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Molecular Orbital Theory

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Presentation on theme: "Molecular Orbital Theory"— Presentation transcript:

1 Molecular Orbital Theory
Atomic orbitals mix together and make: Bonding Orbitals Electrons in these orbitals help hold atoms near each other Antibonding Orbitals Electrons in these orbitals push atoms apart from each other Nonbonding Orbitals Electrons in these orbitals have no effect on bonding Molecular Orbitals can: be Sigma or Pi be spread over multiple atoms

2 What is the hybridization on B?
sp sp2 sp3 sp3d sp3d2

3 What is the hybridization on S?
sp sp2 sp3 sp3d sp3d2

4 What is the hybridization on S?
sp sp2 sp3 sp3d sp3d2

5 Molecular Orbital Theory
Molecular Orbitals can: be Sigma or Pi be spread over multiple atoms

6 MO Diagram for H2 H + H  H2

7 Li2 Bond Order: 2 electrons in a bonding orbital = 1 bond
2 electrons in an antibonding orbital = -1 bond

8 H2/He2 Examples

9 H2/He2 Examples

10 H2/He2 Examples

11 What is the bond order of He2+?
0.5 1.0 1.5

12 H2/He2 Examples

13 Homonuclear Diatomics

14 Homonuclear Diatomics

15 Homonuclear Diatomics

16 Homonuclear Diatomics


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