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Ionic Compounds
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by kind permission of Nick Kim.
by kind permission of Nick Kim. Na+
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Valence Electron Facts
the electrons involved in bonding The # of valence electrons is the same as the group number for the atom (1A, 2A, etc)
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Valence Electrons and Metals
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Electron Configuration & Lewis Dot Structures of Metals
Symbol Atomic No e config Lewis dot H s1 H Li s2 2s1 Li Be s2 2s2 Be B s2 2s2 2p1 B
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Naming Positive Ions The name of the cation is the same as the name of the element plus the term ion magnesium magnesium ion lithium lithium ion
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Negative Ions the electrons involved in bonding
The # of valence electrons is the same as the group number for the atom (5A, 6A, etc)
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Valence Electron and Nonmetals
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Electron Configuration & Lewis Dot Structure of Nonmetals
Symbol Atomic No e config Lewis dot N s2 2s2 2p3 N O s2 2s2 2p4 O F s2 2s2 2p5 F
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Naming Negative Ions The name of the anion uses the root of the element and the ending -ide plus ion oxygen ox ide ion fluorine fluor ide ion
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Ionic Bonding
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Ionic Bonding – the strong vs the weak
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Ionic Bonding – e config style
Na 3p 3p 3s 3s 2p 2p 2s 2s Na Cl 1s 1s
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Ionic Bonding – Lewis dot style
Na + Cl Na+ Cl-
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Ionic Bonding – e config style
Na 3p 3p 3s 3s 2p 2p 2s 2s Mg Cl 1s 1s
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Ionic Bonding – Lewis dot style
Mg + _Cl Mg+2 + Cl-_
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More Ionic Bonding and Lewis dot practice
_K + _Cl _Ca + _ Cl _Ba + _F _Na + _O
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Multivalent Ions Metal Ions with more than one charge
Metal Ions with More than One Ionic Charge - (Inner Transition and Metalloids) Symbol Stock Name Classical Name Cr+2 chromium (II) ion chromous ion Cr+3 chromium (III) ion chromic ion Mn+2 manganese (II) ion manganous ion Mn+3 manganese (III) ion manganic ion Fe+2 iron (II) ion ferrous ion Fe+3 iron (III) ion ferric ion Co+2 cobalt (II) ion cobaltous ion Co+3 cobalt (III) ion cobaltic ion Cu+1 copper (I) ion cuprous ion Cu+2 copper (II) ion cupric ion Hg+1 mercury (I) ion mercurus ion Hg+2 mercury (II) ion mercuric ion Sn+2 tin (II) ion stannous ion Sn+4 tin (IV) ion stannic ion Pb+2 lead (II) ion plumbous ion Pb+4 lead (IV) ion plumbic ion
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Practice Naming Simple Ions
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Polyatomic Ions Collections of tightly bound atoms that behave as a unit and carry a charge examples SO3-2 sulfite ion SO4-2 sulfate ion NO2 -2 nitrite ion NO3-1 nitrate ion ClO2-1 chlorite ion ClO3-1 chlorate ion
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Complicated Ions Polyatomic Ions Formula Name H2PO4-1
dihydrogen phosphate ion PO3-3 phosphite ion PO4-3 phosphate ion C2H3O2-1 acetate ion HSO3-3 hydrogen sulfite ion HSO4-4 hydrogen sulfate ion HCO3-1 hydrogen carbonate ion NO2-1 nitrite ion NO3-1 nitrate ion CN-1 cyanide ion OH-1 hydroxide ion MnO4-1 permanganate ion ClO-1 hypochlorite ion ClO2-1 chlorite ion ClO3-1 chlorate ion ClO4-1 perchlorate ion HPO4-2 hydrogen phosphate ion C2O4-2 oxalate ion SO3-2 sulfite ion SO4-2 sulfate ion CO3-2 carbonate ion CrO4-2 chromate ion Cr2O7-2 dichromate ion SiO3-2 silicate ion IO2-1 iodite ion NH4+1 ammonium ion Complicated Ions Polyatomic Ions
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Practice Naming Polyatomic Ions and Acids
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Ionic Compounds composed of cations and anions electrically neutral
total + charge = total – charge Strong vs weak forces (electronegativity) formula units usua lly solid at room temperature have high melting points conduct electricity
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