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Chap 23 Optical properties of metals and inelastic scattering

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1 Chap 23 Optical properties of metals and inelastic scattering
Propagation of EM wave Plasma wave Optical properties Angle resolved photo-emission M.C. Chang Dept of Phys

2 Attenuation of EM wave (I)
Attenuation of plane wave due to nI Reflectivity (or reflectance, normal direction)

3 Attenuation of EM wave (II)
Decay of intensity (energy density) Penetration depth Power loss (per unit volume) dielectric function for metal

4 (A) Low frequency (Hagen-Ruben’s) regime
ωτ<<1 τ ~10-13~10-14 ∴ω can be as large as 100 GHz (H.W.) Plasma edge transparent Dressel and Gruener, p.99, 308

5 Longitudinal EM wave (plasma)
ωτ >>1 EM wave is damped Signal blocked Longitudinal EM wave (plasma) Plasma edge EM wave propagates with phase velocity

6 Plasma wave Al For copper, n=81022 /cm3
ωp=1.6×1016/s, λp=1200A (ultraviolet) A simple picture of plasma oscillation: εcore correction 10.3 eV surface plasmon 15.3 eV bulk plasmon Al

7 Dynamic susceptibility (long wavelength limit)
(chap 20) For longitudinal EM wave → Energy dispersion for the plasma wave 2D: for long wavelength There is NO plasma gap Collective excitation vs quasiparticle (e-h pair) excitation in metal plasma excitation decays into pair excitations e-h continuum

8 Optical properties of alkali metals
Reσ for Na, K, and Rb 0.64 εF Drude peak Fermi energy Na: 3.24 eV K: 2.12 eV Rb:1.85 eV T. Inagaki et al , Phys. Rev. B 13, 5610 (1976). N.V. Smith PRB n=(ε0+4πiσ/ω)1/2 Absorption ~ Im(n) ~ Re(σ)

9 Tremblay A.M.- N-corps, p.114

10 Optical properties of noble metals
Cu: low threshold (2 eV, orange) d →s copper s →s Ag: high threshold (4 eV, ultraviolet) s →s d →s d→s d →s Empty lattice


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