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Flashcards for Ionic & Metallic Bonding
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What particle is transferred in ionic bonding?
Electron What particle is transferred in ionic bonding?
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How do you identify an ionic formula?
Metal + Nonmetal How do you identify an ionic formula?
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How do you identify a covalent formula?
All Nonmetals How do you identify a covalent formula?
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What do metals do in ionic bonding?
Metals lose electrons & form positive ions. What do metals do in ionic bonding?
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What is a positive ion called?
A cation What is a positive ion called?
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What do nonmetals do in ionic bonding?
Nonmetals gain electrons & form negative ions. What do nonmetals do in ionic bonding?
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What is a negative ion called?
An anion What is a negative ion called?
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Lewis structures of ionic substances
Show all positive ions & all negative ions. Use square brackets to enclose symbol of each ion & put charge outside Lewis structures of ionic substances
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Atoms form ions to achieve the noble gas configuration of the nearest noble gas
Ion formation
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Ion formation Group I metals always form ions with a +1 charge.
Group II metals always form ions with a +2 charge. Transition metals may form more than one kind of positive ion.
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Nonmetal Ions Nonmetals form negative ions in ionic compounds.
The positive oxidation states for the nonmetals are used in covalent compounds.
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+1 ions Group 1 metals form …
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+2 ions Group 2 metals form …
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-1 ions Group 17 nonmetals form …
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They don’t form ions. There the noble gases!
Group 18 nonmetals form …
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-2 ions Group 16 nonmetals form …
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Lewis Dot Structures for Ionic Compounds
Have square brackets and charges. Charges add up to 0. Positive ion has no dots. Negative ion has 8 dots. Lewis Dot Structures for Ionic Compounds
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Lewis diagram of sodium chloride
[Na]+1[:Cl:]-1 : : Lewis diagram of sodium chloride
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Lewis diagram of calcium chloride
: : [Ca]+2[:Cl:]-1[:Cl:]-1 : : Lewis diagram of calcium chloride
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Lewis diagram of aluminum chloride
: : : : [Al]+3[:Cl:]-1[:Cl:]-1 [:Cl:]-1 : : Lewis diagram of aluminum chloride
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Lewis diagram of aluminum sulfide
: : : : [Al]+3[:S:]-2[:S:]-2[:S:]-2[Al]+3 : : Lewis diagram of aluminum sulfide
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Na+1(g) + Cl-1(g) NaCl(s)
Change in energy when one mole of a crystalline ionic compound is formed from its gas phase ions. Na+1(g) + Cl-1(g) NaCl(s) Lattice Energy
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Formation of ionic compounds
Is very exothermic! Formation of ionic compounds
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To get the same electron configuration as the nearest noble gas.
Why do atoms form bonds?
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Force of attraction that holds 2 atoms together.
What is a chemical bond?
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What are the properties of ionic compounds?
Hard, brittle High melting point, high boiling point Low vapor pressure Poor conductors of heat Solids do not conduct electricity at all Melts & solutions do conduct a current Ions in solution react quickly What are the properties of ionic compounds?
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What is the structure of ionic compounds?
Crystal lattice: lattice points are positive & negative ions. What is the structure of ionic compounds?
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Subscripts in chemical formula have smallest whole number ratio
Empirical Formula
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Ionic compounds only have empirical formulas.
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Symbols & Subscripts Formulas
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Subscripts in chemical formulas
Microscopic scale – give atomic ratios Macroscopic scale – give mole ratios Subscripts in chemical formulas
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Regular, repeating pattern in 3 dimensions.
Crystal lattice
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Compounds are electrically …
Neutral. Compounds are electrically …
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Gives exact composition of molecule.
Molecular Formula
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Contains 2 elements Binary Ionic Compound
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What are the properties of metals?
Luster Good conductors of heat & electricity Malleable & ductile Low ionization energy & low electronegativity High mp, high bp & low vapor pressure What are the properties of metals?
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What is the structure of metals.
Crystal lattice: all lattice points are positive ions. What is the structure of metals.
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Delocalized electrons
Valence electrons in metals are free to roam throughout the metal. Delocalized electrons
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Sea of mobile electrons
Phrase used to describe valence electrons in metallic bonding. Sea of mobile electrons
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