1. Natural Gas Analyzer A
Solution for IP 345

2. Natural Gas A Product Value Proposition Competitive Positioning
Sales Tools
How to Order
Step by Step & Demonstrated Analysis

3. Natural Gas A

4. Analyzer Purpose BTU/Calorific Value  Product value $$
Points of measurement
Transport Quality Control

5. Analyzer Scope Component Anaytical Range Precision (%)
O2, N2, CO2, CH4
100 ppm – 100%
<1%
Ethane, Propane, Butane, Iso-butane, Neopentane, Pentane, Iso-pentane
C6+ as a composite peak
YES
H2S NO
O2/N2 Separation
YES*
He/H2 Separation No
Max carbon# speciated C6
LPG
Yes**
DeMethanized NGL
Analysis time
30 min
* Option; Requires Liquid N2/CO2 oven cooling
** Option; requires additional LSV to be installed

6. Analyzer Scope Compliant to IP345
Reporting acc. ASTM D1945, ISO6974/6976, GOST
Designed for analysis up to C9, or C6+ Regroup
TCD/FID in series. TCD for permanent gases & C2, FID for C3-C5 HC
3 modes:
No O2/N2 separation with C6+ backflush
No O2/N2 separation, hydrocarbons up to C9
O2/N2 separation, HC up to C9 (req. N2/CO2 cryo)
No He/H2 Separation

7. Configuration

8. NatGas A – Value Proposition

9. Value Proposition NatGas A
Dedicated Solution
Designed, Built, Tested & Documented to method
Flexible 3 channel platform still allows adding on extra channels
Accuracy - Trusted data!
Proven Results
Sample Integrity Solutions
Software for automation, calculus, reporting
Better ROI / Lower Cost of Ownership
Fast cycle times
Low maintenance due to superior build quality
Compliancy to Method
GPA 2172,
ASTM 1945,
ISO 6976,
GOST-22667

10. Natural Gas A - Options

11. Sampling Options Pressure Station
Inject Sample as Liquid, no premature evaporation and discrimination
Constant P and T for LNG
Mounts On top of GC
Maximum Pressure: 2500 kPa / 360 psi
Requires Inert gas Supply max 2500 kPa
SAMPLE OUT
TO VENT
SAMPLE IN
Carrier
Gas
HIGH GAS
PRESSURE IN
TESCOM
REGULATOR
RESTRICTION
BUMB PR

12. Sampling Options Gasifier Inject sample as Pressure Controlled Gas
Constant Pressure and Temperature
Adjustable Temperature (max. 175°C),
Maximum sample inlet pressure: 1000 psi / 7000 kPa / 7 bars
Integrated in GC
Flush vent
To GC nv
Heated pressure regulator
Sample
inlet
Outlet Pr

13. Sampling Options Liquid Sampling Valve Sampling Valves in Hasteloy C
4-port LSV for LPG samples, unheated
Sampling Valves in Hasteloy C
Maximum inertness

14. Sampling Options HT/HP On/Off Valve For samples up to 6000 psi / 300°C
Ideal for liquid or supercritical fluids.
Controlled & Automated by GC
Mounted directly into Large Valve oven
Easy switch between high- & low- pressure samples
1/16” connection, 0.75 mm bore,
low int. volume (< 2 µl)

15. Sampling Options Low Pressure Sampling Pump Kit
For samples with low pressures
0-10 Psi
Tedlar Bags
Controlled & Automated by GC
Mounted under top GC cover
Automated switching between high- & low-pressure samples

16. Software Options CompassCDS Hydrocarbon Reporting Dry Gas Calculations
Component Mol %,
Normalized Component Mol %,
GPM (Gallons per 1000 ft3)
Fraction Molecular Weight,
Specific Gravity,
Compressibility
Ideal Relative Gas Density, Ideal Gas Density
Real Relative Gas Density, Real Gas Density
Heating Value kJ.mol-1 (Superior), Heating Value kJ.mol-1(Inferior)
Heating Value MJ.kg-1 (Superior), Heating Value MJ.kg-1 (Inferior)
Heating Value MJ.m3 (Superior), Heating Value Mj.m3 (Inferior),
Gross Heating Value BTU/ft3 (Ideal)
Dry Gas Calculations
Net Heating Value BTU/ft3 (Real) Dry Gas,
Gross Heating Value BTU/ft3 (Ideal) Saturated gas
Net Heating Value BTU/ft3 (Real) Saturated gas,
GPM C2+, GPM C3+, GPM C4+
Wobbe Index, Research Octane Number (RON)
Motor Octane Number (MON), Carbon Number.

