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CHAPTER 1.4 Alcohols, Ethers and Thiols
Learning Objective: Learn the nomenclature and uses of Alcohols, Ethers and Thiols. Keywords: Alcohol, Primary Alcohol, Secondary Alcohol, Tertiary Alcohol, Phenol, Thiols, Ether
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Alcohols An alcohol contains a hydroxyl group (—OH) attached to a carbon chain. A phenol contains a hydroxyl group (—OH) attached to a benzene ring. water alcohol phenol Copyright © by Pearson Education, Inc. Publishing as Benjamin Cummings
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Naming Alcohols The names of alcohols
in IUPAC replace the -e with -ol. with common names use the name of the alkyl group followed by alcohol. Formula IUPAC Common Name CH4 methane CH3─OH methanol methyl alcohol CH3─CH3 ethane CH3─CH2─OH ethanol ethyl alcohol
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Names the following Alcohols
IUPAC names for longer chains - number the chain from the end nearest the -OH group. CH3─CH2─CH2─OH OH │ CH3─CH─CH2─CH3 CH OH │ │ CH3─CH─CH2─CH2─CH─CH3
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More Names of Alcohols - Answers
IUPAC names for longer chains - number the chain from the end nearest the -OH group. CH3─CH2─CH2─OH propanol OH │ CH3─CH─CH2─CH butanol CH OH │ │ CH3─CH─CH2─CH2─CH─CH methyl-2-hexanol
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Some Typical Alcohols | “rubbing alcohol” CH3—CH—CH3
2-propanol (isopropyl alcohol) antifreeze HO—CH2—CH2—OH 1,2-ethanediol (ethylene glycol) glycerol HO—CH2—CH—CH2—OH 1,2,3-propanetriol
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End Task Name the following compounds. 1. CH3—CH2—CH2—CH2—OH OH CH3
| | 2. CH3—CH—CH—CH2—CH3 3. 2 minutes End
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Solution OH CH3 | | 2. CH3—CH—CH—CH2—CH3 3-methyl-2-pentanol
1. CH3—CH2—CH2—CH2—OH 1-butanol OH CH3 | | 2. CH3—CH—CH—CH2—CH methyl-2-pentanol cyclopentanol
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Phenols in Medicine Phenol
is the IUPAC name for benzene with a hydroxyl group. is used in antiseptics and disinfectants. phenol resorcinol or benzenediol hexylresorcinol
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Derivatives of Phenol Compounds of phenol are the active ingredients in the essential oils of cloves, vanilla, nutmeg, and mint.
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Naming Phenols To name a phenol
with two substituents, assign C-1 to the carbon attached to the –OH. number the ring to give the lowest numbers. 1 1 3 4 3-chlorophenol bromophenol
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End Task Write the structure of each of the following. A. 3-pentanol
B. ethyl alcohol C methylphenol 2 minutes End
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Solution Write the structure of the following. A. 3-pentanol OH |
CH3—CH2—CH—CH2—CH3 B. ethyl alcohol CH3—CH2—OH C. 4-methylphenol O H C 3
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Classification of Alcohols
Classification of alcohols is determined by the number of alkyl groups attached to the carbon bonded to the hydroxyl. primary (1°), secondary (2°), or tertiary(3). Primary (1º) Secondary (2º) Tertiary (3º) 1 group groups 3 groups H CH CH | | | CH3—C—OH CH3—C—OH CH3—C—OH | | | H H CH3
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End Task 1) primary, 2) secondary, or 3) tertiary. OH |
Classify each alcohol as 1) primary, 2) secondary, or 3) tertiary. OH | A. CH3—CH—CH2—CH3 B. CH3—CH2—CH2—OH C. CH3—CH2—C—CH2—CH3 CH3 2 minutes End
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Solution | A. CH3—CH—CH2—CH3 secondary B. CH3—CH2—CH2—OH primary
C. CH3—CH2—C—CH2—CH3 tertiary CH3
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Thiols Thiols are carbon compounds that contain a –SH group.
are named in the IUPAC system by adding thiol to the alkane name of the longest carbon chain. Copyright © by Pearson Education, Inc. Publishing as Benjamin Cummings
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Thiols Thiols often have strong smells. are used to detect gas leaks.
are found in onions, oysters, and garlic.
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Ethers An ether contains an ─O─ between two carbon groups.
has a common name that gives the alkyl names of the attached groups followed by ether. CH3─O─CH3 CH3─CH2─O─CH3 dimethyl ether ethyl methyl ether
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End Task Write the structure of the following. A. pentyl propyl ether
B. diethyl ether 2 minutes End
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Solution A. pentyl propyl ether B. diethyl ether CH3─CH2─O─CH2─CH3
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Ethers as Anesthetics Anesthetics inhibit pain signals to the brain.
like diethyl ether CH3─CH2─O─CH2─CH3 were used for over a century, but caused nausea and were flammable. developed by the 1960’s were nonflammable. Cl F F Cl F H │ │ │ │ │ │ H─C─C─O─C─H H─C─C─O─C─H F F F H F H Ethane(enflurane) Penthrane
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TASK Answer the questions on the handout. If you don’t finish it in class, do it for homework please
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