1. M/s. ZUARI AGRO CHEMICALS LIMITED, Zuarinagar, Village- Sancoale, Taluka- Mormugao, District- South Goa, GOA. Welcome all for Public Hearing. Kadam Environmental Consultants 1 Project Name: Environmental Clearance for Fertilizer Blending Unit for Customized NPK Grade, Gas Turbine (GT), Heat Recovery Steam Generator (HRSG), Atmospheric Ammonia Storage Tank (AAST) & Urea Granulation Unit. Activity No. and Category (as per Schedule of EIA Notification, 2006): 5(a), Chemical Fertilizers, Category A. Consultant: Kadam Environmental Consultants (Certificate No. NABET/EIA/1316/SA 2 001) Date: 11/07/2016 F. No. J-11011/186/2015-IA II (I)

2. ABOUT ZACL 2 Kadam Environmental Consultants  Incorporated in 1967 as Zuari Agro Chemicals Ltd. (ZACL).  Promoted by K. K. Birla group in collaboration with US Steel Corporation (USX), International Finance Corporation and the Bank of America.  First mega industrial undertaking in the state of Goa.  The factory complex consists of Ammonia plant, Urea plant, NPK-A plant, NPK-B plant, Utilities plant, Raw Material Handling plant, Product Handling plant and the associated facilities like Workshops, Stores, Laboratory, Fire Station, Health Centre etc.  The factory also operates off site facilities at MPT, Mormugao for import & transportation of Ammonia, Phosphoric Acid & Potash.  Ammonia, Urea & NPK-A plants were designed, engineered & constructed on a turnkey basis by Toyo Engineering Corporation, Japan. Ammonia & Urea plants were commissioned in 1973. NPK-A plant was commissioned in 1975.  NPK-B plant was designed, engineered & constructed by Hindustan Dorr-Oliver and commissioned in 1984.  Committed to high standards of Industrial Safety, Occupational Health & Environment Protection.

3. ZACL’S ENVIRONMENT, OH&S POLICY 3 Kadam Environmental Consultants Environment, Occupational Health &Safety Policy

4. ZACL’S ISO 14001:2004 & OHSAS 18001:2007 CERTIFICATE 4 Kadam Environmental Consultants ISO 14001:2004 Certificate ISO 18001:2007 Certificate

5. ABOUT PROJECT & PUBLIC HEARING REQUIREMENT 5 Kadam Environmental Consultants ZACL intends to “modernize” its manufacturing facilities for fertilizers within its existing Fertilizer Complex at Zuarinagar. Proposed project comprises of Fertilizer Blending Unit for Customized NPK Grade, Gas Turbine (GT), Heat Recovery Steam Generator (HRSG), Atmospheric Ammonia Storage Tank (AAST) & Urea Granulation Unit. Customized NPK Production Facility  Soil & Crop Specific NPK Fertilizers fortified with Micro-nutrients  Granulation by means of Steam/Water rather than Slurry Granulation – “Dry” Granulation – Minimal Emission of Pollutants such as Ammonia  Utilities Requirement such as Steam, Power etc. sourced from existing facility – No separate generation facility GT+HRSG Unit  More energy efficient and “State of Art” Cogeneration Facility to generate Captive Power and Steam (than existing)  Maximization of Motor drives instead of Steam Turbines  Conservation of Natural Resources – Natural Gas & Water

6. ABOUT PROJECT & PUBLIC HEARING REQUIREMENT 6 Kadam Environmental Consultants Atmospheric Ammonia Storage Facility  “State of Art”, Double Integrity, “Cup in Tank” Design  Migration from “Pressurized Storage” (Horton Sphere) to “Fully Refrigerated” Storage (stored at Atmospheric Pressure) – Risk Mitigation; Intrinsically Safer  Proposed AAST will be same as per existing storage facility in MPT functional from January, 2002. Urea Granulation Facility  Installation of Urea Granulation Unit facilitates reduction in the Prill Tower Load  Granular Urea behaves as Slow Release fertilizer; ease of handling and lower dust generation at farm gate.  Lower Dust Emission from Prill Tower as well substantially lower emission from the Granulation Unit M/s. ZACL has submitted an application to MoEFCC for Environment Clearance vide letter ZACL/XXX dated 24/06/2015. For the same, Terms of Reference (ToR) issued by MoEFCC vide J-11011/186/2015-IA II (I) dated 18 th February, 2016. An advertisement covering the requirements laid out in EIA notification was issued in widely circulated national daily ‘Indian express’ and regional English newspaper ‘Navhind Times’, ‘Herald’ and vernacular daily ‘Tarun Bharat’ on June 11, 2016. Also given advertisement in TV (GOA 365, HCN & Prudent Channel)

7. Kadam Environmental Consultants SITE LOCATION MAP 7

8. MAP Showing all Proposed Plants in ZACL Complex 8 Kadam Environmental Consultants

9. LANDUSE MAP ~10 KM FROM ZACL 9 Kadam Environmental Consultants Not to Scale

10. PROJECT SYNOPSIS 10 S No.ItemDetails 1Location Survey No. : 110 to 252; Zuarinagar Village : Sancoale; Taluka: Mormugao; District : South Goa; State: Goa. 2Existing LanduseExpansion will be done in existing fertilizer complex. 3Area Customized NPK Grade : 1,125 M 2 GT : 1,952 M 2 HRSG : 1,860 M 2 AAST : 7,999 M 2 Urea Granulation Unit : 1,500 M 2 4Project CostINR 788.60 Crore 5 Expenditure on Environmental Matter Capital Cost : INR 10.35 Crore Recurring Cost: INR 0.91 Crore 6 Manpower Requirement Direct Jobs: During its operational lifecycle of the project around 80-100 jobs will be created. Indirect Jobs: Approx. 100-150 jobs will be indirectly created by the setting up of the project during its construction & operational lifecycle Kadam Environmental Consultants Synopsis of Proposed Project is shown below:

11. PROJECT SYNOPSIS 11 S No. ItemDetails 7 Production Capacity Condensed List of Proposed Products: Total List of Existing and Proposed Products: Kadam Environmental Consultants S. No. Name of Product Existing Capacity (MT) Proposed Capacity (MT) Total Capacity (MT) 1Urea 1500 (All Prilling) -300 (Prilling) +600 (New Granulation Plant) 1200 (Prilling)+ 600 (Granulation) = 1800 2Ammonia Storage tank Horton Sphere 3000 (1+1) Atmospheric Ammonia Storage Tank 1X5000 3 Customized Blending Plant 030 MTPH 4GT025 MW 5HRSG0 Generation of MP Steam (37 Kg/Cm 2 g) - Capacity (Unfired with supplementary firing) = 50 /70 MT/hr. Generation of MP Steam (37 Kg/Cm 2 g) - Capacity (Unfired with supplementary firing) = 50 /70 MT/hr. Continue..

12. Kadam Environmental Consultants PROJECT SYNOPSIS 12 S No. ItemDetails 8 Power Requirement & Source The electricity requirement of about 2 MW will be sourced internally 9 Water Requirement & Source Permissions for the same is attached. 10 Waste Water Generation and Disposal 11Traffic Based on the traffic survey conducted, the road is capable of handling additional movement of traffic for carrying raw materials and finished products. 12 Hazardous Solid Waste treatment and Disposal Click Here for Details Continue.. ExistingProposedTotalSource 9,970 KLD(-2,100) KLD7,870 KLDWater Resource Department ExistingProposedTotalFinal Disposal 2,525 KLD(-220) KLD2,305 KLDZero Liquid Discharge Unit Recycle & Reuse methods will be adopted

13. PROJECT SYNOPSIS 13 S No.ItemDetails 13 Fuel Requirement About 0.17 MMSCMD & 2,000 SCMD NG / RLNG will be used for steam power generation unit & Customized Blending Unit respectively. It shall be arranged from the existing GAIL NG pipeline 14 Air emissions and control Kadam Environmental Consultants Continue.. Stack attached toExpected Pollutant Stack Height (m) Proposed APCM Proposed Flue Gas Stack attached to Boiler / Furnace GT+ HRSG stackPM, SO 2, NO x 30Dry Low NO x burners Hot Air Generator stack + Rotary Dryer Stack for Cust. Plant PM, NO x, NH 3 & SO 2 30Cyclone separators, Bag filters and Dilute Acid Scrubbers Proposed Various Other Stacks/vent of reactors, process, vessel Rotary Cooler StackPM30Cyclone separators, Bag filters and Dilute Acid Scrubbers Urea Granulation PlantPM, NH 3 40Wet Scrubber

14. SITE SPECIFIC METEOROLOGICAL DATA 14 Kadam Environmental Consultants Study period: Summer Season 2013 (March 2013 – May 2013). Site specific data were considered as a Secondary Source from long term climatological tables (1961-1990) for nearest station from site (Marmugao Taluka, Station ID: 43196) published by Indian Meteorological Department (IMD). Meteorological station placed: Within Site. Data recorded for various parameters are: ContentTemp. (°C)Relative Humidity (%)Wind Speed (m/s)Wind Direction (From) Average28.837.73.4NW Meteorological Station at site

15. Kadam Environmental Consultants 15 STUDY AREA AND SAMPLING LOCATIONS Not to Scale Also revalidated Baseline Environmental Monitoring Data in Summer 2016 & it founds to be same as already collected data of Summer 2013.

