Superior performance. powerful technology. SuperPower Inc. is a subsidiary of Furukawa Electric Co. Ltd. SuperPower 2G HTS Conductor Drew W Hazelton Director.

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Presentation transcript:

superior performance. powerful technology. SuperPower Inc. is a subsidiary of Furukawa Electric Co. Ltd. SuperPower 2G HTS Conductor Drew W Hazelton Director of R&D / Applications (USA) WAMHTS-1 Hamburg, Germany May 21, 2014

WAMHTS-1 : Hamburg, Germany : May 21, 2014All Rights Reserved. Copyright SuperPower ® Inc Hastelloy ® C276 substrate high strength high resistance non-magnetic Buffer layers with IBAD-MgO Diffusion barrier to metal substrate Ideal lattice matching from substrate through ReBCO MOCVD grown ReBCO layer with BZO nanorods Flux pinning sites for high in-field I c Silver and copper stabilization SuperPower’s ReBCO superconductor with artificial pinning structure provides a solution for demanding applications 2

WAMHTS-1 : Hamburg, Germany : May 21, 2014All Rights Reserved. Copyright SuperPower ® Inc Microstructure of production MOCVD HTS wires with standard 7.5% Zr doping 5 nm sized, few hundred nanometer long BZO nanocolumns with ~ 35 nm spacing created during in situ MOCVD process with 7.5% Zr

WAMHTS-1 : Hamburg, Germany : May 21, 2014All Rights Reserved. Copyright SuperPower ® Inc I c (B,T, Φ) characterization is critical to understanding the impacts of processing on operational performance 4 Measurements made at the University of Houston Lift factor, I c (B,T)/I c (sf, 77K), particularly a full matrix of I c (B,T, Φ) is in high demand. Frequently sought by coil/magnet design engineer, for various applications. Used to calculate local I op / Ic ratio inside coil body, and design quench protection.

WAMHTS-1 : Hamburg, Germany : May 21, 2014All Rights Reserved. Copyright SuperPower ® Inc K Ic data on recent production material 5 Measured at FEC/Nikko

WAMHTS-1 : Hamburg, Germany : May 21, 2014All Rights Reserved. Copyright SuperPower ® Inc Technology development programs are focused on next level of product improvements … 6 68% improvement demonstrated in wire performance at wind generator operating condition of 30 K, 2.5 T Increase Ic to over 1500A (demo in mid 2014) 68% improvement demonstrated in wire performance at wind generator operating condition of 30 K, 2.5 T Increase Ic to over 1500A (demo in mid 2014) Structured, well-timed process for transfer of these advancements into production (by end of 2014) Increase base Ic Increase lift factor Increase wire strength Reduce ac losses Increase base Ic Increase lift factor Increase wire strength Reduce ac losses

WAMHTS-1 : Hamburg, Germany : May 21, 2014All Rights Reserved. Copyright SuperPower ® Inc Thinner substrates offer improved current density while still providing strong mechanical support Current 2G HTS production material based on either 50 or 100  m Hastelloy® C276 substrate –For standard Cu thickness of 40  m total, the conductor thickness of current production 2G HTS conductor is ~ 0.095mm. 7 Baseline is 50 micron thick Hastelloy C276 Thinner Hastelloy® C276 of 25, 30 and 38  m thicknesses are being evaluated –For standard Cu thickness of 40  m total on a 25  m Hastelloy® C276 substrate, conductor thickness is reduced to ~70  m –This implies a 36% increase in current density Available second half of 2014 Baseline is 40 micron thick copper stabilizer

WAMHTS-1 : Hamburg, Germany : May 21, 2014All Rights Reserved. Copyright SuperPower ® Inc I c uniformity along length (four-probe transport measurement) 8 Position (m) (on a 4 mm wide wire) Ic (A, 77K, s.f.) and n-value

WAMHTS-1 : Hamburg, Germany : May 21, 2014All Rights Reserved. Copyright SuperPower ® Inc I c uniformity along length (TapeStar) 9 Position (cm) (on a 12 mm wide wire) Magnetic, non-contact measurement High spacial resolution, high speed, reel-to-reel Monitoring I c at multiple production points after MOCVD Capability of quantitative 2D uniformity inspection

WAMHTS-1 : Hamburg, Germany : May 21, 2014All Rights Reserved. Copyright SuperPower ® Inc SuperPower 2G HTS conductor has been successfully demonstrated in ROEBEL cables ROEBEL Cable –KIT –General Cable Typically punched from 12 mm wide strips –Measured for 2D uniformity using TapeStar In the future, we may be able to deposit onto a pre-cut shape –There are no inherent process limitations to doing this 10

WAMHTS-1 : Hamburg, Germany : May 21, 2014All Rights Reserved. Copyright SuperPower ® Inc SuperPower 2G HTS conductor is adaptable for use in many demanding cable architectures. Various wire architectures under development by world wide customers to develop high current conductors for use in low inductance magnets Cable on Round Core (CORC) –Advanced Conductor Technologies –Thinner substrates will further enable this architecture Stacked cables –MIT, others Clad conductors (SP) –Increase strand currents –Customize properties for tailored applications (i.e. FCL-XFR) 11 Courtesy: Advanced Conductor Technologies

WAMHTS-1 : Hamburg, Germany : May 21, 2014All Rights Reserved. Copyright SuperPower ® Inc Capability for bonded conductors has been developed [higher amperage, specialty applications (FCL) ] 12 Bonded conductors offer the ability to achieve higher operating currents –LV windings of FCL transformer –HEP applications –High current bus applications Bonded conductors offer higher strength –FCL transformer fault currents –High field HEP applications with high force loadings Bonded conductors offer the ability to tailor application specific operating requirements, i.e. normal state resistance for a FCL transformer

