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Bonding Year 11 Chemistry
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Intramolecular Bonding
Ionic Bonding Definition, chemical formula and nomenclature 1 Covalent Bonding Definition, chemical formula and nomenclature 2 Metallic Bonding Definition and properties 3 Comparing Bonds Bonding and structure characteristics 4 Comparing Bonds Melting and Boiling points 5 Comparing Bonds Conductivity and Density 6
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Ions A chemical species (ie. Element, compound or molecule) with a charge Can form positive or negative ions +ive ions = Cations ( the t looks like a + … Ca+ions ) –ive ions = Anions (-ives always have to be different)
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Ion Formation A chemical species either loses or gains electrons
to attain Noble Gas Configuration or; as a result of energy input that breaks down bonds Example: Self-ionisation of water – enough energy to pass over the activation energy barrier (energy required to make and break bonds) H3O+1 and OH-1 Come together to form 2H2O
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C Ion formation- CARBON
If carbon loses an electron will it be positively or negatively charged? C
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Formation of an ion- CARBON
If carbon loses an electron will it be positively or negatively charged? C
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Formation of an ion- CARBON
If carbon loses an electron will it be positively or negatively charged? C
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Formation of an ion- CARBON
If carbon loses an electron will it be positively or negatively charged? C
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Formation of an ion- CARBON
If carbon loses an electron will it be positively or negatively charged? What will the charge be for carbon if it loses four electrons? [C] +4 What about if it gains four electrons?
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This atom has lost an electron
This atom has lost an electron. Now it has one more proton than electron. One more proton means one more positive charge. This makes the total charge of the atom POSITIVE. This atom has gained an electron. Now it has one less proton than electron. One less proton means one less positive charge. This makes the total charge of the atom NEGATIVE.
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Bonding Quiz What electron interaction occurs in ionic bonding?
What electron interaction occurs in covalent bonding? Will an ionic or covalent bond occur between Lithium and Nitrogen? If an atom loses electrons will it be positive or negative? When atoms share two pairs of electrons it is known as a(n) __________ bond
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ELECTRON SHELLS WANT TO BE FULL
From Previous Lessons ELECTRON SHELLS WANT TO BE FULL The formation of ions occurs when atoms gain or lose electrons Electrons can be transferred (gained or lost) to attain Noble gas configuration through ionic bonding Electrons can be shared to attain Nobel gas configuration through covalent bonding
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metal + non-metal = ionic bond
Ionic Bonding The transfer of elections that result in the formation of positive and negative ions, which cause an attraction between opposite charges metal + non-metal = ionic bond
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Ionic Bonds Formed between metals and non-metals with different electronegativity's The force of attraction is the opposing charges of the ions (opposites attract) [METALS ]+ [NON-METALS ]-
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Ionic Bond example Cl Na Metal Non-metal
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Cl Na Metal Non-metal
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Cl Na Metal Non-metal
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Cl Na Metal Non-metal
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Electrostatic attraction exists ‘bonding’
the two together Cl Na Positive metal ion negative non-metal ion
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Ionic Bonding and Transition Metals
As we know, transition metals are so called transition metals because they have the unique characteristic of being able to transition between charges The charge of a transition metal is always given in one of two formats By the name of the compound it forms By its given charge
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Ionic Bonding and Transition Metals
Name given: the charge is indicated by the roman numeral appearing after the metal name Metals are ALWAYS positively charged ions Example: Lead(II) oxide Numeral is 2, Metal means + ∴ The charge for lead in this compound in 2+
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Ionic Bonding and Transition Metals
Charge given: Iron 3+ and oxygen Fe O2- Fe2O3 Compound name given: Iron(III) oxide Fe3+ and O2-
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Properties of Ionic Bonds
Solid at room temperature High melting points Non-conductors of electricity in solid form Good conductors in liquid form or dissolved in water (aqueous)
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Naming Ionic Compounds
Metal always named first (no changes to spelling) Non-metal named second, with an –ide suffix When the metal is a transition metal, the charge is shown by roman numerals in parenthesis Example: Fe3+ and O2- Fe2O3 Fe – Iron (transition metal, charge of 3) O – Oxygen (non-metal ∴ Oxide Iron(III) oxide
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Name Chemical Formula
Working back from the name Example: Iron(II) chloride 1. Roman numeral give transition metal charge Fe2+ 2. Chloride is chlorine, from periodic table it is 1- Cl-1 3. Fe+2 + Cl-1 Fe1Cl2 FeCl2 4. Iron(II) chloride FeCl2
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Chemical Formula Name
Working back from the chemical formula Example: **FeO2** 1. Reverse the crisscross to get the charges Fe2+ O1- 2. Multiply out the superscripts until the non-metal has the correct charge (-1 needs to be ∴ [x 2]) Fe+2 x 2 and O-1 x 2 Fe+4 and O-2 4. FeO2 Fe+4 and O-2 Iron(IV) oxide Does oxygen have a 1- charge?
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Non-metal + non-metal = covalent bond
Covalent Bonding The sharing of elections that result in the movement of electrons around two atoms Between atoms of similar electronegativities Between non-metals and non-metals Non-metal + non-metal = covalent bond
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Covalent Bonding Equal sharing of electrons when forming the bond
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Cl Cl
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Cl Cl Cl
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Cl Cl
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Cl Cl
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Cl Cl
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Cl Cl
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Naming Covalent Compounds
Highest electronegativity non-metal is listed last Lower electronegativity non-metal is listed first The second element is an anion ∴ -ide suffix Prefixes are used to denote how many of each atom are present in the compound
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Glossary Any words to add?
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