16. 16 Kadam Environmental Consultants BASELINE DATA FOR AIR QUALITY Ambient Air Quality of 10 Locations within study area are tabulated below: Station Details (Km/ Direction) Parameters & Average Results Note: All units are in µg/m 3 except CO, which is in mg/m 3. Figures in brackets indicate CPCB limits. Minimum Reportable Readings are 8 µg/Nm 3 for SO 2, 10 µg/Nm 3 for NO X, 20 µg/Nm 3 for Ammonia, 0.1 µg/Nm 3 for HF, 800 µg/m 3 for HC, 10 µg/m 3 for NMHC, 1.145 mg/Nm 3 for CO and 1 ppm for VOC (CPCB Limits) PM 10 (100) PM 2.5 (60) SO 2 (80) NO x (80) NH 3 (400) HF CO (4 mg/m 3 ) HCNMHC Benzene including VOC [24 Hours] NS[1 Hour][1 Hr] [Annual] AA1: At Project Site 57278.413.228.4<0.1<1134412< 1 ppm AA2: At Zuarinagar (2.26 / E) 61338.913.622.9<0.1<1123912< 1 ppm AA3: At Bogmalo (3.07 / W) 58318.514.2<20<0.1<1112112< 1 ppm AA4: At Sancoale (2.48 / N) 54288.814.8<20<0.1<1109215< 1 ppm AA5: At Pale (1.34 / SE) 57298.815.1<20<0.1<1120011< 1 ppm AA6: At Consaulim (3.93 / SE) 58308.713.9<20<0.1<1114113< 1 ppm AA7: At Verna (5.94 / ESE) 54308.312.9<20<0.1<1111114< 1 ppm AA8: At Nagoa (4.7 / ENE) 57308.112.9<20<0.1<1117411< 1 ppm AA9: At Cortalim (4.89 / NE) 57308.813.7<20<0.1<1111011< 1 ppm

17. BASELINE DATA FOR SURFACE WATER 17 Kadam Environmental Consultants CodeLocation Date of Sampling Source Distance (in Km) & Direction w.r.t Project Site Sampling Rational SW 1Consaulim01/05/13Marine5.0 / SE To check water quality SW 2Zuari04/05/13Estuary4.0 / N SW 3Madkai05/05/13River8.0 / NE SW 4Verna01/05/13Pond9.65 / E SW 5Pale03/05/13Stream1.83 / SE SW 6Zuari04/05/13Dam1.9 / NNE Baseline Data of Surface Water in the study area:

18. 18 Kadam Environmental Consultants DATA FOR SURFACE WATER Analysis Result of Marine Water Sample * As per IS 10500:2012 Standard Limits for drinking water (2 nd Revision) S. No. Parameters Unit Classification for Costal Water Marine (CPCB) Sampling Locations SW1 Consaulim SW-ISW-IISW-IIISW-IVSW-VResult 1pH-6.5 to 8.5 6.0 to 9.0 8.06 2Total Dissolved Oxygenmg/l5.04.03.0 4.3 3Colour and Odour- No Colour No Odour No Colour 4Floating Mattersmg/lNone 10-None 5Suspended Solidsmg/l None from Sewage or Industrial waste Origin ----196 6TurbidityNTU-30 --1.2 7BODmg/l-3-5-20 8 Oil and Grease (including Petroleum Products) mg/l0.1----<0.4 9Mercury (as Hg)mg/l0.001----<0.001 10Lead (as Pb)mg/l0.001----0.533 11Cadmium (as Cd)mg/l0.01----0.026 12Dissolved Iron (as Fe)mg/l--0.5--1.1 13 Dissolved Manganese (as Mn) mg/l--0.5--<0.01 14Faecal Coliformml (MPN)-100/100500/100 4300 15 Sludge Deposits, Solid refuse floating Solids, Oil Grease and Scum ----- None except for treated Sewage and Industrial waste Effluent None Continue..

19. 19 Kadam Environmental Consultants ClassDesignated Best Use SW-ISalt SW-IIBathing, Contact Water Sports and Commercial Fishing SW-IIIIndustrial Cooling, Recreation (Non-contact) and Aesthetics SW-IVHarbor SW-VNavigation and Controlled Waste Disposal Class of Marine water body as per CPCB Guideline: Continue..

20. 20 Kadam Environmental Consultants Analysis Results for River Water Samples S. No. ParametersUnit Classification for Inland Surface Water (CPCB) Sampling Code SW2SW3 ABCDEResult 1pHpH Scale6.5 to 8.5 6.0 to 9.06.5 to 8.5 8.47.95 2Total Dissolved Oxygenmg/l6.05.04.0 NS3.64.1 3BODmg/l2.03.0 NS 27.09.0 4Sodium Absorption Ratiomg/gmNS 26(Max)48.538 5Electrical Conductivityμmoh/cmNS 5336052380 6Free NH 3 mg/lNS 1.2NS<0.014.56 7Boron as Bmg/l-----67 8Total Dissolved Solidsmg/l500-1500-2100 3600835608 9Chlorides(as CL)mg/l250-600- 1843417983 10Sulphatemg/l400- -1000 1258 11ColourPt.co----- 34 12Nitrate (as NO 3 )mg/l20-50-- 2.322.39 13Arsenicmg/l0.050.2 -- <0.001 14Ironmg/l0.3-50-- 0.340.49 15Fluoridemg/l1.5 -- 2.552.12 16Leadmg/l0.1- -- 0.244 0.01 17Coppermg/l1.5- -- 0.0860.079 18Zincmg/l15- -- 0.210.037 19Total ColiformMPN/100ml505005000-- 5400024000 Classification of river water as per their intended use: ADrinking water source without conventional treatment but after disinfection BOutdoor bathing (organized) CDrinking water source without conventional treatment followed by disinfection DPropagation of wildlife, fisheries EIrrigation, industrial cooling, controlled waste disposal Continue..

