1. 6.2 Stratospheric Ozone

2. Atmosphere

4. Stratosphere 12-50 km thick
Temperature increases with altitude (gets warmer!)
Horizontal winds (jet stream)
Contains ozone layer

5. Ozone
3 oxygen molecules

6. Ozone – O3 Dynamic equilibria Balance between two ongoing processes
UV radiation passing through the Earth’s upper atmosphere is absorbed by the formation and destruction of ozone.

7. Ozone
UV (ultraviolet) radiation is absorbed during the formation and destruction of ozone into oxygen (O2)

8. Ozone and UV light Allows UVa and UVb through, but blocks UVc waves
Allows UVa and UVb through, but blocks UVc waves
UVa - causes wrinkles
UVb - causes skin cancer
UVc - worst one because of damage to organisms/tissues

9. UV radiation also affects other living organisms
Damage to photosynthetic organisms.
Especially phytoplankton – basis of many aquatic food webs.

10. Beneficial Effects of UV
In animals stimulates the production of Vit D.
Treat psoriasis and vitiligo (skin diseases)
Steriliser, water purifier
Forensics, lighting, lasers

11. Damage to the Ozone

12. CFCs are usually very stable
CFCs are usually very stable. However, in the high stratosphere the UV radiation breaks them down releasing free chlorine atoms (chlorine is very reactive)

13. HOGS (Halogenated Organic Gases)
HOG’s are usually stable but break down into halogen atoms (F, Cl, Br, I, At) which are highly reactive
Ex. (CFC = chlorofluorocarbon
Cl and F are halogens
Organic = contains carbon

14. Depletion of Ozone

15. Damage to the ozone ODS (Ozone-depleting substance) Substance
Use/source
Notes
Chlorofluorocarbons (CFCs or freons)
Hydrochlorofluorocarbon (HCFCs)
Halons
Methyl bromide
Nitrogen Oxides (NO, NO2, N2O, NOx)

16. Sources of CFC’s
fire extinguishers, refrigerators, AC units

17. Sources of CFC’s
fire extinguishers, refrigerators, AC units

18. Pollution Management Strategies

19. Reducing ODS
Apply the “Replace, regulate and restore” model of pollution management to ODS.
Strategy
Example of action
Altering the human activity producing pollution (replace).
Regulate and reduce the pollutants at the point of emission.
Clean up and restoration

20. Pollution Management of CFC’s and HOGS
Reduce-Regulate-Restore model
Reduce:
Replace CFC’s with CO2, propane, or air
Replace aerosol propellants
Replace methylbromide pesticides with something other than GHG’s
Don’t use aerosol hair products or deodorant

21. Pollution Management of CFC’s and HOGS
Regulate:
Require a switch to HCFC’s because they don’t persist as long in the atmosphere;
(They are still harmful to the ozone layer…just less so)
Create laws to require refrigerators returned to manufacturers to recover harmful materials inside
Capture CFC’s from scrap cars AC units

22. Pollution Management of CFC’s and HOGS
Restore:
Remove chlorine from the stratosphere or add ozone (not exactly feasible!)
Ozone layer is slowly replenishing itself as long as we continue the ban

23. National and International Organizations

24. National and International Organizations
UNEP (United Nations Environmental Programme)
Montreal Protocol 1987

25. National and International Organizations
UNEP (United Nations Environmental Programme)
Key role in:
Providing information
Creating and evaluating international agreements
Protection of stratospheric ozone

26. National and International Organizations
Montreal Protocol 1987
International agreements on the reduction of ODS use.
National laws and regulations aimed at reducing consumption of ODS (CFCs in particular)

27. The Montreal Protocol 1987
This protocol is very significant for a number of reasons:
Best example of international cooperation on an environmental issue.
An example of the precautionary principle in science-based decision making.
Experts from many different fields coming together to research a problem and find solutions.
The first to recognise that different countries could phase-out ODS chemicals at different times depending on their economic status.
The first with regulations that were carefully monitored.
Precautionary principle - in environmental matters, the theory that if the effects of a product or action are unknown, then the product should not be used or the action should not be taken

28. Hair Bands Ruined the Ozone
Poison 1983…
so much hairspray