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Avogadro’s number and the Mole

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1 Avogadro’s number and the Mole
6,020,000,000,000,000,000,000,000 uses for a mole

2 What is a Mole? A Mole is a burrowing rodent
A mole is a blemish on the skin - sometimes dangerous! A Mole is a VERY large number of atoms or molecules

3 How much does an atom weigh?
The mass of a single atom is way too small to determine by weighing The relative atomic mass ma given in the periodic table gives us a comparison of the average masses of different atom types This allows us to compare the number of atoms in a given mass of substance There are as many atoms in 1 gram of hydrogen as there are in 12 grams of carbon

4 } Nucleons Atomic mass Proton Neutron Electron Hydrogen Helium Carbon

5 How many atoms? So if we know 1 gram of hydrogen contains the exact same amount of atoms as 12 grams of carbon, we would only have to go through the effort to count them out once The number of atoms in one gram of hydrogen, or 12 grams of carbon, was determined by Amadeo Avogadro

6 Avogadro’s Number The number of atoms in one gram of hydrogen is:
This number is known as the Avogadro constant (symbol NA) This is quite tedious to write, which is why the scientific notation is often used: 6,02 x 1023 Amadeo Avogadro

7 What does the mole say? Because Avogadro‘s number is quite tedious to even say, chemists use the equivalent term mole (dt. Mol) to express amounts of atoms or molecules Using a word to express a specific number of things is not that uncommon by the way! Examples A dozen = 12 A baker‘s dozen = 13 Une grosse (fr.) = 12x12 = 144 [daher dt. en gros] A mole = 6,02 x 1023

8 Just to get an idea… There are roughly ants on earth (10 x 1015). How many moles (6,02 x 1023) of ants is that? How many molecules are there in 2 moles of water?

9 Amounts of substance A substance amount (dt. Stoffmenge) is usually given in multiples of moles To convert a number of atoms to a substance amount, it is divided by NA The symbol for the substance amount is n, its unit mol

10 Molar mass By definition, the atomic masses in the periodic table are exactly equal to the mass of one mole (= molar mass, dt. molare Masse) of any given atom type The symbol for the molar mass of an atom or molecule is M, its unit 𝑔 𝑚𝑜𝑙 Since we combine atoms into molecules, the molar mass of any molecule is the sum of its molar masses! relative atomic mass ma (in u) molar mass M (in 𝑔 𝑚𝑜𝑙 )

11 Molar mass The molar mass of water (H2O) is M (H2O) = 2 x M(H) + M(O)
= 18 𝑔 𝑚𝑜𝑙 Determine the molar mass M for oxygen (O2), methane (CH4) and chloroform (CHCl3) By the way: When doing calculations with molar masses, it‘s enough to only use the first decimal BONUS: How many units (u) are there to a gram (g)?

12 Molar concentrations Molar concentrations tell us how many moles of a substance are dissolved in 1 liter of a solution The symbol for the molar concentration is c, it‘s unit 𝑚𝑜𝑙 𝑙 Since the volume of a dilute solution barely changes when the substance is dissolved, we can calculate the concentration of a solution we make in advance

13 Molar concentration The molar mass of NaOH is 40 𝑔 𝑚𝑜𝑙
If 40 g of NaOH are dissolved in 1 litre of solution, the concentration of the resulting solution is c = 1 𝑚𝑜𝑙 𝑙 Determine the concentration of 1 litre of solution containing 117 g of sodium chloride (NaCl) Determine the mass of sodium hydroxide (NaOH) in 500 ml of a solution with c = 4 𝑚𝑜𝑙 𝑙

14 Tasks Work through the rests of the tasks on worksheet 19

15 EXTENSION: What is the molarity of water?
Water is H2O, water has a molar mass of 18 𝑔 𝑚𝑜𝑙 There are 1,000 g of water in a liter How many moles of water are there in one liter?

16 EXTENSION 2: The Avogadro constant’s unit
If you take a look at german year 9 chemistry books, things can get a bit confusing. The number 6,02 x is referred to as „Loschmidtzahl“ NL The Avogadro constant NA on the other hand is used to convert a number of atoms or molecules (Teilchenzahl N) to substance amounts n via the equation 𝒏= 𝑵 𝑵 𝑨 Because of this the actual Avogadro constant has a unit. Can you figure out what it is?

17

18 The grand finale: Mole Traffic lights
You have to decide, whether the statements are true or false False Sit down Don‘t know Stand up True Stand up with hand in the air

19 The grand finale: Mole Traffic lights
The mole is a unit The mole is a mass One mole of water (H2O) and one mole of glucose (C6H12O6) have the same mass One mole of H2 contains the same number of molecules as one mole of CO2 One mole of H2 contains the same number of atoms as one mole of CO2 There are more atoms in 12 g of carbon than in 12 g of copper

20 The grand finale: Mole Traffic lights
A mole is a molecule The mole is a number One mole of a substance contains Avogadro‘s number of atoms or molecules One mole of a substance contains 6,02 x 1023 atoms or molecules The amount of a substance is measured in kilograms The amount of substance is a volume I understand what a mole is


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