21. 21 Kadam Environmental Consultants Continue.. Analysis Results for Surface Water Samples S. No.ParametersUnit IS 10500:2012 Standard Limits for drinking water (2 nd Revision) Sampling Code, Location & Source SW4SW5SW6 VernaPaleZuari Acceptable LimitPondStreamDam 1pHpH scale6.5 - 8.5 7.977.296.98 2Temperature o C-29.329.630 3TurbidityNTU1<0.1 1 4TDSmg/lit500801573248 5Electrical conductivityµmhos/cm-109.32514085.6 6CODmg/lit-48128 7BODmg/lit-1232 8Ammonical Nitrogenmg/lit-<0.011.990.29 9Phenolmg/lit0.001<0.001 10Chloridesmg/lit25023829514 11Sulphatesmg/lit200121533 12SAR--0.347.901.04 13Total Hardnessmg/lit20060145040 14Ca++ Hardnessmg/lit-209818 15Mg++ Hardnessmg/lit-40135222 16Total Alkalinitymg/l200 10040 17Nitratemg/l4550.325.81 18Fluoridemg/l10.321.750.34 19Sodiummg/l-6.14223.004.10 20Potassiummg/l-1.1127.30.95 21Calciummg/l75839.37.21 22Magnesiummg/l309.7329.005.35

22. 22 Kadam Environmental Consultants S. No.ParametersUnit IS 10500:2012 Standard Limits for drinking water (2 nd Revision) Sampling Code, Location & Source SW4SW5SW6 VernaPaleZuari Acceptable LimitPondStreamDam 23Salinitymg/l-41.51494824.91 24Total Nitrogenmg/l-1.312.241.68 25Total Phosphorousmg/l-<0.11 26Dissolved Oxygenmg/l-3.43.83.2 27Heavy Metals aArsenic (as As)mg/l0.01<0.001 bCadmium (as Cd)mg/l0.0030.0050.100<0.001 cCromium (as Cr)mg/l0.050.002<0.001 dCopper (as Cu)mg/l0.050.0050.0030.004 eCyanide (as CN)mg/l0.05<0.001 fIron (as Fe)mg/l0.31.2000.9000.720 gLead (as Pb)mg/l0.010.5800.0060.468 hMercury (as Hg)mg/l0.001<0.001 iManganese (as Mn)mg/l0.1<0.001 jNickel (as Ni)mg/l0.020.0240.2640.013 kZinc (as Zn)mg/l50.3650.2840.311 28Total ColiformMPN/100 mlShall not be detectable in any 100 ml sample35000120009400 29Faecal ColiformsMPN/100 ml-1700063004900 Continue..

23. BASELINE DATA FOR GROUND WATER 23 CodeLocation Date of Sampling Source Distance (in Km) & Direction w.r.t Project Site Sampling Rational GW 1 At Project Site 30/04/13Borewell0.0 To check groundwater quality within study area. GW 2Zuarinagar03/05/13Dugwell3.0 / ESE GW 3Bogmalo30/04/13Handpump4.0 / WSW GW 4Chicolna30/04/13Borewell1.25 / WSW GW 5Pale30/04/13Dugwell1.83 / SE GW 6Consaulim30/04/13Dugwell3.93 / SE GW 7Sancoale01/05/13Dugwell2.48 / N GW 8Nagoa30/04/13Dugwell6.0 / ESE GW 9Cortalim03/05/13Dugwell6.0 / NE GW 10Verna03/05/13Borewell5.94 / ESE Baseline Data of Ground Water in the study area:

24. 24 Kadam Environmental Consultants DATA FOR GROUND WATER S. No. ParametersUnit Acceptable Limit* Sampling Code GW1GW2GW3GW4GW5GW6GW7GW8GW9GW10 1 pH pH scale 6.5 - 8.56.953.576.908.277.057.377.296.97.218.01 2 Temp. oCoC -30.130.329.830.630.231.929.629.830.2 3 Turbidity NTU 1<0.1 4 TDS mg/lit 5001885212412812201289612452124 5 EC µmho/cm -30971.2190.7203.42070204.8139172.474178.3 6 COD mg/lit -<4 7 BOD mg/lit -<1 8 Ammonical Nitrogen mg/lit -1.371.161.45<0.01 0.550.87<0.01 9 Phenol mg/lit 0.001<0.001 10 Chlorides mg/lit 250611138 5374846551846 11 Sulphates mg/lit 20017163012958<0.16 1 12 SAR - -0.871.411.221.194.630.901.301.40.60.4 13 Total Hardness mg/lit 20013030801003307030402090 14 Ca++ Hardness - -908405640 1418638 15 Mg++ Hardness mg/lit -402240442903016221452 16 Total Alkalinity mg/lit 2003010203001601201003080240 17 Nitrate mg/lit 450.190.710.060.5831.84.842.935.731.810.65 18 Fluoride mg/lit 1<0.006 0.210.070.010.090.02 19Sodium mg/lit -11.505.0014.89.6229.017.2016.5020.46.58.7 * IS 10500:2012 Standard Limits for drinking water (2 nd Revision) Continue..

25. 25 Kadam Environmental Consultants S. No. ParametersUnit Acceptable Limit* Sampling Code GW1GW2GW3GW4GW5GW6GW7GW8GW9GW10 20Potassium mg/lit -5.915.81.0512.22.95.43.61.11.8 21Calcium mg/lit 7536.073.2116.0322.4416.03 5.67.22.415.2 22Magnesium mg/lit 309.725.359.7210.6970.477.294.005.33.412.6 23 Salinity mg/lit -110.4519.5467.97 968.5686.248399.733.283 24 Total Nitrogen mg/lit -1.491.311.490.197.471.68 8.210.560.19 25 Total Phosphorous mg/lit -<0.11 26 Dissolved Oxygen mg/lit -3.93.84.13.64.33.13.43.84.23.6 27 Heavy Metals a Arsenic (As) mg/l 0.01<0.001 b Cadmium (Cd) mg/l 0.0030.0110.002 <0.001 0.0030.030.0050.0040.094 c Chromium (Cr) mg/l 0.05<0.001 d Copper (Cu) mg/l 0.05<0.001 0.0150.0040.003<0.0010.058<0.001 0.024 e Cyanide (CN) mg/l 0.05<0.001 f Iron (Fe) mg/l 0.30.280<0.0010.3920.0830.3210.0520.0140.032<0.0010.14 g Lead (Pb) mg/l 0.010.021<0.0010.0470.0120.0220.0430.011<0.0010.0020.007 h Mercury (Hg) mg/l 0.001<0.001 i Manganese (Mn) mg/l 0.1<0.001 j Nickel (Ni) mg/l 0.02<0.001 0.023<0.001 0.026<0.0010.01 k Zinc (Zn) mg/l 50.0560.0460.1200.4600.0950.2160.0080.0990.0670.018 28 Total Coliform MPN Shall not be detectable in any 100 ml sample <1.8 29 Faecal Coliforms MPN -<1.8 Continue.. * IS 10500:2012 Standard Limits for drinking water (2 nd Revision)

26. 26 Kadam Environmental Consultants BASELINE DATA FOR NOISE LEVELS Ambient Noise Level in Study Area Station Code Noise Monitoring Location Date of Monitoring Category of Area/Zone Distance (in Km) & Direction from Project Site CPCB Limits in dB (A) Average Noise levels in dB (A) Leq Day Time Hours [06:00 to 22:00] Night Time Hours [22:00 to 06:00] Day Time Hours [06:00 to 22:00] Night Time Hours [22:00 to 06:00] NL 1 At Project Site (Lab) 29.04.13Industrial0.075.070.069.257.5 NL 2 At Project Site (Near Main Gate) 29.04.13Industrial0.075.070.052.749.6 NL 3 At Project Site (Near Material entry gate) 30.04.13Industrial0.075.070.056.549.7 NL 4 At Project Site (Near ETP plant) 02.0513Industrial0.075.070.053.150.9 NL 5 At Project Site (Gate No. 1) 02.0513Industrial0.075.070.056.850.1 NL 6Zuarinagar24.04.13Residential2.26 / E55.045.062.651.9 NL 7Bogmalo03.04.13Residential3.07 / W55.045.060.447.5 NL 8Sancoale25.04.13Residential2.48 / N55.045.053.248.9 NL 9Pale24.04.13Residential1.34 / SE55.045.049.141.3 NL 10Verna27.04.13Residential5.94 / ESE55.045.054.346.6

27. 27 Kadam Environmental Consultants BASELINE DATA FOR SOIL SAMPLES CodeLocation Date of Sampling Source Distance from Project Site in Km Direction w.r.t Project Site Justification ST 1At Project Site13/05/13Industrial0.0 Base Station To check surface soil quality at core area. ST 2Zuarinagar13/05/13Residential2.26E To check surface soil quality within study area ST 3Chicalim04/05/13Residential1.5NW ST 4Bogmalo01/05/13Residential3.07W ST 5Sancoale04/05/13Residential2.48N ST 6Pale30/04/13Residential1.34SE ST 7Consaulim30/04/13Residential3.93SE ST 8Verna01/04/13Residential5.94ESE ST 9Nagoa01/04/13Residential4.7ENE ST 10Cortalim30/04/13Residential4.89NE

