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Nomenclature of Inorganic Compounds

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Presentation on theme: "Nomenclature of Inorganic Compounds"— Presentation transcript:

1 Nomenclature of Inorganic Compounds
The Periodic Table Binary Compounds Ternary Compounds Salts Bases

2 Table 1 examples of Compounds with Names Ending in ide
Symbol Element Stem Binary Name Endings B Boron Bor- Boride Br Bromine Brom- Bromide Cl Chlorine Chlor- Chloride F Fluorine Fluor- Fluoride H Hydrogen Hydr- Hydride I Iodine Iod- Iodide N Nitrogen Nitr- Nitride O Oxygen Ox- Oxide P Phosphor Phosph- Phosphide S sulfur Sulf- or sulfur- Sulfide

3 Table 2 shows the more examples of compounds with the names ending in ide
Formula Name MgBr2 Magnesium bromide Na2O Sodium oxide AlCl3 Aluminum chloride PbS Lead (II) sulfide LiI Lithium iodide NH4F Ammonium fluoride Ca(OH)2 Calcium hydroxide KCN Potassium cyanide

4 Table 3 Names of Selected Binary Acids
Formula Acid Name HF Hydrofluoric acid HCl Hydrochloric acid HBr Hydrobromic acid HI Hydriodic acid H2S Hydrosulfuric acid H2Se Hydroselenic acid

5 Table 4. Names and Formulas of Selected Ternary Compounds
K2CO3 Potassium carbonate Al2(SO4)3 Aluminum sulfate KClO3 Potassium chlorate AlPO4 Aluminum phosphate FeSO4 Iron (II) sulfate or ferrous sulfate Fe2(SO4)3 Iron (III) sulfate or ferric sulfate PbCrO4 Lead (II) chromate H2SO4 Hydrogen sulfate HNO3 Hydrogen nitrate NaNO2 Sodium nitrite

6 Table 5. Names and Formulas of Selected Ternary oxyacids
H2SO3 Sulfurous acid HClO4 Perchloric acid H2SO4 Sulfuric acid HNO2 Nitrous acid H3PO2 Hypophosphorous acid HNO3 Nitric acid H3PO3 Phosphorous acid HBrO3 Bromic acid H3PO4 Phosphoric acid HIO3 Iodic acid HClO Hypochlorous acid H3BO3 Boric acid HClO2 Chlorous acid H2C2O4 Oxalic acid HClO3 Chloric acid H2CO3 Carbonic acid

7 Table 6. Comparison of Acid and Salt Names in Ternary oxy-compounds
Name of Salt HNO3 KNO3 Potassium nitrate Nitric acid HgNO3 Hg(NO3)2 Fe(NO3)2 Al(NO3)3 Mercury(I) nitrate or mercurous nitrate Mercury(II) nitrate or mercuric nitrate Iron(II) nitrate or ferrous nitrate Aluminum nitrate HNO2 Nitrous acid KNO2 Co(NO2)2 Mg(NO2)2 Potassium nitrite Cobalt(II) nitrite or cobaltous nitrite Magnesium nitrite HClO HClO2 HClO3 HClO4 NaClO NaClO2 NaClO3 NaClO4 Sodium hypochlorite Sodium chlorite Sodium chlorate Sodium perchlorate H2CO3 Carbonic acid Na2CO3 NaHCO3 Sodium carbonate Sodium hydrogen carbonate or sodium bicarbonate

8 Table 7. Names of Selected Salts Containing more than One Positive Ion
Acid Salt Name of salt H2SO4 KHSO4 Potassium hydrogen sulfate or potassium bisulfate H2SO3 Ca(HSO3)2 Calcium hydrogen sulfite or calcium bisulfite H2S NH4HS Ammonium hydrogen sulfide or ammonium bisulfide H3PO4 MgNH4PO4 Magnesium ammonium phosphate NaH2PO4 Sodium dihydrogen phosphate Na2HPO4 Disodium hydrogen phosphate Na3PO4 trisodium phosphate

9 KOH potassium hydroxide
NH4OH ammonium hydroxide NaOH sodium hydroxide

10 Nomenclature of Organic Compounds
Alkanes Alkyl Substituents Alkenes and Alkynes Aromatic Compounds Alcohols and Ethers Carboxylic Acids Diacids

11 8. Sulfonic acids 9. Acid Anhydride 10. Acid Halides 11. Aldehydes 12. Amides 13. Esters and salts of carboxylic acids 14. Ketones 15. Organometallics and Metal Alkoxides 16. The prefixes 17. Summary

12 Tables 1. Names of Continuous-Chain Alkanes
Molecular formula Name CH4 Methane C9H20 Nonane C2H6 Ethane C10H22 Decane C3H8 Propane C11H24 Undecane C4H10 Butane C12H26 Dodecane C5H12 Pentane C13H28 Tridecane C6H14 Hexane C14H30 Tetradecane C7H16 Heptane C15H32 Pentadecane C8H18 Octane