17. Software Options CompassCDS Hydrocarbon Reporting Plug-in Methods
IS * Natural Gas – Calculation of calorific values, density, relative density and Wobbe index from composition
GPA Table of Physical Properties for Hydrocarbons and Other Compounds of Interest to the Natural Gas Industry
GPA ** Calculation of Gross Heating Value, Relative Density, Compressibility and Theoretical Hydrocarbon Liquid Content for Natural Gas Mixtures for Custody Transfer
GPA ** Tentative Method of Extended Analysis for Natural Gas and Similar Gaseous Mixtures by Temperature Programmed Gas Chromatography
GPA ** Method for the Extended Analysis of Hydrocarbon Liquid Mixtures Containing Nitrogen and Carbon Dioxide by Temperature Programmable Gas Chromatography
GPA ** Analysis for Natural Gas and Similar Gaseous Mixtures by Gas Chromatography
ASTM D Standard Practice for Calculating Heating Value, Compressibility Factor, and Relative Density of Gaseous Fuels
* ISO-6976 reporting at combustion & metering Temperatures: 0°/0°, 15°/0°, 25°/0°, 15°/15°, 20°/20° or 25°/20° C kPa
** GPA 2172, 2186, 2286 and 2261 at psia, psia and psia at 60ºF and 76ºF for Dry, with options for Wet and Saturated calculations. ASTM D psia at 60ºF

18. Software Options Standard Reporting Template
Customizable for Logo & Headers
Compound Table
Advanced Calculus and Ext. Reporting

19. Software Options Standard Reporting Template
Customizable for Logo & Headers
Compound Table
Advanced Calculus and Ext. Reporting
No Excel required
Exclude errors in manual calculus
Embedded/automated in Compass

20. Other Options Additional channels Channel for He/H2 separation
Inert Sulphur Channel with PFPD (D6228)
Inert Sulphur Channel with SCD (D5504)
Peak ID
Compound Name 1
H2S 2
COS 3
MethylMercaptan

21. Compliancy IP 345 (obsolete 2000), GPA 2172 ASTM D5504* ASTM D6228*
ISO 6976
GOST-22667
* Option; Requires extra channel with SCD or PFPD Detector

22. Other Solutions/Methods for Natural Gas
Components measured
Natural Gas A
Natural Gas B
Natural Gas C
Oxygen, Nitrogen, Carbondioxide, Methane
Yes
Ethane, Propane, Butane, Isobutane, Neopentane, Pentane, Isopentane (all speciated)
H2S
C6+ (as composite)
C7+ (as composite)
O2/N2 separation
Yes1
He/H2 separation No
Yes2
Max Hydrocarbon number speciated C6 C7
C16
Lower Reporting Limit & Range
100 ppm - 100%
Precision (Repeatabiity % RSD, n=20)
<1.0
Analysis Time (minutes) 30 14
15-205
Sample Scope
LPG
Yes3
Demethanized Natural Gas / NGL 1
Requires liquid nitrogen or liquid CO2 oven cooling (optional) 2
Requires additional channel for H2/He separation (optional) 3
Requires LSV (optional) 4
Requires Additional Channel with PFPD (optional) 5
20 mins In GPA-2286 Extended mode (app A) 6
Requires Additional Channel with SCD (optional)