28. 28 Kadam Environmental Consultants BASELINE DATA FOR SOIL SAMPLES S. No ParameterUnit Sampling Location At Project Site ZuarinagarChicalimBogmaloSancoalePaleConsaulimVernaNagoaCortalim 1Porosity% 40384850414046535258 2WHC %39.5140.4365.6368.7546.6143.0565.8164.8868.0170.98 3Permeabilitycm/sec.1.07x 10 -3 1.66x 10 -3 6.81x 10 -4 2.07x 10 -4 9.22x 10 -4 1.66x 10 -3 6.96x 10 -4 3.61x 10 -4 7.72x 10 -5 4Moisture%8.648.799.8910.759.56.929.689.8410.7812.03 5 Particle Size Distribution - aSand%88.8487.8470.5641.8485.8488.8470.5657.5652.8414.12 bClay%4.166.884.888.764.88 12.1611.1614.1638.60 cSilt%7.005.2824.5649.409.286.2817.2831.2833.0047.28 6Texture - Loamy Sand Sandy Loam Silty Loam Loamy Sand SandSandy Loam Loam Silty Clay Loam 7ESP<0.01 0.33<0.01 0.01<0.01 8 Cation Exchange Capacity mg/100gm13.6014.4021.2024.4014.4016.0021.6020.4015.2016.20 9ECμmohs/cm0.7070.468 0.2830.9870.4120.3780.4250.7070.996 Continue..

29. 29 Kadam Environmental Consultants S. No ParameterUnit Sampling Location At Project Site ZuarinagarChicalimBogmaloSancoalePaleConsaulimVernaNagoaCortalim 10 Organic Carbon % -- 11pH 6.016.256.836.407.266.716.506.653.514.80 12Calcium0.370.22 0.060.370.191.120.210.100.40 13Magnesium-0.510.300.250.400.171.440.150.170.090.53 14Sodiumgm/kg0.320.180.190.080.450.150.140.170.220.30 15Potassiumgm/kg0.111.520.100.020.140.040.600.060.030.02 16Fluoridegm/kg0.020.03<0.00010.02<0.00010.03 <0.0001 Continue..

30. DATA FOR THE STACK EMISSIONS 30 Kadam Environmental Consultants Air emission parameters as prescribed in latest consent orders by GSPCB were monitored for  11 stacks (5 flue gas stacks and 6 stacks attached to vents, reactors and process vessels) in all plants. It was found that all the parameters are well within the prescribed standards. Monitoring results were compared with latest available third party report, monthly monitoring reports by ZACL. No abnormal emissions were reported in secondary data.

31. DATA FOR THE STACK EMISSIONS 31 Kadam Environmental Consultants Summary of Stack Emissions Continue.. ParameterPMSO 2 NO x NH 3 NMHC (as C)CO Prescribed Limit 150 mg/Nm 3 (General) / 800 mg/Nm 3 of 6 MW CPP + MP Boiler (Common Stack) 832 Kg/Hr. of Power Station Boilers/ 30.4 Kg/Hr. of 6 MW CPP + MP Boiler / 105.6 Kg/Hr. of DG Set 1100 ppmv (as 15% O 2 ) Dry basis in ppmv of DG Set 10 kg/Hr. 150 mg/Nm 3 (as 15% O 2 ) Minimum 14 mg/Nm 3 at NPK-A Plant Dryer Stack 6.19 Kg/Hr. at DG Set 155.84 ppmv at DG Set 1.03 kg/Hr. at NPK-A Plant Fumes Stack 5.19 mg/Nm 3 at DG Set 6.47 mg/Nm 3 at DG Set Maximum 95.91 mg/Nm 3 at Power Station Boiler 235.16 Kg/Hr. at Power Station Boiler 253.92 ppmv at Power Station Boiler --

32. 32 Kadam Environmental Consultants Impact on Air Environment, Impact Zone, Mitigation Measures with Management Plan: S No. Expected Aspect due to Proposed Activity Impact ZonesMitigation Measures / Management Plan Air Environment 1 PM, SO 2, NO x & NH 3 emissions from Rotary dryer/ Co-current dryer 250 to 1,000 meters in predominant wind direction  Provision of adequate stack height ~ 30 m will be ensured;  Ensure periodic monitoring of stacks for parameters prescribed by GSPCB. 2 Dispersion of Ammonia in atmosphere 1,500 meters in predominant wind direction  Provision of dyke wall with Fixed foam system, flare system, interlock and safety valves will be ensured;  Proper operation will be ensured;  Appropriate onsite plan will be put in place. Also offsite plan will be strictly adhered to. 3 NO x & SO 2 emissions from GT/HRSG operation 250 to 1,000 meters in predominant wind direction  Provision of Dry Low NO x Combustors will be ensured;  Provision of adequate stack height ~ 30 m will be ensured;  Ensure periodic monitoring of stacks for SO 2 & NO x concentrations. IMPACT ON AIR QUALITY

33. 33 Kadam Environmental Consultants S No. Expected Aspect due to Proposed Activity Impact ZonesMitigation Measures / Management Plan Air Environment 4 PM & NH 3 from Urea Granulation. 250 to 1,000 meters in predominant wind direction  Provision of Wet scrubber will be ensured;  Provision of adequate stack height ~ 40 m will be ensured;  Ensure periodic monitoring of stacks for parameters prescribed by GSPCB. 5 Dust generation due to Transportation activity. Nearby Villages & Roads  Transportation of raw materials and finished goods will be carried out in covered trucks. IMPACT ON AIR QUALITY Continue..

34. 34 Kadam Environmental Consultants INCREMENTAL GLC’s DUE TO PROPOSED PROJECT Maximum Ground Level Concentrations (GLC’s) of all expected pollutants: S No. Parameters Number of Sources Maximum GLC Concentration, µg/m 3 Distance, mDirection 1PM 10 42.57500E 2NO x 21.39500N 3SO 2 20.08500N 4Ammonia20.851500E

35. 35 Kadam Environmental Consultants IMPACT ON NOISE ENVIRONMENT Impact on Noise Environment, Impact Zone, Mitigation Measures with Management Plan: S No. Expected Aspect due to Proposed Activity Impact Zones Mitigation Measures / Management Plan Noise Environment 1 Noise generation due to construction activities. At site  Properly certified, tested and calibrated equipment will be used;  Ear muffs and ear plugs will be provided to workers. 2 Noise generation due to operation of various equipment like pumps, blowers, compressors, gas turbine, DG Sets and due to popping up of safety valves At site  At design stage, procurement of low noise equipment will be ensured;  Proper engineering control measures will be taken;  Periodic maintenance of equipment shall be ensured;  Adequate acoustic enclosures will be placed;  Green belt of more than 33 % will be maintained around the site.

36. 36 Kadam Environmental Consultants IMPACT ON WATER & LAND ENVIRONMENT Impact on Water Environment, Impact Zone, Mitigation Measures with Management Plan: S No. Expected Aspect due to Proposed Activity Impact ZonesMitigation Measures / Management Plan Water Environment 1 Overflow of surface water Nearest water bodies  Ensuring periodic monitoring;  Storm water management;  Rain water harvesting for storage. 2 Monitoring of ETP & STPWithin site  Ensuring periodic monitoring;  Reuse & recycle scheme;  Zero Liquid Discharge will be maintained. Land Environment 1 Chemical spillage Around the project site  Ensuring monitoring during Pre & post monsoon and in the event of accidental spillage.

37. 37 Kadam Environmental Consultants IMPACT ON SOCIAL ENVIRONMENT Impact on Social Environment, Impact Zone, Mitigation Management with Management Plan: Well established Environmental Management Cell is in place having professional expertise to discharge responsibilities related to environmental management including statutory compliance, pollution prevention, environmental monitoring, etc. S No. Expected Aspect due to Proposed Activity Impact ZonesMitigation Measures / Management Plan Social Environment 1 Job opportunities, ancillary developments in and around project site and CSR activities. No Negative Impacts is envisaged.  Timely approval of funds for new and proposed CSR activities.

38. SAFETY PERFORMANCE (Last 5 Years) 38 Kadam Environmental Consultants Reportable Incidents, Fire & Chemical Leakage Education & Training Safety Related Activities & Record Frequency Rate = (No. of incidents x 10 6 )/Total man-hours of exposure Severity Rate = (Total no. of days lost x 10 6 )/Total man-hours of exposure Frequency & Severity Rate Analysis All fire and leakage incidents were minor in nature. Mock drills/ Off site drills/ Fire drills/ Mutual aid drills conducted in last five year.

