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FACT OR FRICTION The Most Advanced Technology In Lubrication

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1 FACT OR FRICTION The Most Advanced Technology In Lubrication
EVERGREEN AMERICA CORPORATION FACT OR FRICTION The Most Advanced Technology In Lubrication Represented by: Will Monsell, President GREEN ENERGY PRODUCTS, LLC Damariscotta, Maine THE OPENER AND PREVIEW ------Drag sidebar to left. After you view with notes, click F5 on keypad to view show in animation and full screen. ©Evergreen America Corporation, 2003, 2004 1

2 Lubrication Lubrication is the act of applying lubricants and lubrication substances which are capable of reducing friction between moving mechanical parts The challenge of the lubricant as you will see is to prevent or delay component failure by forming a barrier between two opposing surfaces thus reducing particle generation. So a good lubricant reduces wear is save to say. The problem is that even the best lubricants deteriorate as a result of chemical and physical contamination caused by particle generation as a result of friction and heat. The costly results of friction will be very obvious as we proceed. 2

3 Asperities Asperities
All surfaces, no matter how smooth they may appear to the unaided eye, when sufficiently magnified are rough and uneven. This unevenness is know as asperities. Asperities Even the best lubricants can not prevent asperities from generating particles nor can the Anti-wear additives in the base oil maintain a sufficient barrier for long. Asperities when rubbed together generate particulate 3

4 Friction Consumes Power
Friction is the resistance to relative motion between two bodies in contact. According to the Department of Energy, 62.4% of energy is lost to friction in the engine resulting in the loss of fuel, horsepower & components Greatest friction occurs by particles the same size as the oil film thickness Particle induced wear is greatest when the particle is same size as oil film thickness. As you can see, under the present conditions the OEM filter does not remove particles under microns nor does the present boundary lubricant prevent particle generation. Little protection is offered against wear particles resulting in energy loss, oxidation, heat, viscosity loss, additive depletion, six times emissions output, 5% plus fuel loss, 18% loss of horse power, increased friction, chemical reactions, 70% higher component replacement. 4

5 Adhesion and Cohesion Adhesion is the property of a lubricant that causes it too stick or adhere to the parts lubricated. Cohesion is the property which holds a lubricant together and resist a breakdown of the lubricant under pressure. Moving Surface Adhesion According to the Langmuir theory oil is composed of many layers of molecules under motion which in the perfect world separates moving surfaces. In the real world oil is quickly contaminated as a result of friction and heat. Cohesion Oil molecules Oil molecules slide over each other 5

6 Relationship of Friction, Cohesion, Adhesion and Lubrication
Friction always consumes power and produces heat Any fluid when placed between two surfaces tends to keep them apart and change sliding friction into fluid friction, thus they are said to be lubricated The extent to which lubrication reduces the friction between two surfaces is governed by two factors: 1) The selection of the fluid which has the best proportion of cohesive & adhesive properties. 2) The amount of pressure between the two surfaces To insure lubrication, the layer of fluid must be kept intact, the greater the pressure the more difficult this becomes

7 3 Common Types of Wear as a Result of Friction
(3) SURFACE FATIGUE (1) ABRASIVE WEAR Stress Risers Cutting away Denting Affect (2) ADHESION 1) Abrasive wear: Dr, Rabinowizz of MIT American Society of engineers bearing workshop in “70% of component replacements “loss of usefulness” is due to surface degradation” in hydraulic and lube systems”. Particles act like cutting tools Particles broken away from surface become harder that surface “work hardened” Chain reaction of abrasive wear Under present maintenance practice abrasive wear considered normal Break the chain reaction of wear Fluid Pump greatly affected -greater leakage -higher temperatures -lower oil pump pressure -reduced efficiency 2) Abrasive wear: Excessive load, low speed, and/or reductions and/or reductions in fluid viscosity can reduce the oil film thickness to a point where metal to metal contact occurs. The microscopic ridges are known as “aspirates” are “cold welded” together and particles are sheared off as surfaces move. 3) Surface fatigue: Bearing surfaces are subject to fatigue failure. 46% of bearing failure due to particles under 10 microns. What happens is that first the surface is dented by the bearing load-eventually the surface fails, produces a spall. Bearing replacement is required. This can be avoided by eliminating the damaging particles and protecting the surfaces against friction. Productive maintenance seeks to eliminate the cause, not manage the problem. Weld Junctions *High pressure pump *Bearings *Gears *Rings & cylinders *Valves *Seals Surface Roughness 7

8 Tribology Since the late 1960’s the field of Tribology – the study of
friction, wear and lubrication in fluid systems - has developed sophisticated tests to gain much knowledge into the effects of friction and ways to reduce friction in order to reduce wear, heat and particle contamination. The field of Tribology has developed the most sophisticated test to scientifically measure the effects of contamination in fluid systems in order to reduce friction, heat and energy. Today we can see the most damaging particles are under 5 micron, invisible to the eye. 8

