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ChE 402: Chemical Reaction Engineering

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Presentation on theme: "ChE 402: Chemical Reaction Engineering"— Presentation transcript:

1 ChE 402: Chemical Reaction Engineering
Review of the concepts of reaction kinetics- Chapter 1 Classification of chemical reactions, definition of reaction rate The general mole balance

2 CHEMICAL REACTION: A chemical reaction is a process that leads to the transformation of one set of Chemical substances to another.

3 How can we count them? Reaction

4 Batch Reactor Batch Continuous Stirred Tank Reactor (BCSTR)

5 Flow Reactor CSTR

6 Flow Reactor Continuous Stirred Tank Reactor (CSTR) Tubular Reactor

7 Tubular Reactor Plug Flow Reactor (PFR) Packed Bed Reactor (PBR)

8 Tubular Reactor Fluidized bed Reactor (FBR) Bubble Column Reactor (PBR)

9 Industrial Reactors

10 The Rate of Reaction Chemical kinetics
is the study of rates of chemical reactions

11 The Rate of Reaction What factors influence the rate of a reaction?
Once we specify a particular reacting system, the factors that influence the rate of a reaction are (1) temperature, (2) concentrations of reactants, (3) physical state of reactants, (4) presence of a catalyst. The rate equation (Rate Law) is an algebraic equation of a Chemical Reaction that links the Reaction Rate with concentrations or pressures of reactants and constant parameters (normally rate coefficients and partial Reaction Orders) Independent of the type of reactor (Batch or Continuous)

12 The Rate of Reaction Rate of Disappearance :
Rate of Formation (Generation): Reaction in presence of Catalyst number of moles of A reacting per unit time per unit mass of catalyst (mol/s. g catalyst)

13 The Rate of Reaction

14 The Rate of Reaction Rate of reaction or Rate law may be like :

15 General Mole Balance

16 Batch Reactor Mole Balance

17 CSTR Mole Balance

18 Plug Flow (Tubular) Reactor Mole Balance
PFR: The integral form is: or This is the volume necessary to reduce the entering molar flow rate (mol/s) from FA0 to the exit molar flow rate of FA.

19 Packed Bed Reactor Mole Balance
PBR The integral form to find the catalyst weight is:

20 Reactor Mole Balance Summary
Differential Algebraic Integral BATCH CSTR PFR PBR

21 Chemical Kinetics or Reaction Engineering
Mole Balance Rate Laws Stoichiometry These topics build upon one another Mole Balance Rate Laws Stoichiometry Isothermal Design Heat Effects

22 Isothermal Reactor Design Algorithm

23

24 QUESTIONS ?

25 ChE 402: Chemical Reaction Engineering
Review of the concepts of reaction kinetics- Chapter 1 Classification of chemical reactions, definition of reaction rate The general mole balance

26 General Mole Balance

27 Batch Reactor Mole Balance

28 CSTR Mole Balance

29 Plug Flow (Tubular) Reactor Mole Balance
PFR: The integral form is: or This is the volume necessary to reduce the entering molar flow rate (mol/s) from FA0 to the exit molar flow rate of FA.

30 Packed Bed Reactor Mole Balance
PBR The integral form to find the catalyst weight is:

31 Reactor Mole Balance Summary
Differential Algebraic Integral BATCH CSTR PFR PBR

32 The Rate of Reaction What factors influence the rate of a reaction?
Once we specify a particular reacting system, the factors that influence the rate of a reaction are (1) temperature, (2) concentrations of reactants, (3) physical state of reactants, (4) presence of a catalyst. The rate equation (Rate Law) is an algebraic equation of a Chemical Reaction that links the Reaction Rate with concentrations or pressures of reactants and constant parameters (normally rate coefficients and partial Reaction Orders) Independent of the type of reactor (Batch or Continuous)

33 The Rate of Reaction Rate of Disappearance :
Rate of Formation (Generation): Reaction in presence of Catalyst number of moles of A reacting per unit time per unit mass of catalyst (mol/s. g catalyst)

34 The Rate of Reaction

35 The Rate of Reaction Rate of reaction or Rate law may be like :

36 Chemical Kinetics or Reaction Engineering
Mole Balance Rate Laws Stoichiometry These topics build upon one another Mole Balance Rate Laws Stoichiometry Isothermal Design Heat Effects

37 Isothermal Reactor Design Algorithm

38

39 QUESTIONS ?


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