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HELP Balancing Redox Reactions 3 I2 (s) + Al (s)  2 2 AlI

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Presentation on theme: "HELP Balancing Redox Reactions 3 I2 (s) + Al (s)  2 2 AlI"— Presentation transcript:

1 HELP Balancing Redox Reactions 3 I2 (s) + Al (s)  2 2 AlI3 +7 +3 +2
+4 MnO4- + C2O42-  Mn2+ + CO2 MnO C2O42-  Mn CO2 2 2 O2 4 H2O HELP 4 OH-

2 MnO4- + C2O42-  Mn2+ + CO2 1. Break it into two half-reactions MnO4-  Mn2+ C2O42-  CO2 2. Balance redox active species MnO4-  Mn2+ 3. Balance oxygen using H2O MnO4-  Mn2+ + H2O 4

3 +7 +2 MnO4-  Mn2+ 4. Balance hydrogen using H+ 8 H+ + MnO4-  Mn2+ + H2O 4 5. Balance charge using e- 5 e- + MnO4-  Mn2+ + H2O 4 H+ + 8 This is a balanced half-reaction electrons are a ________ reactant MnO4- is _______ electrons gaining MnO4- is being _______ reduced Where do the e- come from?

4 C2O42-  CO2 2. Balance redox active species C2O42-  CO2 2 3. Balance oxygen using H2O C2O42-  CO2 2 4. Balance hydrogen using H+ C2O42-  CO2 2 5. Balance charge using e- C2O42-  CO2 2 + e- 2

5 +3 +4 C2O42-  CO2 2 + e- 2 This is a balanced half-reaction electrons are a ________ product C2O42- is _______ electrons losing C2O42- is being _______ oxidized Now combine the two half-reactions

6 2 ( ) 5 e- + MnO4-  Mn2+ + H2O 4 H+ + 8 5 ( ) 2 + e- C2O42-  CO2 16H+ + 2MnO4- + 5C2O42- 2Mn2+ + 8H2O + 10CO2 stoichiometry additional product, H2O additional reactant, acid

7 Ag+ (aq) + C6H12O6 (aq) Ag (s) + C6H12O7 (aq) Ag+ Ag (s) C6H12O6 C6H12O7

8 Ag+ + C6H12O6  Ag (s) + C6H12O7 Ag+ + e- Ag (s) balance mass balance oxygen H2O balance hydrogen H+ balance charge e-

9 H2O + C6H12O6 C6H12O7 + H+ 2 + e- 2 balance mass balance oxygen H2O balance hydrogen H+ balance charge e-

10 H2O + C6H12O6 C6H12O7 + H+ 2 + e- 2 ( ) 2 Ag+ + e- Ag (s) H2O + C6H12O6 + 2Ag+ C6H12O7 + H+ 2 + 2Ag (s) Ag+ reduced Ag+ oxidizing agent C6H12O6 oxidized C6H12O6 reducing agent C C + 3+

11 H2O + C6H12O6 C6H12O7 + H+ 2 + e- 2 2 ( ) Ag+ + e- Ag (s) H2O + C6H12O6 + 2Ag+ C6H12O7 + H+ 2 + 2Ag (s) 2 OH- 2 OH- H2O 2 This reaction takes place in a basic solution OH- 1 OH- 2 +H2O+ C6H12O6 +2Ag+ C6H12O7 +2Ag (s) H2O +2 OH- 2 + C6H12O6 +2Ag+ C6H12O7 +2Ag (s) H2O +

12 CN-(aq) + MnO4- (aq) CNO- (aq) + MnO2 (s) separate half-reactions CN- CNO- MnO4- MnO2 balance mass CN- CNO- MnO4- MnO2 balance oxygen H2O+ CN- CNO- MnO4- MnO2 + H2O 2

13 H2O+ CN- CNO- MnO4- MnO2 + H2O 2 balance hydrogen CN- CNO- H2O+ + H+ 2 MnO4- MnO2 + H2O 2 + H+ 4 balance charge 3 ( ) CN- CNO- H2O+ + H+ 2 + e- 2 ( ) 2 3 e-+ MnO4- MnO2 + H2O 2 + H+ 4 3 CN- +2 MnO4- + 2 H+ 3 CNO- + 2 MnO2 + H2O

14 3 CN- +2 MnO4- + 2 H+ 3 CNO- + 2 MnO2 + H2O OH- 2 OH- 2 make the solutions basic add OH- 3 CN- + 2 MnO4- + H2O 3 CNO- + 2 MnO2 + 2 OH-


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