WAMHTS-1 : Hamburg, Germany : May 21, 2014All Rights Reserved. Copyright SuperPower ® Inc Copper stabilization can be tailored to meet application requirements Copper stabilization typically added by electro-deposition –10  m to 120  m total thickness Alternatively, copper stabilization can be clad to the superconductor to provide thicker stabilization –Laminates up to 1 mm thick have been clad to the 2G HTS –Alternates to copper can be clad (copper alloys, stainless steel) 13 < 0.1 mm 20  m Cu 50  m Hastelloy 20  m Cu SCS4050 w/ 40  m Cu

WAMHTS-1 : Hamburg, Germany : May 21, 2014All Rights Reserved. Copyright SuperPower ® Inc Tensile strength predominately determined by substrate 14 Tensile stress-strain relationship of SCS4050 wires with different Cu stabilizer thickness (room temperature) Tensile stress-strain relationship of as-polished Hastelloy substrate (room temperature) 100 µm Cu 40 µm Cu 20 µm Cu

WAMHTS-1 : Hamburg, Germany : May 21, 2014All Rights Reserved. Copyright SuperPower ® Inc Copper thickness 40 µm 60 µm 100 µm Conductor Stress-Strain at 77K and 4 K with Various Copper Thickness Significant softening of the stress-strain curve with added copper due to reduced modulus and yielding of the copper.

WAMHTS-1 : Hamburg, Germany : May 21, 2014All Rights Reserved. Copyright SuperPower ® Inc Tensile test of wires with SCS 16 Measurement of baseline data Effect of Cu/Hastelloy ratio M (100µm Cu) Stress limit  460MPa M (40µm Cu) Stress limit  620MPa

WAMHTS-1 : Hamburg, Germany : May 21, 2014All Rights Reserved. Copyright SuperPower ® Inc Axial compressive tests at BNL on pancake coil show no Ic degradation to at least 100 MPa 17 WB Sampson et al, Proceedings of 2011 Particle Accelerator Conference, New York, NY TUP169 Pancake coil fabricated from 12mm wide SP 2G HTS Compressive Ic test setup (LN2 testing) Typical Ic trace Summary of Ic data on coil sections

WAMHTS-1 : Hamburg, Germany : May 21, 2014All Rights Reserved. Copyright SuperPower ® Inc G HTS offer low heat leak in current lead applications Eliminate I 2 R heat load Can be tailored to meet your target heat loads New configurations becoming available –Ag alloy –Bonded 18

WAMHTS-1 : Hamburg, Germany : May 21, 2014All Rights Reserved. Copyright SuperPower ® Inc PropertyCurrentFuture (2/5 yrs) Width range (mm)2-12 (2,3,4,6,8,12)2-12 / 2-12, others? Production length (m) / 2000 Unit piece lengths (m)100 – / 1000 SubstrateHastelloy® C276Hastelloy® C276, others? Buffers5 layer stack w/IBAD MgO5 layer stack w/IBAD MgO, other? REBCO thickness (  m) Copper thickness (  m) 10 – 120 (total) plating Up to 1mm by lamination 5 – 120 (total) plating Up to 1 mm by lamination Ic range (A/cm)250 – 420 (77K, sf) 450 – 600 (4.2K, 15T//c) 350 – 800 (77K, sf) 1000 – 2500 (4.2K, 15T//c) Jc range (A/mm 2 135A (77K, sf) 230A (4.2K, 15T//c) SCS4050, 40  m Cu 240A (77K, sf) 725A (4.2K, 15T//c) SCS3050, 40  m Cu Critical current variation< 10% std dev (spec)< 5% std dev (spec) Maximum stress/strain (tensile)> 550 MPA, > 0.5% SCS4050, 40  m Cu > 550 MPA, >0.5% SCS3050, 40  m Cu Maximum stress/strain (comp)> 80 MPA w/o failure – limit TBDTBD 19

WAMHTS-1 : Hamburg, Germany : May 21, 2014All Rights Reserved. Copyright SuperPower ® Inc Pricing Pricing will be driven down on two fronts –Improved manufacturing Better yields Reduced costs on scale up –Improved performance Higher baseline Ic (77K, sf) –Thicker HTS films –Better quality HTS films Improved lift factor at operating conditions –Next generation AP with 2x or more improvement over current pinning –Demonstrated in samples, moving into production later this year The resulting price – performance ratio ($/kA-m) will continue to drop over the next years by factors of

WAMHTS-1 : Hamburg, Germany : May 21, 2014All Rights Reserved. Copyright SuperPower ® Inc Closing remarks SuperPower 2G HTS conductor offers a flexible architecture to address the broad range of demanding applications requirements. SuperPower is engaging major resources in improving it manufacturing capabilities to deliver a consistent, reliable, high quality 2G HTS product –Improved mechanical properties –Improved piece length / uniformity –Improved current density –Improved splice resistance Alternative conductor configurations are being developed to address customer specific requirements –Ag alloy –Bonded conductors We are open to exploring “out-of-the-box” configurations 21

WAMHTS-1 : Hamburg, Germany : May 21, 2014All Rights Reserved. Copyright SuperPower ® Inc For more information on SuperPower, please visit us at: SuperPower Inc. is a world leading developer and producer of second-generation high-temperature superconducting (2G HTS) wire, providing enormous advantages over conventional conductors of electric power - high efficiency, smart grid compatible, clean, green, safe and secure. 22