39. 39 Kadam Environmental Consultants Safety Awards  Gomant Sarvochcha Suraksh Puraskar in 2009 by Green Triangle Society-Goa  Most Outstanding Safety Performance In Occupational Safety, Health & Environment (First Prize) by Green Triangle Society-Goa in 2012  Gomant Uchcha Suraksha Puraskar” from Green Triangle Society for the Outstanding Safety Performance in Occupational Safety, Health & Environment in 2015 Safety Awards  Gomant Sarvochcha Suraksh Puraskar in 2009 by Green Triangle Society-Goa  Most Outstanding Safety Performance In Occupational Safety, Health & Environment (First Prize) by Green Triangle Society-Goa in 2011  Gomant Sarvochcha Suraksh Puraskar on 2011 by Green Triangle Society-Goa  Gomant Suraksh Puraskar, 2013 by Green Triangle Society for achieving Good Performance in Safety  Gomant Uchcha Suraksha Puraskar” from Green Triangle Society for the Outstanding Safety Performance in Occupational Safety, Health & Environment in 2015

40. 40 Kadam Environmental Consultants Safety Awards  Gomant Sarvochcha Suraksh Puraskar in 2009 by Green Triangle Society-Goa  Most Outstanding Safety Performance In Occupational Safety, Health & Environment (First Prize) by Green Triangle Society-Goa in 2012  Gomant Uchcha Suraksha Puraskar” from Green Triangle Society for the Outstanding Safety Performance in Occupational Safety, Health & Environment in 2015 Plaque of Excellence - 2 nd place in ‘Best Environmental Practice Competition’ by Goa State Pollution Control Board in 2014 Environment Award

41. 41 Kadam Environmental Consultants GREEN BELT MANAGEMENT Green Belt Area – Management and Development ZACL has achieved ‘Best Plantation Puraskar’ from Govt. of Goa during 1997-98. Species: Decorative Plants, Flowering Plants, Fruit Trees and Other Plant Species. Sr. No.SpeciesLocal Name 1Ashoka 2Banyan TreeWad 3Coconut PalmNaral 4Copper PodPivla Gul Mohur 5Devil’s TreeSatvin 6Goda NeemGoda/ Bakan Neem 7Gul Mohur 8Indian Cork TreeAkash Nimb 9Indian Mast TreeAshoka 10Jack FruitFanas 11Kanchan 12KudaKudo/ Kuda 13Mango TreeAmbo/ Amba 14Pangara 15Parijatak 16Queen’s FlowerBondara 17Rain TreeVilaiti Siris 18Royal PalmBottle/ Royal Palm 19Scarlet CordiaBhokar 20Sesbania GrandifloraAgasthi 21Silk Cotton TreeSavri 22Tamarnd TreeChinch 23Tabebuia RoseNil

42. 42 Kadam Environmental Consultants RAIN WATER HARVESTING/RECHARGING Information on Existing Dam: Zuari Dam Reservoir Catchment AreaCapacityLengthDepth 72 Ha1.1356 Million m 3 340 Meter22.86 Meter

43. 43 Kadam Environmental Consultants ENTERPRISE SOCIAL COMMITMENT (ESC) Various community development/Social Welfare activities will be implemented with a total provision of Rs. 20 crore (approx.) of the capital expenses for the next 10 years within 10 km of proposed project area. S. No.Proposed ActivityAmount (Rs. Lakhs) per year 2016- 2017 2017- 2018 2018- 2019 2019- 2020 2020- 2021 2021- 2022 2022- 2023 2023- 2024 2024- 2025 2025- 2026 Total Amont 1 Development of Children’s Play Ground with Sports Equipment 10.5011.5512.7113.9815.3716.9118.6020.4622.5124.76167.34 2 Provision of Safe Drinking Water Facility in Balwadi and Primary Schools 8.509.3510.2911.3112.4413.6915.0616.5618.2220.04135.47 3Renovation of Anganwadi or Balwadi10.7511.8313.0114.3115.7417.3119.0420.9523.0425.35171.33 4 Supply of Plastic Chairs for Balwadi& Primary schools 8.759.6310.5911.6512.8114.0915.5017.0518.7620.63139.45 5 Scholarship to Meritorious Students for Higher Education 9.5010.4511.5012.6413.9115.3016.8318.5120.3622.40151.41 6 Up gradation of School Infrastructure, Equipment 9.7510.7311.8012.9814.2715.7017.2719.0020.9022.99155.39 7 Promotion and improvement in living standard of Fisherman Community 7.007.708.479.3210.2511.2712.4013.6415.0116.51111.56 8 Immunization Program/Medical or Health Check-up Camps (Twice a Year) 6.507.157.878.659.5210.4711.5212.6713.9315.33103.59 9 Garbage Collection & Management system 11.2512.3813.6114.9716.4718.1219.9321.9224.1226.53179.30 10Renewable Energy Lighting5.756.336.967.658.429.2610.1911.2112.3313.5691.64 11 Up gradation of Water tank capacity/Water Supply System/ R.O. System 10.7511.8313.0114.3115.7417.3119.0420.9523.0425.35171.33 12 Horticulture Entrepreneurship Development 6.507.157.878.659.5210.4711.5212.6713.9315.33103.59 13 Construction of Public Toilet (Community Toilets) 12.5013.7515.1316.6418.3020.1322.1424.3626.7929.47199.22 14Cleaning of Drainage, Ponds and Wells7.508.259.089.9810.9812.0813.2914.6216.0817.68119.53 125.50138.05151.86167.04183.74202.12222.33244.56269.02295.922000.15 Total provision for 10 years Rupees Twenty Crore and Fifteen Thousand Only (Approx. 20 Crore)

44. EXISTING CSR ACTIVITIES 44 Kadam Environmental Consultants Year 2014-15 S. NoDescriptionLocationYearAmount (INR) 1Supply of drinking water @ 50m 3 per day @ Rs 33 per m 3 Dando & Belem village2014-152,37,600/- 2Renovation of childrens park at Vasco Municipal parkVascoDec-149,50,000/- 3Maintenance of the median along NH-17BZuarinagar (Sancoale)Year round 8,50,000/- 4Scholorship of meritious students in 10 th & 12 th std.Zuarinagar (Sancoale)Jul-1434,000/- 5Laying of new water pipelineDando villageJul-141,30,000/- Total22,01,600/- Year 2015-16 S. NoDescriptionLocationYearAmount (INR) 1Painted Panchayat OfficeVelsaoNov-151,30,000/- 2Construction of toilet for Govt. Primary schoolZuarinagar (Sancoale)Aug-154,80,000/- 3Supply of drinking water @ 50m 3 per day @ Rs 33Dando & Belem village2015-162,37,600/- 4Donated land for setting of garbage management system-1000 Sqmts.Zuarinagar (Sancoale)Dec-1550,00,000/- 5 Donated land for setting of community center to Goa Rehabilitation Centre 1000 sqmts Zuarinagar (Sancoale)Dec-1550,00,000/- 6 Setting up of Skill Development Centre in trades like Electrician, Data operator, Sewing Zuarinagar (Sancoale)Jan-169,00,000/- 7 Donated land around 100 sq mts of land for setting up Sulabh sauchalayas at 3 locations Zuarinagar (Sancoale)May-1515,00,000/- 8Maintenance of median along NH-17B strech of 4 KmZuarinagar (Sancoale)Year Round8,50,000/- 9 Working in association with Vasco Industrial training Institute to impart added skill in new trade AOCP involving our manpower to conduct classes for the students Vasco- ITIFeb-1660,000/- 10 Conducting various activities on health and hygeine with NGO Margadarshak Zuarinagar (Sancoale)Sep 15-March’168,00,000/- Total1,49,57,600/-

45. 45 Kadam Environmental Consultants ENVIRONMENTAL MANAGEMENT CELL & REPORTING MECHANISM Hierarchy of Environmental Management Cell:  ZACL have a system of reporting of non compliance / violations of environmental norms to the board of Directors of the company.  Meetings are conducted to review the status of non compliances as mentioned below: Daily: General meeting, department wise. Once in 2 months: Board meeting. Yearly: ISO 14001 review meeting.

