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Crystallography H. K. D. H. Bhadeshia Introduction and point groups
Stereographic projections Low symmetry systems Space groups Deformation and texture Interfaces, orientation relationships Martensitic transformations
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Introduction
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Form
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Anisotropy Ag Mo
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Polycrystals
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The Lattice
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Centre of symmetry and inversion
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Bravais Lattices Triclinic P Monoclinic P & C Orthorhombic P, C, I & F
Tetragonal P & I Hexagonal Trigonal P Cubic P, F & I
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Bravais Lattices
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2D lattices
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Crystal Structure 1/2 1/2 1/2 1/2
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lattice + motif = structure
primitive cubic lattice motif = Cu at 0,0,0 Zn at 1/2, 1/2, 1/2
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Lattice: face-centred cubic Motif: C at 0,0,0 C at 1/4,1/4,1/4
3/4 1/4 3/4 1/4 3/4 1/4 3/4 1/4 Lattice: face-centred cubic Motif: C at 0,0,0 C at 1/4,1/4,1/4
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3/4 1/4 1/4 3/4
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Lattice: face-centred cubic Motif: Zn at 0,0,0 S at 1/4,1/4,1/4
3/4 1/4 1/4 3/4 Lattice: face-centred cubic Motif: Zn at 0,0,0 S at 1/4,1/4,1/4
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fluorite
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Point groups 2m
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Water and sulphur tetrafluoride have same point symmetry and hence same number of vibration modes - similar spectra
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Gypsum 2/m
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Epsomite 222
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2/m
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mm2
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4/m mm or 4/mmm
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If a direction [uvw] lies in a plane (hkl) then uh+vk+wl = 0
Weiss Law If a direction [uvw] lies in a plane (hkl) then uh+vk+wl = 0 [uvw] (hkl)
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[110] (110) x y z y x z
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