9 The Problem Thus far you have seen the effects of friction and the challenge facing lubricants under pressure, heat and particle contamination Friction and heat cause the destruction of asperities resulting in metal particles interrupting the oil film between two surfaces generating more particles These particles react with moisture, impurities and lubricant additives creating corrosive acids that further pit the surface creating new asperities These acids oxidize the lubricant, accelerate wear and rapidly deteriorate the functions of the lubricant resulting in the 3-common wears in the fluid system As you can see, the historical problem with lubrication is its short life and inability to have a big affect on wear and friction. PARTICLES UNDER 5µ CAUSE THE MOST COMPONENT DAMAGE -Dr. E. Rabinowicz of M.I.T. (American Society Of Lubrication Engineers 1981) 9

10 5 Functions of the Lubricant
Friction Reduction Seal Heat removal Cleanse Absorb Shock Friction reduction: Maintain clean film between surfaces. Under present “normal” conditions, friction accounts for 64.4% energy loss % occurs in pistons, rings, crankshaft, piston connecting bearings, & lifters. 2. Sealing: goal is to fill in surface aspirates forming seals. Keep out combustion blow-by contaminants, maintain fluid system pressure and efficiency. 3. Heat removal: Removes heat generated by friction and high temperature surfaces. Remove heat generating particles. Maintain thermal stability of the oil. less component failure, higher efficient operating equipment. 4. Cleansing effect: Remove contaminants and trap them-water, particles, soot and acidic by-products thus maintaining the oils oxidative stability. Results in reducing the cost of owning and operating a fluid system. 5: Shock absorbing: Diffuse high pressure created from combustion to reduce engine wear and positively affect horsepower. CLEAN LUBRICANT PERFORMS TWO MAJOR BENEFITS: Maximize Performance: Optimum efficiency, less wear, less fuel, less friction, higher productivity. 2. Minimize Cost: up to 90% less oil purchased, up to 12% less fuel cost, 50% less downtime, 70% less component replacement, reduced labor and maintenance cost, reduced liability, higher safety and less pollution released into our living and breathing space. 10

11 Challenge of the Lubricant
A good lubricant must reduce particulate wear from the interaction of metal-metal contact Even the best lubricants degrade over time, as a result of friction and chemical in the additive package reacting with particulate, moisture, heat and oxygen resulting in acidic properties These acids react with the metal surface causing micro-pitting (asperities) and the vicious cycle begins anew The very anti-wear additive package designed to protect metal-metal contact, turns acidic and become part of the problem

12 The Downfall of Lubricants
The typical downfall of a lubricant occurs as a result of an imperfect, temporary and sacrificial boundary layer between surfaces allowing asperity-asperity contact thus introducing particulate into the lube Heat, moisture, air, and metal particulates combined with certain additives interact causing acids which micro pit the surfaces and oxidizes the oil The efficiency & longevity of a lubricant dramatically increases as the asperity-asperity contact decreases The goal is to reduce friction through a solid and permanent boundary layer on the surfaces

13 Boundary Additives The intent of boundary additives are to form a boundary layer of molecules to prevent surface-surface contact Additives in use are Graphite, Molybdenum, Zinc, Phosphorous, and Sulfur Downside of these additives are their chemical reaction with metal and other contaminates such as moisture causing them to become acidic, corrosive and a part of the problem they are intended to solve These additives are also highly toxic; such as Zinc that is linked to cancer and other illnesses The field of Tribology over the years has researched for a solid boundary lubricant that is biodegradable and permanent.

14 The Present Condition of Friction
Loss of horsepower or power in hydraulics Graduated loss of fuel economy Frequent oil drains due to degradation Component wear Increased emissions Rising maintenance cost Rising labor cost Half the words energy is lost to friction – DOE Even the best synthetics rely on sacrificial boundary anti-wear additives Dept. Of Energy 14

15 18% Decrease in Horsepower
“Wear promoted by particles (under 10µ) leads to diminished fuel efficiency, reduced component life, oil service, and power output” -Needelman, Filtration For Wear Control & Affects of Contamination 18% Decrease in Horsepower Extending oil drains without friction protection this engine dropped from 365 HP to 300HP Cummins engine Under present conditions OEM engine filters are 30 microns and Hydraulic System filters are 10 microns. The cause of the loss of power is friction induced wear from particles the same size as oil film clearance. 15

16 America's First National Laboratory
THE DISCOVERY Argonne National Laboratories is under the Department of Energy and managed by Chicago University. Every nuclear facility in the world carries the name Argonne. This lab is dedicated to reducing the worlds energy waste. 16