13 Tables 1. Names of Continuous-Chain Alkanes
Hexadecane C24H50 Tetracosane C17H36 Heptadecane C25H52 Pentacosane C18H38 Octadecane C26H54 Hexacosane C19H40 Nonadecane C27H56 Heptacosane C20H42 Eicosane C28H58 Octacosane C21H44 Heneicosane C29H60 Nonacosane C22H46 Docosane C30H62 triacotane C23H48 Tricosane

14 Table 2. Trivial Names for Some Common Alkyl Groups
Structure Name CH3CH2CH2- n-propyl (CH3)2CH- isopropyl CH3CH2CH2CH2- n-butyl (CH3)2CHCH2- isobutyl CH3CH2CH(CH3) - secondary-, or sec-butyl (CH3)3C- tertiary-, tert-, or t-butyl CH3CH2CH2CH2CH2- n-pentyl or n-amyl (CH3)2CHCH2CH2- Isopentyl or isoamyl (CH3)3CCH2- neopentyl CH3(CH2)4CH2- n-hexyl- CH3(CH2)5CH2- n-heptyl- CH3(CH2)6CH2- n-octyl-

15 Table 3. Trivial names for some alkenes and alkynes
Structure Name ethene or ethylene Propene or propylene 1-butene 2-butene isobutene acetylene Propyne ormethyl acetylene 1-butyne 4,5-dimethyl-2-hexyne allene

16 Table 4. IUPAC Names for Some Unsaturated Groups
Structure Name methylene ethenyl (vinyl) 2-propenyl (allyl) 1-propenyl isopropylidene acetylene

17 Table 5. Names for some Arenes and Aryl Groups
Structure arenes Name Benzene cumene naphthalene styrene Anthracene mesitylene Toluene

18 Table 5. Names for some Arenes and Aryl Groups
Structure aryl groups Name p-tolyl Phenyl 1-naphthyl Benzyl cinnamyl

19 tert-butylalcohol benzyl alcohol
(CH3)3COH C6H5CH2OH tert-butylalcohol benzyl alcohol

20 Table 6. Naming and Classification of Alcohols
Formula IUPAC name Common name Primary CH3OH Methanol Methyl alcohol CH3CH2OH Ethanol Ethyl alcohol CH3(CH2)3CH2OH 1-pentanol n-pentyl alcohol CH3(CH2)6CH2OH 1-octanol n-octyl alcohol (CH3)2CHCH2OH 2-methyl-1-propanol Isobutyl alcohol Secondary CH3CH(OH)CH3 2-propanol Isopropyl alcohol CH3CH2CH(OH)CH3 2-butanol Sec-butyl alcohol Tertiary (CH3)3COH 2-methyl-2-propanol t-butyl alcohol

21 Table 7 Names of some monocarboxylic Acids
structure Name of the acid HCO2H Formic acid CH3CO2H Acetic acid CH3CH2CO2H Propionic acid CH3(CH2)2CO2H Butyric acid CH3(CH2)3CO2H Valeric acid CH2=CHCO2H Acrylic acid C6H5CO2H Benzoic acid

22 Table 8. Names of Some Diacids
Structure Name HO2CCO2H Oxalic acid HO2CCH2CO2H Malonic acid HO2C(CH2)2CO2H Succinic acid Cis-HO2CCH=CHCO2H Maleic acid Trans- HO2CCH=CHCO2H Fumaric acid HO2CCH(OH)CH(OH)CO2H Tartaric acid

23 Methanesulfonic acid benzenesulfonic acid p-toluenesulfonic acid
CH3SO3H C6H5SO3H p-CH3C6H5SO3H Methanesulfonic acid benzenesulfonic acid p-toluenesulfonic acid

24 CH3(CH2)4CHO hexanal CH3CHO Acetaldehyde C6H5CHO benzaldehyde

25 CH3(CH2)4CO2CH3 Methyl hexanoate
CH3CO2CH2CH ethyl acetate CH3CH2CO2Na sodium propionate

26 (CH3CH2)3Al C6H5MgBr triethylaluminum phenylmagnesium bromide

27 Table 9. Some Common Functional Groups Named as Prefixes
Structure Name -OR Alkoxy -I Iodo -NH2 amino -F Fluoro -N=N- azo -H Hydro -Br Bromo -NO2 Nitro -Cl Chloro -NO nitroso

28 -an- means all single bonds in the carbon chain
1 carbon = meth- 5 carbons = pent- 2 carbons = eth- 6 carbons = hex- 3 carbons = prop- 7 carbons = hept- 4 carbons = but- 8 carbons = oct- -an- means all single bonds in the carbon chain -en- means a double bond in the carbon chain -yn- means a triple bond in the carbon chain

29 -e means only hydrogen is joined to the chain
-ol means an –OH -amine means an –NH2 -al means a carbonyl group on the end of the chain -one means a carbonyl group on the chain, but not at the end -oic acid means a carboxylic group on the chain


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