23. Other Solutions/Methods for Natural Gas
Compliance to Method
Natural Gas A
Natural Gas B
Natural Gas C
IP-345
Method Withdrawn
GPA 2165
GPA 2172
Yes
GPA 2177 No
GPA 2261
GPA 2286
GPA 2186
Yes, except Extended
ASTM D1945
ASTM D5504
Yes6
ASTM D6228
Yes4
ISO
ISO /2 are universal and only refer to guidelines and calculations of uncertainties. Therefore not applicable to a GC system and Quantification per se.
ISO
ISO
ISO
ISO
ISO
ISO 6975
ISO 6976
GOST-22667 1
Requires liquid nitrogen or liquid CO2 oven cooling (optional) 2
Requires additional channel for H2/He separation (optional) 3
Requires LSV (optional) 4
Requires Additional Channel with PFPD (optional) 5
20 mins In GPA-2286 Extended mode (app A) 6
Requires Additional Channel with SCD (optional)

24. NatGas A – Value Proposition

25. Value Proposition NatGas A
Dedicated Solution
Proven Results
Designed, Built, Tested & Documented to Purpose.
Accuracy
Superior Accuracy  most accurate determination of Product Value
Best ROI / Lower Cost of Ownership
Reliable, low maintenance.
Compliant to Method
GPA 2261, GPA2165, D1945

26. Competitive Positioning

27. Competitive Landscape
Scion USP:
3 Independent Ovens (LVO, GC oven, SVO (Single, Dual or Triple)
More accurate Temp controls, more accurate Retention Times
Superior Build quality
HT/HP sampling Valve (Top mounted!)
up to 6000 PSI/300°
Simplifies quick switch low/high pressure samples
High Quality SS Sample connections standard
Low pressure Sampling Option for Tedlar bags
456: true 3 channel platform, allowing 3rd and 4th (MS) channel
GC Language Localization (if applicable for area)
Software: CompassCDS with Hydrocarbon Reporting
Scalable, C/S, and dedicated for Natural gas!

28. Sales Tools

29. Sales Tools PPT NatGas A, B & C App Notes Poster Board
Customer Value
How to order
Competitive
App Notes
Poster Board
Demonstrated Analysis
Hydrocarbons Ebook

30. How to Order

31. How to Order - System P/N DESCRIPTION 4569973201
Natural Gas Analyzer A, 120V
Natural Gas Analyzer A, 230V
Based on a 456-GC with TCD/FID in series. The TCD is used for the determination of O2, N2, CH4, CO2, and C2 and C3 hydrocarbons. The FID is automatically switched to determine hydrocarbons in low concentrations, i.e. C4 through C9, either individually or as a backflush group. Three modes of operation are available: separation of air and hydrocarbons with backflush at C6+, separation of O2, N2, and hydrocarbons with backflush at C6+, separation of O2/N2 (requires oven cryo option), and individual hydrocarbons through C9. Electronic flow control is implemented.

32. How to Order – Additional Channel
P/N
DESCRIPTION
CSA
Additional Channels : D6228 w. mini-splitter 120V
CSA
Additional Channels : D6228 w. mini-splitter 230V
CSA
Additional Channels : D6228 w. S/SL injector 120V
CSA
Additional Channels : D6228 w. S/SL injector 230V
CSA
Additional Channels : D5504 w. minisplitter 120V*
CSA
Additional Channels : D5504 w. minisplitter 230V*
CSA
Additional Channels : D5504 w. injector, 120V
Additional Channels : D5504 w. injector, 230V
Can be added to Natural Gas Analyzer.
For LPG type sample streams, an additional cryogenics option will be required.
*strictly speaking D5504 requires independent heated inlet, thus not compliant!

33. How to Order - Options P/N DESCRIPTION VLA4CI4UW1P
Automated, Unheated 4 Port Liquid Sampling Valve
for injection of LPG type samples. Single loop valve. Factory installed & tested.
CP739647
Pressure Station for LPG Samples
CP740531
Integrated 456-GC Micro-Gasifier.
For all Voltages. Factory installed. Requires a gas injection valve and a Valve oven.
Column Oven Cryogenics for 450-GC/456-GC, LCO2, Factory Installed Cools column oven to -65°C. Requires LCO2 cylinder with educator (dip) tube at psig ( bar).
Column Oven Cryogenics for 450-GC/456-GC, LN2, Factory Installed Cools column oven to -160°C. Requires LN2 cylinder at psig ( bar).
CP740021
Sampling Valve Upgrade to Hasteloy C
Upgrades 1 valve to Hasteloy C
CP740267
Sample path per channel in Inert Steel treated material Includes Inert Steel treated sample loop and sample in/out connections.
VLASFVOLHTP
High Temp / High Pressure On/Off Valve
Max pressure 6,000 psi, max Temp 300°C, 1/16” connection, 0.75 mm bore, 1” stand off
Low Pressure Sampling Pump Kit
For low pressure samples

34. How to Order - Software P/N DESCRIPTION BR502030
CompassCDS Hydrocarbon Reporting Tool.
Includes reporting for GPA/ISO/ASTM methods.
Requires CompassCDS Base License Software (BR502002) to already be installed on the computer.