17 The “Big Bang” Discovery In Friction Reduction Technology
Following years of research in support of the US space program, a discovery in 1990 by scientist at the prestigious Argonne National Laboratory redefined the potential of lubrication technology Argonne Website:

18 The Discovery In 1991 the DOE patented boric acid as a solid boundary- layer lubricant. Developed by Dr. Erdemir, Boron CLS Bond was the result of years of research at the Argonne National Laboratories Tribology Department under the Department of Energy Winner of the prestigious R&D 100 award Holds a U.S. DOE Government patent #5,431,830 BORON CLS BOND has been tested worldwide under the harshest conditions with millions spent and producing the same consistent results every time Written up in Journals of Tribology. Lubrication Engineers and many other publications as a self replenishing solid boundary lubricant

19 The Technology Biodegradable Boric Acid is used to form a permanent solid boundary layer lubricant on Metal Surfaces NO additive in oil has the ability to form a permanent solid boundary layer

20 BORIC ACID Step One: Boric Acid is Introduced METAL SUBSTRATE
A new permanent surface is about to be created

21 Step 2: Interaction between Boric Acid, moisture and the metallic substrate forms Boric Oxide
H2O METAL SUBSTRATE AIR BORIC OXIDE METAL SUBSTRATE

22 Step 3: Boric Oxide bonds to the metallic substrate and forms a solid surface barrier on the substrate preventing metal-to-metal contact. METAL SUBSTRATE BORIC OXIDE Boric Acid BORIC OXIDE METAL SUBSTRATE 85% hardness of a diamond

23 BORIC OXIDE BORIC OXIDE
Step 4: Interaction between Boric Oxide and moisture reforms Boric Acid into crystalline platelets METAL SUBSTRATE BORIC ACID PLATELETS BORIC OXIDE BORIC OXIDE METAL SUBSTRATE An effective new technology protecting surfaces

24 Step 5: Crystalline Boric Acid Platelets Form Crystal Lattice Structure - CLS
Electron micro- photograph of boric acid Crystal Lattice Structure (15 micron field Of view) Like a deck of brand new playing cards sliding over each other

25 BORIC OXIDE BORIC OXIDE
Step 6: Boric Acid platelets align themselves parallel to the metal surface and conform to the direction of movement METAL SUBSTRATE BORIC OXIDE BORIC OXIDE METAL SUBSTRATE “70% of component replacement is the result of surface degradation” –Dr. Rabinowitz, MIT at American Society of Engineers workshop

26 NO LUBRICANT CAN ACHIEVE THIS LOW COEFFICIENT
Virtually eliminates particle generation EXTREME LOW FRICTION COEFFICIENT* LESS THAN 0.01% (80% REDUCTION IN FRICTION) *The ratio of the force that maintains contact between an object and a surface and the frictional force that resists the motion of the object.

27 BORIC OXIDE BORIC OXIDE
Step 7: Weak van-der-Waals forces* between the crytalline layers allows very low friction movement between layers METAL SUBSTRATE Weak inter- platelet bonds BORIC OXIDE BORIC OXIDE METAL SUBSTRATE *A weak attractive force between atoms or nonpolar molecules

28 Resists High Pressure LOAD EXTREME PRESSURE PERFORMANCE

29 Extreme hardness of crystalline structures prevents metal-to-metal contact when load is applied
METAL SUBSTRATE BORIC OXIDE BORIC OXIDE METAL SUBSTRATE

30 Step 8: Self-renewing cycle: Interaction between Boric Acid, Boric Oxide, Air and Moisture leads to self-replenishing cycle. BORIC ACID AIR + MOISTURE MOISTURE BORIC OXIDE

31 Lubrication Performance
Friction Coefficient Less Than 0.01 Timken Load Greater Than 90+ Reduces wear up to 90% Reduces Friction up to 80% Increases Engine Efficiency 5-7%+ Increases Fuel Efficiency 2-12%+ Reduces Friction Heat 40-50% Coefficient less that 0.01 = 80% less friction Timken Load test highest rating is 90. Most greases rated at 60 and fail at We outperformed the test! Engine efficiency translates to increased horse power (Test performed at Disney Florida on Detroit Diesel Engine showed an increase of horse power from 219 to 264 in 7 days) Fuel efficiency is increased as a result of less energy to move the object Reducing heat is vital to delay the oxidation process and another reason oil drains are safely extended 31

32 Added Values Biostat Anti-Corrosive Anti-Oxidant Reactive Coating
Water Resistant Displaces carbon, varnish and sludge previously built up in Engine/machinery Prevents deposit formation in new engines Biodegradable and the Hydraulic and Engine oil is 90% biodegradable with no toxic additives. The 10% difference is the polymers used for viscosity. Corrosion is a major problem eliminated Anti-Oxidant and reactive coating, does not react with moisture or metal to oxidize the fluid In older engines carbon and varnish build up. The Boron will displace it. Protects fluid systems against any buildup 32

