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Chapter 7 Light and Color
Copyright ©2019 Cengage Learning. All Rights Reserved. May not be scanned, copied or duplicated, or posted to a publicly accessible website, in whole or in part.
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A New England Fall Trees change from a uniform green into a tapestry of color Why do leaves change color? Molecules within the leaves interact with light The orange color of leaves in the fall is caused by the interaction of light with b-carotene molecules (shown here) in the leaves. Figure is from page 178 2
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Colors within White Light
Sir Isaac Newton separated and recombined white light and its constituent colors Figure 7.1; page 178
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What Causes Color? The color of any object depends on how the molecules or the atoms of the material interact with light Molecules present within an object determine which colors are absorbed and which colors are reflected A substance that appears white reflects all colors of light A substance that appears black absorbs all colors of light
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What Causes Color? (continued)
Figure 7.2; page 178
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Chlorophyll and Carotenes
Chlorophylls are responsible for the green color in a leaf As chlorophylls are destroyed in the fall, the colors red and orange of the carotenes dominate leaf color Top: Figure 7.3; page 178 Bottom: Figure 7.5; page 179
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Light Has no mass Nothing is known to travel faster than light
Top: Figure 7.6; page 180 Bottom: Figure 7.7; page 181
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Light (continued) Has both wave and particle properties
Photons are particles of light Considered as tiny packets of energy traveling at the speed of light Wave properties are embodied in an oscillating wave of electric and magnetic fields
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Wavelength (λ) Distance between wave crests
Determines the color of light Determines how much energy one of its photons carries Has an inverse relationship with energy Equation from graphic on Page 181
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Frequency Represented by the Greek letter
The number of cycles (crests) that pass through a stationary point in one second Unit is 1/s and is called the hertz (Hz) Figure 7-6; page 180
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Frequency (continued)
Has an inverse relationship with wavelength = c/ where is the frequency in units of 1/s, c is the speed of light (3.0×108 m/s), and is the wavelength, usually in meters
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The Electromagnetic Spectrum
Electromagnetic radiation is the general term for all forms of light Visible spectrum extends from 400 nm to 780 nm Figure 7.8; page 182
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Parts of the Electromagnetic Spectrum
Visible light Seen by human eyes Ultraviolet (UV) light Energetic; can break chemical bonds X-rays Discovered by Roentgen More energy than UV light Gamma rays Most energetic Most do not reach Earth Figure 7.9; page 183
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Parts of the Electromagnetic Spectrum (continued)
Infrared (IR) Heat; used in commercial night vision equipment Microwave radiation Efficiently absorbed by water molecules Used in cooking Radio waves Discovered by Hertz; wavelengths as long as football fields Used to transmit communication signals
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Concept Check 7.1 MRI imagers typically use electromagnetic radiation with frequencies of 42.6 MHz (42.6 × 106 Hz). What is the wavelength (λ), and where in the spectrum is the radiation of 42.6 MHz?
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Concept Check 7.1 Solution
Hz units convert to 1/s 1 MHz = 1 × 106 Hz Speed of light (c) = 3.00 × 108 m/s The radiation of 42.6 MHz is found in the radio frequency section of the EM spectrum.
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Excited Electrons What happens within a molecule or atom when it absorbs light? Electrons are excited from lower-energy orbits to higher-energy ones The required energy (photon) must match the energy required to move an electron from one orbit to the next Figure 7.10; page 184
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Energy State Electron configuration of a molecule or atom with electrons in particular orbits Ground state All electrons are in the lowest-energy orbits possible Excited state State in which an atom or molecule is said to be in, when an electron has moved to a higher-energy orbit
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Energy State (continued)
Electronic transition Caused by light The energy of this light determines which transition will occur Some molecules absorb many different wavelengths of light Some absorb one, and some absorb none Depends on the electrons and the energy differences between their orbits
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Excited State The excited state is unstable
Energy of the absorbed photon will dissipate in several ways Photodecomposition Electronic relaxation Phosphorescence Fluorescence Figure 7.11; page 185 20
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