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Rough1234 Initial0.015.730.60.215.3 Final15.730.646.215.330.6 Total Should another titration be done? Why or why not?

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Presentation on theme: "Rough1234 Initial0.015.730.60.215.3 Final15.730.646.215.330.6 Total Should another titration be done? Why or why not?"— Presentation transcript:

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2 Rough1234 Initial0.015.730.60.215.3 Final15.730.646.215.330.6 Total Should another titration be done? Why or why not?

3  Find the average titre volume.  15.1 +15.1+15.2 /3=15.1mL  3 results within.1mL are called concordant results  (exclude trial 1 since it is more than.1 away from the rest) Rough1234 Initial0.015.730.60.215.3 Final15.730.645.715.330.5 Total15.714.915.1 15.2

4  Remember that c=n/V  c=concentrantion  n=moles  V=volume (in L)

5 1. Identify the known and the unknown in the problem. 2. Find the amount of moles of the known using the c=n/V equation. 3. Look at the balanced equation to find the mole ratio and multiply the moles of the known by the mole ratio (unknown/known) to find the moles of the unknown. 4. The concentration of the unknown can be calculated from the moles calculated above and the volume from the titration.

6 15.0 mL of an aqueous solution of 0.105 mol L -1 sodium carbonate is titrated with hydrochloric acid solution.12.6mL of solution is needed to reach the equivalence point. What is the concentration of the sodium carbonate solution? 2 HCl (aq) + Na 2 CO 3(aq)  2 NaCl (aq) + CO 2(g) + H 2 O (l)

7 HClNa 2 CO 3 ratio21 n c0.105 mol L -1 V0.01260.015L

8  Calculate moles of known – sodium carbonate  n=c*V  n=0.105*0.015L  n=0.001575mol

9 HClNa 2 CO 3 ratio21 n0.00158 mol c0.105 mol L -1 V0.0126L0.0150L

10 Find the number of moles of unknown using mole ratio and moles of known. =0.001575mol *(unknown/known) =0.001575mol * 2/1 =0.00315mol of HCl

11 HClNa 2 CO 3 ratio21 n0.00315m ol 0.00158 mol c0.105 mol L -1 V0.0126L0.0150L

12  Calculate concentration of unknown  c=n/V  c=0.00315mol/0.0126L  c=0.250mol L -1

13 HClNa 2 CO 3 ratio21 n0.00315mo l 0.00158 mol c0.250 mol L -1 0.105 mol L - 1 V0.0126L0.0150L

14  2HCl (aq) + Ca(OH) 2(aq)  CaCl 2(aq) + 2H 2 O (l)  We know the following…  V = 50.0 mL Ca(OH) 2 in flask  [HCl] = 0.100 mol L -1  V HCl added = 20.0 mL for 3 concordant titres.


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