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I. Physical Properties (p. 303 - 312)
Ch. 10 & 11 - Gases I. Physical Properties (p )
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The Kinetic-Molecular Theory of Matter
Used to explain the properties of gases, liquids and solids in terms of: 1) Energy of particles 2) Forces acting between particles. Kinetic Theory is based on the idea that particles of matter are in constant motion and that this motion has consequences.
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The Kinetic-Molecular Theory of Gases
Ideal Gas - Imaginary gas that conforms perfectly to all assumptions of the Kinetic Theory.
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A. Kinetic Molecular Theory
Particles in an ideal gas… have no volume. have elastic collisions. are in constant, random, straight-line motion. don’t attract or repel each other. have an avg. KE directly related to Kelvin temperature.
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B. Real Gases Particles in a REAL gas… have their own volume
attract each other, therefore collisions are not elastic (slowed down) Avg KE still directly related to Kelvin Temp
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Real gas Gas behavior is most ideal… at low pressures
at high temperatures in nonpolar atoms/molecules
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The Kinetic Theory and the Nature of Gases
The Kinetic Theory accounts for the following physical properties of gases: Expansion - gases do not have a definite shape nor definite volume, they fill the container they are in. Fluidity - There is very little attraction between gaseous particles, they flow past each other. Low Density - Most of a gas is empty space. The same amount of a gas as a liquid/solid takes up 100% more space.
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Compressibility - because there is so much space between molecules in a gas they can be crowded closer together. Diffusion - spontaneous mixing of 2 substances due to random motion. A) Rate of Diffusion - depends upon 1) speed of molecules 2) size 3) attractive forces Effusion gas particles under pressure pass through a very small hole from one container to another. A) Rate of Effusion - is directly proportional to the velocity of the particles.
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C. Characteristics of Gases
Gases expand to fill any container. random motion, no attraction Gases are fluids (like liquids). no attraction Gases have very low densities. no volume = lots of empty space
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C. Characteristics of Gases
Gases can be compressed. no volume = lots of empty space Gases undergo diffusion & effusion. random motion
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10.2 Qualitative Description of Gases
To describe gases accurately, you must use 4 measureable quantities; 1. Temperature 2. Pressure 3. Volume 4. Quantity or # of Particles
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Temperature Scales a) Celsius - developed by Anders Celsius(1701-1744)
- 0oC freezing pt. of water - 37oC body temperature - 100oC boiling pt. of water - 20oC normal room temperature b) Fahrenheit - developed by inventor of Mercury thermometer - Gabriel Daniel Fahrenheit in 1714. - 32oF freezing pt. of water - 98.6oF body temperature - 212o F boiling pt. of water c) Kelvin - developed by William Thomson, Lord Kelvin. - K, Kelvin is the SI unit of Temperature - 0 K, Zero Kelvin - Absolute Zero - 273 K freezing pt. of water - 373 K boiling pt. of water
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D. Temperature Always use absolute temperature (Kelvin) when working with gases. ºF ºC K -459 32 212 -273 100 273 373 K = ºC + 273
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E. Pressure Which shoes create the most pressure?
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E. Pressure Barometer measures atmospheric pressure Aneroid Barometer
Mercury Barometer Aneroid Barometer
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E. Pressure Manometer measures contained gas pressure U-tube Manometer
Bourdon-tube gauge
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E. Pressure KEY UNITS AT SEA LEVEL 101.325 kPa (kilopascal)
1 atm = 30 in. Hg 760 mm Hg 760 torr 14.7 psi
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VOLUME Volume- amount of space an object takes up
Solid – L x W x H, cm3 Fluid(Gas/Liquid) -- Graduated Cylinder in ml Quantity/# of Particles – measured in moles(6.022 x 1023 particles)
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Standard Temperature & Pressure
F. STP STP Standard Temperature & Pressure 0°C K 1 atm mm -OR-
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