46. JUSTIFICATION OF THE PROJECT 46 Kadam Environmental Consultants  “Modernization” of the Complex to enhance Safety, reduce Risk and to be Environment Friendly in all the components of the proposed Project  Continuance of the ZERO Liquid Discharge (ZLD) Status of the Complex  Conservation of precious Natural Resources – Natural Gas and Water  Application of “State of Art” Technologies  Emission level will continue to be maintained well within the GSPCB/CPCB Norms  Employment potential includes skilled, semi-skilled and unskilled labourers both during construction and operational phases of the project with specific attention to employment potential of local population.  Other tangible benefit includes improved standards of living, health and education and upgrade the socio-economic level of residents of study area.

47. INFRASTRUCTURE FACILITIES 47 Kadam Environmental Consultants Existing Facility  Sufficient Land is available for putting up project;  Manpower including security;  Energy infrastructure like power generation unit & emergency backup;  Water infrastructure;  Internal communication facilities;  Township with amenities like Bank, ATM, Post Office, sport and recreation club etc. Connectivity  Well connected with National Highway – 17B & local road;  Having own Railway lines for mobility of products.

48. CONCLUSION 48 Kadam Environmental Consultants The production of Urea, Customized NPK will be beneficial for the farming community in meeting the increasing demands of Fertilizer in the state and country. Appropriate air pollution abatement systems, adequacy check for treatment of waste water generation in ETP’s and hazardous waste management and Properly certified, tested and calibrated equipment will be used which leads to very negligible environmental impact which can be mitigated by taking preventive measures. Any abnormal and emergency situations can be handled by well experienced staff of ZACL as identified in onsite and offsite emergency plans with well-equipped safety equipment and fire hydrant network. Based on the baseline studies as per ToR issued by MoEFCC, there are no sensitive areas located in study area. No endangered or threatened species of flora and fauna are reported. Critically polluted areas or industries are not located in the study area. Project will bring pride to the State and Country. Overall, the EIA study has concluded that the Project would be environmentally acceptable, in compliance with environmental legislation and standards. Hence the Proposed Projects deserve to be considered for getting Environmental Clearance.

49. 49 Kadam Environmental Consultants

50. 50 Kadam Environmental Consultants Backup Slides

51. Kadam Environmental Consultants SITE LAYOUT MAP 51 P.S

52. LAND DISTRIBUTION BREAK UP 52 Kadam Environmental Consultants S No.TitleArea in m 2 Existing Coverage Calculation 1Existing Coverage1,21,453.09 2Area to be demolished188.41 3Proposed Coverage1,511.61 4Total area covered on ground1,22,776.29 Total Coverage-- Existing FAR Calculation 5Existing floor area1,31,794.85 6Area to be demolished188.41 7Proposed floor area1,588.79 8Total floor area1,33,195.23 Total FAR-- 9Open space required 15%61,113.75 10Open Space proposed1,29,658.00 PROPOSED 1Customized NPK Grade1,125 2GT1,952 3HRSG1,860 4Atmospheric Ammonia Storage Tank7,999 5Urea Granulation Unit1,500 Total14,436 P.S

53. LIST OF EXISTING AND PROPOSED PRODUCTS 53 Kadam Environmental Consultants P.S S. No. Plant Capacity, MT (Existing) Capacity, MT (Proposed) Capacity Total, MT (Post-Expansion) 1Urea 1500 (All Prilling) -300 (Prilling) +600 (New Granulation Plant) 1200 (Prilling)+ 600 (Granulation) = 1800 2 Complex Fertilizers produced in NPK A Plant 16000 3 Complex Fertilizers produced in NPK B Plant 16000 4Ammonia10500 5By-Products: CO 2, Argon 104 & 2.2 Million Sm 3 0 6 Horton Sphere Ammonia Storage tank 3000 (1+1) Atmospheric Ammonia Storage Tank 1X5000 7Customized Blending Plant030 MTPH 8Gas Turbine025 MW 9 Heat Recovery Steam Generator 0 Generation of MP Steam (37 Kg/Cm 2 g) - Capacity (Unfired with supplementary firing) = 50 /70 MT/hr.

54. 54 EXPENDITURE ON ENVIRONMENTAL MATTERS Total Cost of the project is INR 788.60 Crore. S No.Head Approx. Capital Cost (INR Crore) Approx. Recurring Cost per Annum (INR Crore) 1Air Environment9.20.81 2Water Environment--0.04 3Noise Environment1.10.05 4Soil Pollution Control0.050.001 5Green Belt--0.01 Total10.350.91 P.S

55. SITE SPECIFIC METEOROLOGICAL DATA (2016) 55 Kadam Environmental Consultants Study period: Summer Season 2016 (March 2016 – May 2016). Site specific data were considered as a Secondary Source from long term climatological tables (1961-1990) for nearest station from site (Marmugao Taluka, Station ID: 43196) published by Indian Meteorological Department (IMD). Meteorological station placed: Within Site. Data recorded for various parameters are: ContentTemp. (°C)Relative Humidity (%)Wind Speed (m/s)Wind Direction (From) Average30.366.13.8NW Meteorological Station at site

56. 56 Kadam Environmental Consultants BASELINE DATA FOR AIR QUALITY (2016) Ambient Air Quality of 10 Locations within study area are tabulated below: Station Details (Km/ Direction) Parameters & Average Results Note: All units are in µg/m 3 except CO, which is in mg/m 3. Figures in brackets indicate CPCB limits. Minimum Reportable Readings are 8 µg/Nm 3 for SO 2, 10 µg/Nm 3 for NO X, 20 µg/Nm 3 for Ammonia, 0.1 µg/Nm 3 for HF, 800 µg/m 3 for HC, 10 µg/m 3 for NMHC, 1.145 mg/Nm 3 for CO and 1 ppm for VOC (CPCB Limits) PM 10 (100) PM 2.5 (60) SO 2 (80) NO x (80) NH 3 (400) HF CO (4 mg/m 3 ) HCNMHC Benzene including VOC [24 Hours] NS[1 Hour][1 Hr] [Annual] AA1: At Project Site 59.023.08.113.318.9< 0.1<1122622< 1 ppm AA2: At Zuarinagar (1.1 / NNW) 58.022.08.112.722.4< 0.1<1128425< 1 ppm AA3: At D Colony (0.9 / SE) 60.624.88.510.040.5< 0.1<1110014< 1 ppm AA4: At Primary School (1.5 / E) 77.527.28.710.237.9< 0.1<1124417< 1 ppm AA5: At Jai Kisaan Club (1.6 / N) 66.625.99.410.839.8< 0.1<1107212< 1 ppm AA6: At C Colony (0.8 / NW) 49.324.58.710.437.6< 0.1<1104112< 1 ppm

57. Ambient Air Quality Stations (March 2014) by GSPCB 57 Kadam Environmental Consultants Station No.Location Results (in µg/m 3 ) RSPMSPMNO 2 SO 2 1Fuse Call Office, Vasco43.986.09.0BDL 2Nr. Fire Brigade Station- MPT, Vasco56.9121.9BDL * Considered as a secondary data (Within 10 km radius) Ambient Air Quality Data

58. BASELINE DATA FOR SURFACE WATER (2016) 58 Kadam Environmental Consultants CodeLocationSource Distance (in Km) & Direction w.r.t Project Site Sampling Rational SW 1ConsaulimMarine5.0 / SE To check water quality SW 2ZuariEstuary4.0 / N SW 3MadkaiRiver8.0 / NE SW 4VernaPond9.65 / E SW 5PaleStream1.83 / SE SW 6ZuariDam1.9 / NNE Baseline Data of Surface Water in the study area:

59. 59 Kadam Environmental Consultants DATA FOR SURFACE WATER (2016) Analysis Result of Marine Water Sample * As per IS 10500:2012 Standard Limits for drinking water (2 nd Revision) S. No. Parameters Unit Classification for Costal Water Marine (CPCB) Sampling Locations SW1 Consaulim SW-ISW-IISW-IIISW-IVSW-VResult 1pH-6.5 to 8.5 6.0 to 9.0 7.95 2Total Dissolved Oxygenmg/l5.04.03.0 4.4 3Colour and Odour- No Colour No Odour No Colour 4Floating Mattersmg/lNone 10- None 5Suspended Solidsmg/l None from Sewage or Industrial waste Origin ---- 175 6TurbidityNTU-30 -- 2.1 7BODmg/l-3-5- 6 8 Oil and Grease (including Petroleum Products) mg/l0.1---- <0.4 9Mercury (as Hg)mg/l0.001---- <0.001 10Lead (as Pb)mg/l0.001---- 0.096 11Cadmium (as Cd)mg/l0.01---- <0.001 12Dissolved Iron (as Fe)mg/l--0.5-- 0.895 13 Dissolved Manganese (as Mn) mg/l--0.5-- <0.01 14Faecal Coliformml (MPN)-100/100500/100 1100 15 Sludge Deposits, Solid refuse floating Solids, Oil Grease and Scum ----- None except for treated Sewage and Industrial waste Effluent None Continue..

