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Chapter 16: Ethers, Epoxides, and Sulfides

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Presentation on theme: "Chapter 16: Ethers, Epoxides, and Sulfides"— Presentation transcript:

1 Chapter 16: Ethers, Epoxides, and Sulfides

2 16.1 – Nomenclature of Ethers, Epoxides, and Sulfides

3 16.2 – Structure and Bonding on Ethers and Epoxides
Oxirane (ethylene oxide)

4 Natural products containing ethers
Brevetoxin B

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7 16.3 – Physical Properties of Ethers

8 16.4 – Crown Ethers

9 16.4 – Crown Ethers

10 16.5 – Preparation of Ethers
Earlier chapters:

11 16.6 – The Williamson Ether Synthesis
Old lab experiment:

12 16.7-16.8 – Acid-catalyzed Cleavage of Ethers
Symmetrical: nonsymmetrical:

13 16.9-16.10 – Preparation of Epoxides – Review
Epoxidation: From bromohydrins:

14 16.11-16.12 – Reactions of Epoxides with Nucleophiles

15 16.13 – Acid-catalyzed Ring Opening of Epoxides

16 16.14 – Epoxides in Biological Processes

17 16.15 – Preparation of Sulfides
Acid-base reaction followed by SN2

18 Not covering and 16.17

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