IIIIII C. Johannesson I. Lewis Diagrams (p. 170 – 175) Ch. 6 – Molecular Structure.

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IIIIII C. Johannesson I. Lewis Diagrams (p. 170 – 175) Ch. 6 – Molecular Structure

C. Johannesson A. Octet Rule n Remember…  Most atoms form bonds in order to have 8 valence electrons.

C. Johannesson  Hydrogen  2 valence e -  Groups 1,2,3 get 2,4,6 valence e -  Expanded octet  more than 8 valence e - (e.g. S, P, Xe)  Radicals  odd # of valence e - n Exceptions: A. Octet Rule F B F F H O HN O Very unstable!! F F S F F

C. Johannesson B. Drawing Lewis Diagrams n Find total # of valence e -. n Arrange atoms - singular atom is usually in the middle. n Form bonds between atoms (2 e - ). n Distribute remaining e - to give each atom an octet (recall exceptions). n If there aren’t enough e - to go around, form double or triple bonds.

C. Johannesson B. Drawing Lewis Diagrams n CF 4 1 C × 4e - = 4e - 4 F × 7e - = 28e - 32e - F F C F F - 8e - 24e -

C. Johannesson B. Drawing Lewis Diagrams n BeCl 2 1 Be × 2e - = 2e - 2 Cl × 7e - = 14e - 16e - Cl Be Cl - 4e - 12e -

C. Johannesson B. Drawing Lewis Diagrams n CO 2 1 C × 4e - = 4e - 2 O × 6e - = 12e - 16e - O C O - 4e - 12e -

C. Johannesson C. Polyatomic Ions n To find total # of valence e - :  Add 1e - for each negative charge.  Subtract 1e - for each positive charge. n Place brackets around the ion and label the charge.

C. Johannesson C. Polyatomic Ions n ClO Cl × 7e - = 7e - 4 O × 6e - = 24e - 31e - O O Cl O O + 1e - 32e - - 8e - 24e -

C. Johannesson n NH N × 5e - = 5e - 4 H × 1e - = 4e - 9e - H H N H H - 1e - 8e - - 8e - 0e - C. Polyatomic Ions

C. Johannesson D. Resonance Structures n Molecules that can’t be correctly represented by a single Lewis diagram. n Actual structure is an average of all the possibilities. n Show possible structures separated by a double-headed arrow.

C. Johannesson D. Resonance Structures O O S O O O S O O O S O n SO 3