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Behavior of Gases Byeong-Joo Lee Thermodynamics POSTECH - MSE

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Presentation on theme: "Behavior of Gases Byeong-Joo Lee Thermodynamics POSTECH - MSE"— Presentation transcript:

1 Behavior of Gases Byeong-Joo Lee Thermodynamics POSTECH - MSE

2 Equation of State - Real Gases
as p → 0 ▷ Critical Point

3 Equation of State - Real Gases: Compressibility factor Z
@ 0 oC

4 Law of Corresponding States
Reduced variables

5 van der Waals Gas - Basic Concept
The particles of a real gas occupy a finite volume The particles of a real gas have mutual interactions

6 van der Waals Gas Prove that the van der Waals gases follow the law of corresponding states

7 van der Waals constants for real gases

8 Isothermal behavior of van der Waals gases

9 van der Waals behavior - example: CO2

10 ※ Other EOS: Virial Equation
van der Waals behavior - Heat of Evaporation ※ Other EOS: Virial Equation


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