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The Nature of Acid-Base Equilibria

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1 The Nature of Acid-Base Equilibria
Section 8.1 The Nature of Acid-Base Equilibria

2 Brønsted-Lowry Acids/Bases
A Brønsted-Lowry acid is any compound which can donate a proton (H+). A Brønsted-Lowry base is a cmpd that accepts a proton. HCl is the acid b/c it donates the H+ H2O is the base b/c it accepts the H+

3 BLA, BLB, CA, BB A pair of compounds or ions that differ by the presence of one proton (H+). In every reaction that involves and acid or a base, there is a conjugate acid-base pair. Label the BL acid, BL base, the conjugate acid and the conjugate base

4 Some Specifics… A substance is classified as a Brønsted-Lowry acid or base only for a specific reaction. Some substances are amphoteric (or ambiprotic) which means they can act as either a Brønsted-Lowry acid or base depending on the reaction.

5 If the acid/base is Strong (ionizes 100%), the equilibrium lies entirely to the right.
However, if the acid/base is a Weak (ionizes < 100%), the equilibrium is dependent on the acid/base equilibrium constant: Ka or Kb

6 Ka Expression

7 Kb Expression

8 Auto Ionization of Water
All samples of water contain an equilibrium mixture of water and its ions. The ion product constant for water (Kw)

9 The acid equilibrium constant and the base equilibrium constant for a conjugate acid and a conjugate base can be related. Therefore, if you know the Ka for a weak acid (HA), you can calculate the Kb for its conjugate base (A-).

10 Some More Details… The stronger an acid, the weaker its conjugate base
And, conversely The weaker the acid the stronger its conjugate base

11 Seatwork Pg. 532 #1-3 Pg. 549 #1, 3


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