60. 60 Kadam Environmental Consultants ClassDesignated Best Use SW-ISalt SW-IIBathing, Contact Water Sports and Commercial Fishing SW-IIIIndustrial Cooling, Recreation (Non-contact) and Aesthetics SW-IVHarbor SW-VNavigation and Controlled Waste Disposal Class of Marine water body as per CPCB Guideline:

61. 61 Kadam Environmental Consultants Analysis Results for River Water Samples S. No. ParametersUnit Classification for Inland Surface Water (CPCB) Sampling Code SW2SW3 ABCDEResult 1pHpH Scale6.5 to 8.5 6.0 to 9.06.5 to 8.5 8.127.95 2Total Dissolved Oxygenmg/l6.05.04.0 NS4.34.1 3BODmg/l2.03.0 NS 14.08.0 4Sodium Absorption Ratiomg/gmNS 26(Max)43.825.6 5Electrical Conductivityμmoh/cmNS 4850046300 6Free NH 3 mg/lNS 1.2NS<0.013.9 7Boron as Bmg/l-----2.73.71 8Total Dissolved Solidsmg/l500-1500-2100 3229627732 9Chlorides(as CL)mg/l250-600- 1622213180 10Sulphatemg/l400- -1000 3757 11ColourPt.co----- 45 12Nitrate (as NO 3 )mg/l20-50-- 4.97.22 13Arsenicmg/l0.050.2 -- <0.001 14Ironmg/l0.3-50-- 0.2960.426 15Fluoridemg/l1.5 -- 1.211.67 16Leadmg/l0.1- -- 0.1120.011 17Coppermg/l1.5- -- 0.0780.096 18Zincmg/l15- -- 0.1960.041 19Total ColiformMPN/100ml505005000-- 3500021000 Classification of river water as per their intended use: ADrinking water source without conventional treatment but after disinfection BOutdoor bathing (organized) CDrinking water source without conventional treatment followed by disinfection DPropagation of wildlife, fisheries EIrrigation, industrial cooling, controlled waste disposal Continue..

62. 62 Kadam Environmental Consultants Continue.. Analysis Results for Surface Water Samples S. No.ParametersUnit IS 10500:2012 Standard Limits for drinking water (2 nd Revision) Sampling Code, Location & Source SW4SW5SW6 VernaPaleZuari Acceptable LimitPondStreamDam 1pHpH scale6.5 - 8.5 7.17.427.23 2Temperature o C- 31 3TurbidityNTU1 <0.11.91.3 4TDSmg/lit500 62894150 5Electrical conductivityµmhos/cm- 91.51620091 6CODmg/lit- 2465 7BODmg/lit- 832 8Ammonical Nitrogenmg/lit- <0.012.080.14 9Phenolmg/lit0.001 <0.001 10Chloridesmg/lit250 18460918 11Sulphatesmg/lit200 81612 12SAR-- 0.427.600.79 13Total Hardnessmg/lit200 50113030 14Ca++ Hardnessmg/lit- 2211214 15Mg++ Hardnessmg/lit- 28101816 Total Alkalinitymg/l200 6012090 17Nitratemg/l45 51.484.77 18Fluoridemg/l1 0.21.660.2 19Sodiummg/l- 6.02145.007.40 20Potassiummg/l- 2.295.61.1 21Calciummg/l75 8.844.95.61 22Magnesiummg/l30 6.8247.003.89

63. 63 Kadam Environmental Consultants S. No.ParametersUnit IS 10500:2012 Standard Limits for drinking water (2 nd Revision) Sampling Code, Location & Source SW4SW5SW6 VernaPaleZuari Acceptable LimitPondStreamDam 23Salinitymg/l- 33.2830533.22 24Total Nitrogenmg/l- 1.122.431.31 25Total Phosphorousmg/l- <0.110.22<0.11 26Dissolved Oxygenmg/l- 4.44.24.0 27Heavy Metals aArsenic (as As)mg/l0.01 <0.001 bCadmium (as Cd)mg/l0.003 <0.001 cCromium (as Cr)mg/l0.05 <0.001 dCopper (as Cu)mg/l0.05 <0.001 eCyanide (as CN)mg/l0.05 <0.001 fIron (as Fe)mg/l0.3 0.8960.8520.541 gLead (as Pb)mg/l0.01 0.045<0.0010.049 hMercury (as Hg)mg/l0.001 <0.001 iManganese (as Mn)mg/l0.1 <0.001 jNickel (as Ni)mg/l0.02 0.0190.175<0.001 kZinc (as Zn)mg/l5 0.1520.3120.297 28Total ColiformMPN/100 mlShall not be detectable in any 100 ml sample 28000110007000 29Faecal ColiformsMPN/100 ml- 940046003300 Continue..

64. BASELINE DATA FOR GROUND WATER (2016) 64 CodeLocationSource Distance (in Km) & Direction w.r.t Project Site Sampling Rational GW 1BogmaloHandpump4.0 / WSW To check groundwater quality within study area. GW 2ChicolnaBorewell1.25 / WSW GW 3PaleDugwell1.83 / SE GW 4ConsaulimDugwell3.93 / SE GW 5SancoaleDugwell2.48 / N GW 6NagoaDugwell6.0 / ESE GW 7CortalimDugwell6.0 / NE GW 8VernaBorewell5.94 / ESE Baseline Data of Ground Water in the study area:

65. 65 Kadam Environmental Consultants DATA FOR GROUND WATER (2016) S. No. ParametersUnit Acceptable Limit* Sampling Code GW1GW2GW3GW4GW5GW6GW7GW8 1 pH pH scale 6.5 - 8.56.988.027.157.217.357.17.157.58 2 Temp. oCoC -31 3 Turbidity NTU 1<0.1 4 TDS mg/lit 500148130108516711816050111 5 EC µmho/cm -247225186520516322082184 6 COD mg/lit -<4 7 BOD mg/lit -<1 8 Ammonical Nitrogen mg/lit -0.98<0.01 0.260.66<0.01 9 Phenol mg/lit 0.001<0.001 10 Chlorides mg/lit 25047334906251741441 11 Sulphates mg/lit 200271775113413 12 SAR - -1.591.954.632.001.801.30.9 13 Total Hardness mg/lit 20010012033010050 70 14 Ca++ Hardness - -4450404220 430 15 Mg++ Hardness mg/lit -56702905830 4640 16 Total Alkalinity mg/lit 2003024070801106070150 17 Nitrate mg/lit 450.9 31.83.612.6422.382.061.42 18 Fluoride mg/lit 1<0.006 0.030.250.050.070.050.03 19Sodium mg/lit -20.014.0230.025.0030.0022.05.018.0 Continue.. * IS 10500:2012 Standard Limits for drinking water (2 nd Revision)