35. How to Order – Spare/Consumables Kits
P/N
DESCRIPTION
Consumable Kit : Natural Gas A
Includes all consumables for the system to operate.
Al columns are included (1 pce each)
Spare Kit : Natural Gas A
Includes typical spare parts for the system (such as valves, ferrules, connections etc)
Main system components and/or voltage dependant parts/modules (such as EFC/DEFC, Inlets and Detectors are not included!).

36. How to Order - Spares P/N DESCRIPTION 4561300401F / 402F
PWOC ON COL. EFC24 120V
F / 402F
TCD/TRANSF. 2CHAN. DEFC14(NON-H2) 120V
550013F
DEFC 13 for 436/456-GC series
F / 102F
FID DEFC11 120V
CP742552UM
Insert 1041 for headspace injection, UM
CP86517
BHU Valco 1/8"x1/16" Silco steel treated
CP72486
Twin retainer 4x6 GC
CP821037
WASHER M8 A2
CP742382
SCREW M4X6 I7380 TORX SST-A2
CP6545
TUBING ULTIMETAL UNC. 10X.76 EA/1000CM P
SST Solenoid 3/2 way series 065 valve kit (fact.) insta
OVEN DUAL HEATED VALVE 120V 456-GC
VLA4C8UWEP
8 p.2-pos.vlv Air Act.4"so 225°,FI
vlhwsc-pl6-20m
Screw, PLMS, 6-32*1 1/4" long, SS.190 modified head
VLSL250CUWUM
UltiMetal Sample Loop 250ul for CUW vlv
CP742806
Air valve actuator kit 1

37. How to Order - Spares P/N DESCRIPTION CP742386
SCREW M4X6 TORX SILVER COATED
CP86517
BHU Valco 1/8"x1/16" Silco steel treated
SWSS2021
1/8 in SS Nuts, PK/10EA
SWSS200SET
1/8" SS SWAGELOK F/B FERRULE SET 10/PK

38. How to Order - Consumables
P/N
DESCRIPTION
SC15924
12’ X 1/8” Inert Steel Hayesep R mesh
SC15918
2’ X 1/8” Inert Steel 1.5% OV-101/Chrom G HP mesh

39. Demonstrated Analysis

40. Step by Step – Fill / Backflush

41. Step by Step - Inject

42. Results FID w. backflush C6+
Peak ID
Compound Name 1
Methane 2
Ethane 3
Propane 4
i-Butane 5
n-Butane 6
neoPentane 7
i-Pentane 8
n-Pentane 9
C6+ 10

43. Thank you

44. Pre-Install Requirements
Carrier gas
Helium , > %, with Moisture and Oxygen filter
Supply pressure 80 psi (5.3 bar)
Detector gases
FID
Hydrogen (>99.999%, 40 psi / 2.6 bar)
Air (moisture & oil free, 60 psi / 4 bar)
Helium (>99.999%, 80 psi / 5.3 bar).
TCD
Helium (>99.999%, 80 psi / 5.3 bar)
Charcoal filters for Helium, Hydrogen and Air are required.

45. Pre-Install requirements
Compressed Air (Valves)
Minimum supply pressure 60 psi / 4 bar
Connections
1/8” Swagelok.
Gas Filters
P/N
Description
#Required
BRB1024B8
Filter kit for TCD incl. 2 filters (1/8” tube) 1
BRB1040S8
Filter kit for FID incl. 4 filters (1/8” tube)
BRB0010B8
Connecting unit for 1 filter (1/8” tube)
BRF0103
Hydrocarbon filter

46. Recommended Gas Standards