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Isoelectronic Species and Effective Nuclear Charge

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Presentation on theme: "Isoelectronic Species and Effective Nuclear Charge"— Presentation transcript:

1 Isoelectronic Species and Effective Nuclear Charge

2 Isoelectronic Ions Have the same number of electrons
Na+ has 11 protons, a nuclear charge of +11. F- has 9 protons, a nuclear charge of +9. Na+ has a smaller ionic radius than F- Isoelectronic Ions Number of electrons Na+, F- 10 e- S2-, Cl-, K+, Ca2+ 18 e-

3 Isoelectronic Ions S2- has 16 protons, a nuclear charge of +16.
Number of electrons Na+, F- 10 e- S2-, Cl-, K+, Ca2+ 18 e- S2- has 16 protons, a nuclear charge of +16. Cl- has 17 protons, a nuclear charge of +17. K+ has 19 protons, a nuclear charge of +19. Ca+2 has 20 protons, a nuclear charge of +20. Ca+2 < K+ < Cl- < S2- (smallest)                    (largest)

4 Isoelectronic Ions For isoelectronic ions, the radius decreases as the positive nuclear charge increases.


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