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Acids, Bases & Salts
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Naming Acids Binary acids Ternary acids
Hydro(first syllable of element)ic acid Ternary acids Replace PAI suffix –ate with –ic Replace PAI suffix –ite with –ous
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Name that Acid HF HBr HNO3 H2SO4 H3PO4 CH3COOH
We will work mainly with the –ic acids, but you should know that the others exist.
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Definitions of Acids Brønsted-Lowry Acids Arrhenius Acids
Ionize to form H+ in water Brønsted-Lowry Acids Proton donor HCl + H2O H3O+ (aq) + Cl- (aq)
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? water hydrogen ion “proton” hydronium ion
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Ionization of Acids H3PO4 + H2O 3 3H3O+(aq) + PO4-3(aq)
CH3COOH + H2O H3O+(aq) + CH3COO-(aq) H3PO4 + H2O H3O+(aq) + PO4-3(aq) 1 H+ = Monoprotic 2 H+ = Diprotic 3 H+ = Triprotic
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H2CO3 KH CH3OH KI Acid? Yes or No An Acid must ionize
with H+ as the only positive ion in soln H2CO3 KH CH3OH KI
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Acids are electrolytes
…because they ionize in water The more ions, the stronger the electrolyte Strong acids completely ionize Form lots of ions Weaker acids do not
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Acid dissociation constant
Ka Acid dissociation constant Stronger acids larger Ka
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. . . Other Acid Characteristics
Acids change the colors of indicators blue litmus changes to red pH < 7 can be neutralized by bases Dilute acids taste sour
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Characteristics of Bases
Arrhenius Base Defined as a substance that provides OH- ions to solution BrØnsted-Lowry Base proton acceptor Ex: NH3 + H2O NH4+ + OH-
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all bases end in hydroxide
Naming Bases Name the ca+ion all bases end in hydroxide KOH Mg(OH)2 NH4OH Exception?
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NaOH Na+ + OH - NH4OH NH4+ + OH - Base ionization Metal ion
Group 1 hydroxides are your strongest bases. Polyatomic Ion NH4OH NH4+ + OH -
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Change the colors of indicators
Bases never contain carbon Feel Slippery ex. soap Taste bitter Change the colors of indicators Phenolphthalein Red litmus turns blue pH > 7 can be neutralized by acids
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THE END
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