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The Mystery of Half- Life and Rate of Decay
BY CANSU TÜRKAY 10-N The truth is out there...
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Before we start.... At the end of this presentation, you will be a genious about these fallowing issues (at least I hope so ) : Conservation of Nucleon Number Radioactive (a type of exponentional) Decay Law and its Proof - Concept of Half- life How to solve half-life problems
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Conservation of.... All three types of radioactive decays (Alfa, beta and gamma) hold classical conservation laws. Energy, linear momentum, angular momentum, electric charge are all conserved
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Conservation of... The law of conservation of nucleon number states that the total number of nucleons (A) remains constant in any process, although one particle can change into another ( protons into neutrons or vica versa). This is accepted to be true for all the three radioactive decays.
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Radioactive Decay Law and its Proof
Radioactive decay is the spontaneous release of energy in the form of radioactive particles or waves. It results in a decrease over time of the original amount of the radioactive material.
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Radioactive Decay Law and its Proof
Any radioactive isotope consists of a vast number of radioactive nuclei. Nuclei does not decay all at once. Decay over a period of time. We can not predict when it will decay, its a random process but... 6
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Radioactive Decay Law and its Proof
... We can determine, based on probability, approximately how many nuclei in a sample will decay over a given time period, by asuming that each nucleus has the same probability of decaying in each second it exists. 7
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Exponentional Decay A quantity is said to be subject to exponentional decay if it decreases at a rate proportional to its value. 8
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Exponentional Decay Symbolically, this can be expressed as the fallowing differential equation where N is the quantity and λ is a positive number called the decay constant: ∆N = - λN ∆ t
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Relating it to radioactive decay law:
The number of decays are represented by ∆N The short time interval that ∆N occurs is represented by ∆t N is the number of nuclei present λ is the decay constant 10
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Relating it to radioactive decay law:
Here comes our first equation AGAIN, try to look it with the new perspective: ∆N = - λN ∆ t 11
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What was that?!!! In the previous equation you have seen a symbol like: λ λ is a constant of proportionality, called the decay constant. It differs according to the isotope it is in. The greater λ is, the greater the rate of decay This means that the greater λ is, the more radioactive the isotope is said to be. 12
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Still confused about the equation...
Don’t worry! If you are still confused about why this equation is like this, here is some of the important points....
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Confused Minds... With each decay that occurs (∆N) in a short time period (∆t),a decrease in the number N of the nuclei present is observed. So; the minus sign indicates that N is decreasing. 14
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Got it!!!! ∆N = - λN ∆ t Now, here is our little old equation:
POF!!! ∆N = - λN ∆ t Now it has become the radioactive decay law! (yehu)
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What was that??? N0 is the number of nuclei present at time t = 0
The symbol e is the natural expoentional (as we saw in the topic logarithm) 16
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So what? Thus, the number of parent nuclei in a sample decreases exponentionally in time If reaction is first order with respect to [N], integration with respect to time, t, gives this equation. 17
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As seen in the figure below…
Please just focus on how it decays exponetionally. Half-life will be discussed soon…
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HALF-LIFE The amount of time required for one-half or 50% of the radioactive atoms to undergo a radioactive decay. Every radioactive element has a specific half-life associated with it. Is a spontaneous process.
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HALF-LIFE
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Ooops!!! Remember the first few slides? We stated that we can not predict when particular atom of an element will decay. However half-life is defined for the time at which 50% of the atoms have decayed. Why can’t we make a ratio and predict when all will decay???
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Answer The concept of half-life relies on a lot of radioactive atoms being present. As an example, imagine you could see inside a bag of popcorn as you heat it inside your microwave oven. While you could not predict when (or if) a particular kernel would "pop," you would observe that after 2-3 minutes, all the kernels that were going to pop had in fact done so. In a similar way, we know that, when dealing with a lot of radioactive atoms, we can accurately predict when one-half of them have decayed, even if we do not know the exact time that a particular atom will do so.
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HALF-LIFE Range fractions of a second to billions of years.
Is a measure of how stable the nuclei is. No operation or process of any kind (i.e., chemical or physical) has ever been shown to change the rate at which a radionuclide decays.
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How to calculate half-life?
The half life of first order reaction is a constant, independent of the initial concentration. The decay constant and half-life has the relationship : hl = ln(2) / λ 24
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Calculations for half-life
As an example, Technetium-99 has a half-life of 6 hours.This means that, if there is 100 grams of Technetium is present initially, after six hours, only 50 grams of it would be left.After another 6 hours, 25 grams, one quarter of the initial amount will be left. And that goes on like this. 25
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Bye! 26
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Calculating Half-Life
R (original amount) n (number of half-lifes) R . (1/2)n
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Try it!!! Now lets try to solve a half-life calculation problem…
64 grams of Serenium-87, is left 4 grams after 20 days by radioactive decay. How long is its half life?
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Solution Initially, Sr is 64 grams, and after 20 days, it becomes 4 grams.The arrows represent the half-life. 64 g ½ ½ . ½ … It goes like this till it reaches 4 grams, in 20 days. 1/2 1/2 30
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Solution We have to find after how many multiplications by ½ does 64 becomes 4. We can simply state that, Where n is the number of half lifes it has experienced. (1/2)n
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Solution . (1/2)n = 4 26-n = 22 n = 4 half-lifes
And as we are given the information that this process happened in 20 days ; 4 half-lifes = 20 days 1 half life = 5 days Tataa!!! We have found it really easily!
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Questions Explain the reason for why can’t we predict when/if a nucleus of a radioactive isotope with a known- half life would decay? Define half-life briefly.
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Questions Explain the law of conservation of nucleon number.
Does nuclei decay all at once/ how does it decay? A quantity is said to be subject to exponentional decay if…?
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THE END!!! Resources: http://cathylaw.com/images/halflifebar.jpg
radio/halflife3.htm sld003.htm
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