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Hess’s Law Start Finish A State Function: Path independent.

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Presentation on theme: "Hess’s Law Start Finish A State Function: Path independent."— Presentation transcript:

1 Hess’s Law Start Finish A State Function: Path independent.
Both lines accomplished the same result, they went from start to finish. Net result = same.

2 and.. the H values must be treated accordingly.
Determine the heat of reaction for the reaction: 4NH3(g) O2(g)  4NO(g) + 6H2O(g) Using the following sets of reactions: N2(g) + O2(g)  2NO(g) H = kJ N2(g) + 3H2(g)  2NH3(g) H = kJ 2H2(g) + O2(g)  2H2O(g) H = kJ Hint: The three reactions must be algebraically manipulated to sum up to the desired reaction. and.. the H values must be treated accordingly.

3 Found in more than one place, SKIP IT (its hard).
Goal: 4NH3(g) O2(g)  4NO(g) + 6H2O(g) Using the following sets of reactions: N2(g) + O2(g)  2NO(g) H = kJ N2(g) + 3H2(g)  2NH3(g) H = kJ 2H2(g) O2(g)  2H2O(g) H = kJ 4NH3  2N H2 H = kJ NH3: Reverse and x 2 Found in more than one place, SKIP IT (its hard). O2 : NO: x2 2N O2  4NO H = kJ H2O: x3 6H O2  6H2O H = kJ

4 Found in more than one place, SKIP IT.
Goal: 4NH3(g) O2(g)  4NO(g) + 6H2O(g) 4NH3  2N H2 H = kJ NH3: Reverse and x2 Found in more than one place, SKIP IT. O2 : NO: x2 2N O2  4NO H = kJ H2O: x3 6H O2  6H2O H = kJ Cancel terms and take sum. + 5O2 + 6H2O H = kJ 4NH3 4NO Is the reaction endothermic or exothermic?

5 Consult your neighbor if necessary.
Determine the heat of reaction for the reaction: C2H4(g) + H2(g)  C2H6(g) Use the following reactions: C2H4(g) O2(g)  2CO2(g) H2O(l) H = kJ C2H6(g) + 7/2O2(g)  2CO2(g) H2O(l) H = kJ H2(g) /2O2(g)  H2O(l) H = -286 kJ Consult your neighbor if necessary.

6 Determine the heat of reaction for the reaction:
Goal: C2H4(g) + H2(g)  C2H6(g) H = ? Use the following reactions: C2H4(g) O2(g)  2CO2(g) H2O(l) H = kJ C2H6(g) + 7/2O2(g)  2CO2(g) H2O(l) H = kJ H2(g) /2O2(g)  H2O(l) H = -286 kJ C2H4(g) :use 1 as is C2H4(g) O2(g)  2CO2(g) H2O(l) H = kJ H2(g) :# 3 as is H2(g) /2O2(g)  H2O(l) H = -286 kJ C2H6(g) : rev # CO2(g) H2O(l)  C2H6(g) + 7/2O2(g) H = kJ C2H4(g) + H2(g)  C2H6(g) H = -137 kJ

7 enthalpy is a state function and is path independent.
Summary: enthalpy is a state function and is path independent.

8

9 Standard Enthalpies of formation:

10 Thermodynamic Quantities of Selected Substances @ 298.15 K


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