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Determination of Cu in Brass
By: Nayan Patel
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Molarity of Na2S2O3 Sample Calculation Mass of Na2S2O3 5H2O = 25 grams
Mass of KIO3= g Volume of KIO3 =50 ml Volume of Na2S2O3 Titrated = ml O.6978 g KIO3 * (1 mol KIO3) * (1000ml) * (50ml) = e-4 mol KIO3 ( g) (250ml) (1000ml) Molarity of KIO3 e-4 mol KIO3 = mol/L 0.050 L
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Molarity of Na2S2O3 Determine Moles of S2O32-
e-4 mol KIO3 * (3 mol I3-) * (2 mol S2O32-) = mol S2O32- 1 mol IO mol I3- Trial 1 mol S2O32- = mol/L S2O32- 0.038 L Trial 2 mol S2O32- = mol/L S2O32- L Trial 3 mol S2O32- = mol/L S2O32- L
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Average, Standard Deviation and Relative Standard Deviation
Average= ( )/3 = mol/L S2O32- Standard Deviation Formula S.D.= ((( )2+( )2+( )2/(3-1)))^(1/2) S.D= R.S.D. = (0.0018/.1046)*100 =1.721%
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Moles of Na2S2O3 (Molarity of Na2S2O3 )(Volume Titrated)= Moles Na2S2O3 Moles of Na2S2O3 = moles Cu 2 Moles of Na2S2O3 = 1 mole I3- Find moles of Na2S2O3 Moles of Cu Moles I3- Grams of Cu
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Calculations ( mol/L of Na2S2O3)(.03530L) = mol S2O3 2- mol S2O3 2- = mol Cu mol Cu * ( grams Cu) = g Cu 1 mol Cu mol S2O3 2- * (1 mole I3-) = mol I mol S2O3 Do This For Each Trial and Find mass of Cu in grams
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Wt/Wt % Cu from Sample Trial 1 0.24202g Cu * 100 =79.638 %=79.6%
79.364%= 79.4% Trial 3 78.349%= 78.3% Average= =79.117%=79.1% 3 S.D. = = +0.7
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Question? Given 0.00184619 moles I3-. Find grams of Cu? ANSWER
moles I3- * (2 moles S2O3 2-) = moles S2O32- 1 mol I3- moles S2O32- = moles of Cu* ( g/mol) = grams Cu
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ANY QUESTIONS???? PLEASE READ THE LABEL ON THE BOTTLE
Susan was in chemistry. Susan is no more, for what she thought was H2O was H2SO4. Q: Why do chemists call helium, curium and barium the medical elements? A: Because if you can't helium or curium, you barium!
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