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Chemical Reactions Chapter 11
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Writing chemical equations
To write a word equation: write names of reactants left of the arrow separated by plus signs; write names of products right of the arrow separated by plus signs. Hydrogen + oxygen water
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Skeleton equation Chemical equation that does not indicate amounts of the reactants and products. Not balanced! H2(g) + O2(g) H2O(l) Catalyst is a substance that speeds up the reaction but is not consumed in the reaction. Neither reactant or product and written above the arrow.
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Balancing equations Coefficients: small whole numbers that are placed in front of the formulas in an equation in order to balance it. A balanced equation is where each side of the equation has equal numbers of atoms of each element and mass is conserved.
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Balancing equations First write the skeleton equation
Then use coefficients to balance the equation so that it obeys the law of conservation of mass. Never change subscripts. Simplify if possible
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Chemical reactions The five general types of reactions are:
Combination Decomposition Single-replacement Double-replacement Combustion *Chemical change occurs with all of them!
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Combination Reactions
Two or more substances react to form a single new substance. 2Mg(s) + O2(g) 2MgO(s)
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Decomposition A single reactant forms 2 or more products
2HgO(s) 2Hg(l) + O2(g)
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Single-Replacement Reactions
One element replaces a second element in a compound. Both the reactants and products have a single element and a compound. Activity series: lists metals in order of decreasing reactivity. Page 333 A reactive metal will replace any metal listed below it in the activity series. A reactive halogen will replace any halogen below it.
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Single-replacement reactions
Br2(aq) + NaI(aq) NaBr(aq) + I2(aq) Br2(aq) + NaCl(aq) No reaction
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Double-Replacement Reactions
Exchange of positive ions between two compounds. Aqueous solutions Form a precipitate (solid), a gas, or a molecular compound such as water Na2S(aq) + Cd(NO3)2(aq) CdS(s) + 2NaNO3(aq) 2NaCN(aq) + H2SO4(aq) 2HCN(g) + Na2SO4(aq) Ca(OH)2(aq) + 2HCl(aq) CaCl2(aq) + 2H2O(l)
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Combustion Reaction An element or a compound reacts with oxygen often producing energy in the form of heat and light. Always involves oxygen as a reactant. The other reactant is usually a hydrocarbon (compound composed of carbons and hydrogens). Products are carbon dioxide and water for complete combustion.
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Combustion Reaction 2C8H18(l) + 25O2(g) 16CO2(g) + 18H20(l)
Reactions between oxygen and some elements other than carbon can also be combustion reactions. 2Mg(s) + O2(g) 2MgO(s)
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Predicting the products of a chemical reaction
The number of elements and/or compounds reacting is a good indicator of possible reaction type and thus possible products. Figure on page
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