66. 66 Kadam Environmental Consultants S. No. ParametersUnit Acceptable Limit* Sampling Code GW1GW2GW3GW4GW5GW6GW7GW8 20Potassium mg/lit -4.1312.2512522.6 21Calcium mg/lit 75182016.0317881.612 22Magnesium mg/lit 30141770.4714.007.007.32.19.7 23 Salinity mg/lit -85.059.47883.6112.1191132.924.974.7 24 Total Nitrogen mg/lit -1.120.287.471.121.315.040.370.35 25 Total Phosphorous mg/lit -<0.11 26 Dissolved Oxygen mg/lit -3.23.73.63.33.13.63.83.4 27 Heavy Metals a Arsenic (As) mg/l 0.01<0.001 b Cadmium (Cd) mg/l 0.0030.002<0.001 <0.003 c Chromium (Cr) mg/l 0.05<0.001 d Copper (Cu) mg/l 0.050.0150.0040.003<0.0010.032<0.001 e Cyanide (CN) mg/l 0.05<0.001 f Iron (Fe) mg/l 0.30.3920.0830.3210.0410.0210.026<0.0010.184 g Lead (Pb) mg/l 0.010.0470.0120.022<0.001 h Mercury (Hg) mg/l 0.001<0.001 i Manganese (Mn) mg/l 0.1<0.001 j Nickel (Ni) mg/l 0.02<0.001 0.023<0.001 k Zinc (Zn) mg/l 50.1200.4600.0950.285<0.0080.089<0.008 28 Total Coliform MPN Shall not be detectable in any 100 ml sample <1.8 29 Faecal Coliforms MPN -<1.8 Continue.. * IS 10500:2012 Standard Limits for drinking water (2 nd Revision)

67. 67 Kadam Environmental Consultants BASELINE DATA FOR NOISE LEVELS (2016) Ambient Noise Level in Study Area Station Code Noise Monitoring Location Category of Area/Zone Distance (in Km) & Direction from Project Site CPCB Limits in dB (A) Average Noise levels in dB (A) Leq Day Time Hours [06:00 to 22:00] Night Time Hours [22:00 to 06:00] Day Time Hours [06:00 to 22:00] Night Time Hours [22:00 to 06:00] NL 1 At Project Site (Lab) Industrial0.075.070.068.8557.68 NL 2 At Project Site (Near Main Gate) Industrial0.075.070.057.0051.28 NL 3 At Project Site (Near Material entry gate) Industrial0.075.070.057.1951.13 NL 4 At Project Site (Near ETP plant) Industrial0.075.070.054.5451.32 NL 5 At Project Site (Gate No. 1) Industrial0.075.070.055.6551.22 NL 6ZuarinagarResidential2.26 / E55.045.064.4353.16 NL 7BogmaloResidential3.07 / W55.045.060.5749.97 NL 8SancoaleResidential2.48 / N55.045.054.1651.78 NL 9PaleResidential1.34 / SE55.045.050.0442.47 NL 10VernaResidential5.94 / ESE55.045.054.8649.41

68. 68 Kadam Environmental Consultants BASELINE DATA FOR SOIL SAMPLES (2016) CodeLocationSource Distance from Project Site in Km Direction w.r.t Project Site Justification ST 1At Project SiteIndustrial0.0Base StationTo check surface soil quality at core area. ST 2ZuarinagarResidential2.26E To check surface soil quality within study area ST 3ChicalimResidential1.5NW ST 4BogmaloResidential3.07W ST 5SancoaleResidential2.48N ST 6PaleResidential1.34SE ST 7ConsaulimResidential3.93SE ST 8VernaResidential5.94ESE ST 9NagoaResidential4.7ENE ST 10CortalimResidential4.89NE

69. 69 Kadam Environmental Consultants BASELINE DATA FOR SOIL SAMPLES (2016) S. No ParameterUnit Sampling Location At Project Site ZuarinagarChicalimBogmaloSancoalePaleConsaulimVernaNagoaCortalim 1Porosity% 41405153414449515357 2WHC %46.3347.6458.6470.8545.6244.7163.1061.5767.9869.67 3Permeabilitycm/sec.1.44x 10 -3 1.53x 10 -3 6.96x 10 -4 2.66x 10 -4 8.98x 10 -4 1.53x 10 -3 6.81x 10 -4 6.41x 10 -4 3.54x 10 -4 6.06x 10 -5 4Moisture%9.917.078.2912.298.4210.788.3811.259.4910.90 5 Particle Size Distribution - aSand%87.8485.1269.8442.5684.2487.5669.8456.1253.5613.84 bClay%9.448.884.167.884.16 11.4410.4413.4437.88 cSilt%2.726.0026.0049.5611.608.2818.7233.4433.0048.28 6Texture - LOAMY SAND SANDY LOAM SILTY LOAM LOAMY SAND SAND SANDY LOAM LOAM SILTY CLAY LOAM 7ESP<0.1 0.18<0.1 0.26<0.1 8 Cation Exchange Capacity mg/100gm14.0015.4016.0020.0015.0017.00 19.0016.0024.00 9ECμmohs/cm738.0328.3145.296.689.6214.184.4160.9118.3122.4

70. 70 Kadam Environmental Consultants S. No ParameterUnit Sampling Location At Project Site ZuarinagarChicalimBogmaloSancoalePaleConsaulimVernaNagoaCortalim 10 Organic Carbon % -- 11pH 6.126.186.916.526.696.856.886.085.255.34 12Calcium0.160.210.190.180.240.32 0.190.130.64 13Magnesium-2.041.040.220.231.510.10 0.220.120.24 14Sodiumgm/kg0.500.240.220.110.210.350.200.180.30.44 15Potassiumgm/kg0.140.240.070.030.070.120.050.060.040.11 16Fluoridegm/kg0.010.02<0.00010.02<0.00010.03 <0.0001 Continue..

71. FUGITIVE EMISSIONS & ITS CONTROL 71 Kadam Environmental Consultants Various hazardous chemicals and gases are stored and handled at ZACL plants. Control measures for fugitive emission reduction (primary and secondary) during loading/ unloading, storage and handling of chemicals are described below:  All the joints and flanges are maintained in good conditions through predictive and preventive maintenance.  Workplace monitoring is carried out at various sections of plants

72. Agreement Letter for Gas Supply 72 Kadam Environmental Consultants P.S

73. Permissions for Drawl of Water 73 Kadam Environmental Consultants P.S

74. PROCESS FLOW DIAGRAM OF CUSTOMIZED NPK PLANT 74 Kadam Environmental Consultants

75. PROCESS FLOW DIAGRAM OF GT, HRSG 75 Kadam Environmental Consultants

76. PROCESS FLOW DIAGRAM OF UREA GRANULATION PLANT 76 Kadam Environmental Consultants

77. POLLUTION LOAD STATEMENT 77 Kadam Environmental Consultants S. No. ParameterExisting Plant Proposed Expansion / Modernization TotalRemarks 1Land Area (Acre)10130 No additional land required. 2Raw Water (m 3 /day)9970(-2100)7870 Reduction of Water Consumption due to modernization of technologies. 3Power (MW)12.5214.5 No additional power will be required, Will be sourced internally. 4 Waste Water (Effluent Generation), (m 3 /day) aIndustrial1885(-220)1665 Reduction in Waste Water generation. bDomestic6400 5Effluent Disposal ModeZero Liquid Discharge Zero Liquid Discharge will be maintained. 6Solid Waste aNon Hazardous Solid Waste No additional non hazardous waste will be generated. Waste resin material from DM plant 2-40 Waste sand from TWP filters10-200 Waste activated carbon from WTP filters 6-100 Sludge from STP10-200

78. 78 Kadam Environmental Consultants S. No. ParameterExisting Plant Proposed Expansion / Modernization TotalRemarks bHazardous (MT/annum) Used/Spent Oil 35Negligible35 No additional Hazardous waste generation. Furnace oil tank cleaning residue and washing water & sludge 2500 Spent catalyst 1170 Chemical sludge from waste water treatment 450 7Hazardous Chemical Storage No additional Hazardous Chemical will be stored. In proposed expansion Ammonia storgage will be converted to Double Integrity wall from Horton sphere which is more suitable & safe. 8Air Emissions Proper efficient APCM will be installed, minimal emission load will be increased. Urea dust will be reduced from 150 mg/Nm 3 to 30 mg/Nm 3. Within limit Total No. of stack will be more or less same as existing Continue..

79. Hazardous Waste 79 Kadam Environmental Consultants

80. Stack Details 80 Kadam Environmental Consultants

81. 81 Kadam Environmental Consultants End of Backup Slides