
Carrier gas Helium , > %, with Moisture and Oxygen filter Supply pressure 80 psi (5.3 bar) Detector gases FID Hydrogen (>99.999%, 40 psi / 2.6 bar) Air (moisture & oil free, 60 psi / 4 bar) Helium (>99.999%, 80 psi / 5.3 bar). TCD Helium (>99.999%, 80 psi / 5.3 bar) Charcoal filters for Helium, Hydrogen and Air are required.

45 Pre-Install requirements
Compressed Air (Valves) Minimum supply pressure 60 psi / 4 bar Connections 1/8” Swagelok. Gas Filters P/N Description #Required BRB1024B8 Filter kit for TCD incl. 2 filters (1/8” tube) 1 BRB1040S8 Filter kit for FID incl. 4 filters (1/8” tube) BRB0010B8 Connecting unit for 1 filter (1/8” tube) BRF0103 Hydrocarbon filter

46 Recommended Gas Standards


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