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Published byCaren Russell Modified over 8 years ago
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Carbon allotropes
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The physical properties depend on the chemical bonding
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Diamond Strong covalent bonds in 3 dimensions Every carbon atom bonds 4 other carbon atoms in a crystalline lattice The hardest material known
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Diamond Hard, colourless, insulator Tetrahedral, giant structure Covalent bond => sp 3 orbitals (HL)
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Graphite Animation The double bonds are delocalised and move- electric conductivity in the plane The planes bond with weak intermolecular bonds- van der Waals bonds The layers move easily- graphite colours
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Graphite Slippery, black, electricity conductor Layers of fused six-membered rings. Each carbon surrounded by three others in a planar trigonal arrangement => sp 2 + p-orbital (HL) The p-orbital is perpendicular to the layer and give close packed p-orbitals stabilise the layers Delocalisation of electrons => electrical conductivity
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Fullerenes och nanotubes Nanotubes
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Fullerene, C 60 Spherical molecule. Looks like a football. 12 pentagons and 20 hexagons. Bonds: C 60 –hydration C 60 H 60 (C 2 H 4 + H 2 C 2 H 6 ; 1 H 2 / double bond) Each carbon has a double bond
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Graphén
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