33 TEST RESULTS Millions in research and testing support every claim for this US Goverment patent technology. Nothing in the marketplace is comparable. This is not an additive, rather a treatment for metal surfaces. Lets look at a handful of test since documentation available is insurmountable. Visit test results at 33

34 Partial Test List Pin on disk Ball on three disk Friction Coefficient
HFRR Engine test: Fuel consumption, emissions, horsepower Scar width Spectrographic analysis Timken load Corrosion Oxidation Prevention & protection from deposit formation … And more A handful of sophisticated test measuring the results you can expect when treating your fluid systems with Boron CLS Bond. 34

35 Engine Oil Treatment Test Test performed at BNM Research, Sweden in March 2002
Test indicated a 5% reduction in fuel consumption. Long term benefits are reduced wear due to reduced friction Significant reduction of metal residue in drain oil Significant reduction of corrosion

36 Diesel Fuel Treatment Test Test performed at BNM Research, Sweden in March 2002
Results indicate a >5% increase in fuel economy Long term reduced wear, due to reduced friction Lower emissions (HC) The diesel treatment is 1000 to 1 dilution and you can expect significant better fuel mileage (Show Hummer results) 36

37 Pin On Disk Test With diesel fuel treatment, grease, gear/engine
treatment combined with different ceramic compounds Low sulfur diesel fuel without Boron CLS Bond Low sulfur diesel fuel with Boron CLS Bond Treatment Maintains fuel system free from buildup 37

38 Corrosion Standard comparative corrosion test using metal
in a corrosive environment A test done in Germany applied the Lubrisilk grease on one metal bar and no treatment on the other and placed in salt water for 30 days. The treated bar had NO corrosion and the untreated bar was corroded. Halliburton uses the Boron grease under water since it does not leak and prevents corrosion resulting in significant savings and downtime. Boron CLS Bond resists corrosion even in salt water 38

39 Solvency Test Pennzoil Pennzoil & Motor Silk Test coupons immersed in
beakers for 4-days alternately heating 100C, lightly stirring with coupon, cooling & repeating. Motor Silk sample displaced a greater portion of the carbon deposits leaving more visible metal with a slight varnish coating. Overall carbon thickness reduced within 4-days. In only 4 days carbon lifted. Older engines restored to fuel efficiency and power. A very inexpensive “rebuild”. Pennzoil Pennzoil & Motor Silk 39

40 The most Advanced Friction Reduction Technology Available
Argonne Tribology Labs has contributed the greatest development in lubrication and friction reduction technology available today. Taking advantage of the Boron CLS Bond technology for your fluid system will have the greatest impact for you financially, mechanically, and environmentally. You now know of the most advanced technology developed not by a company bit the US government for the space program and military. 40

41 Fluid Treatments to Custom Formulations
We have a whole line of formulations and always developing new formulations to meet specific needs Motor Silk for engines is a 10-1 dilution so 16 ounces treats 5 quarts and is a one time treatment 41

42 Some Companies Already Using
Allied Signal Bartell Yachts Bimba Corporation Boeing Aerospace & Aircraft Robert Bosch Chem Tool Enron Wind General Petroleum Haliburton Corporation Henkel Chemical Hitachi Refrigeration Florida Light and Power Ford Motor Company Fujikoshi Husqvarna Idemetsu Kaiman Aerospace Marine Industries Matsushita Mitsubishi Heavy Industries Mitsubishi Metals Mitsui Mabuchi Motors Navistar Neste/Fortum Oil Nihon Chemical Kogyo Nihon Victor Oil Disney Florida Plus Many More World Wide

43 The Proactive Maintenance Consultants
Evergreen America Corporation Proactive Maintenance Engineering Thank you for your time investigating the most advanced fluid system protection available anywhere in the world The Proactive Maintenance Consultants Visit for more technical info.

44 NO RISK INVOLVED Equipment Inventory Data
Cost Analysis (ROI within 2 weeks to 2 months) Integrate on a monthly basis Savings from present maintenance budget invested into a permanent solution Money Back Guarantee (pay for itself or money back) In-House Performance Evaluation We work with you every step of the way Obtain information on all equipment in order to suggest products Obtain required info on equipment for cost analysis Work out a monthly budget to integrate the technology Use savings for a permanent solution If an in house performance evaluation is requested then we need equipment with an oil trend analysis and accurate fuel records. Pick out 5 vehicles or equipment, and use our Lab – Analysis Inc, a leader in the field of oil analysis. They will incur all cost for oil analysis and product used for the evaluation. The evaluation is for six weeks and requires particle analysis. We will be there for oil samples and in communication for the entire evaluation. Who will be in charge of the evaluation? What scientific method will they employ for fuel efficiency? 44


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