Chemistry GT 6/9/15.  No Drill – drill Quiz  Take out a sheet of notebook paper. On it, write the Questions AND Answers for these drills:  5/5, 5/28.

Slides:



Advertisements
Similar presentations
Le Châtelier’s Principle.  Concentration  Pressure and volume  Temperature  Catalysts.
Advertisements

Le Châtelier's Principle
Reaction Rates & Equilibrium
Section 8.4—Le Chatelier’s Principle How can we push a reaction to make more products?
Equilibrium.
Chemical Equilibrium CHAPTER 15
For equilibrium to occur: System must be closed. Temperature must be constant. Reactions must be reversible (do not go to completion). H 2 (g) + Cl 2.
Equilibrium The condition of a system in which competing influences are balanced. The condition of a system in which competing influences are balanced.
Chemical Equilibrium. Complete and Reversible Reactions  Complete – Forms a precipitate or evolves gas, all reactants are used up  Reversible - When.
Equilibrium A state in which opposing processes of a system are occurring at the same rate. 1.Physical (a) Saturated Solution – dissolution and crystallization.
Chemical Equilibrium A Balancing Act.
“Equilibrium”  What does it mean?  What word does it look like?  What does it mean?  What word does it look like?
(7.3) Le Chatelier’s Principle - Regaining Equilibrium.
EQUILIBRIUM TIER 4 Apply LeChatelier’s principle to predict the qualitative effects of changes of temperature, pressure and concentration on the position.
Equilibrium Topic THE EQUILIBRIUM CONSTANT (K c or K) For any type of chemical equilibrium of the type a A + b B  c C + d D a A + b B  c C.
Chemical Equilibrium What is a reversible reaction? What is LeChatlier’s Principle? Predicting Equilibrium Shifts.
TOPIC 8 – KINETICS AND EQUILIBRIUM
Factors Affecting Equilibrium. Equilibrium: Once equilibrium has been reached, it can only be changed by factors that affect the forward and reverse reactions.
Equilibrium Notes: Factors Affecting Equilibrium Part 2.
Aim : How can equilibrium be shifted? Do Now: 1.Take out a calculator and reference tables. 2.What can change the equilibrium of a phase change?
Reaction Rates and Equilibrium Ch. 19. Rates of Reaction 19-1.
Chemical Equilibrium Unit 11. My Chemistry Presentation Chemical Reactions We usually think of chemical reactions as having a beginning and an end. reactants.
Equilibrium SCH4U organic photochromic molecules respond to the UV light.
Dynamic Equilibrium. Objectives Describe chemical equilibrium in terms of equilibrium expressions Use equilibrium constants Describe how various factors.
$$$ Quiz $$$ Reaction Rates and Equilibrium. What are the units for a reaction rate? M/s, molarity per second, concentration per second.
General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 1 Collision Theory of Reactions A chemical reaction occurs when  collisions.
Jeopardy $100 Equilibrium Constants Le Chatelier’s Principle Reaction Quotients Miscellaneous $200 $300 $400 $500 $400 $300 $200 $100 $500 $400 $300 $200.
Thermochemistry: The heat energy of chemical reactions
Chemical Kinetics Branch of chemistry concerned with the rates and mechanisms of chemical reactions.
Chapter 14 & 16 Chemical Equilibrium and reaction rates.
Reversible Reactions Reactions are spontaneous if  G is negative. If  G is positive the reaction happens in the opposite direction. 2H 2 (g) + O 2 (g)
Section 17.3 Application of Equilibria 1.To learn to predict the changes that occur when a system at equilibrium is disturbed 2.To learn to calculate equilibrium.
Le Chatelier’s Principle
 What is the formula for Gibbs Free energy?  What does each variable represent?  How can you tell if a reaction will be spontaneous?  How can you tell.
Le Chatelier’s Principle  A reaction at equilibrium, when “stressed,” will react to relieve the stress.  (If you mess with it, it will work to return.
Energy transformations
Enthalpy, Entropy, and Spontaneity Explained. Review of Enthalpy Change.
Chemical Equilibrium. n In systems that are in equilibrium, reverse processes are happening at the same time and at the same rate. n Rate forward = Rate.
Preview Lesson Starter Objectives Predicting the Direction of Shift Reactions That Go to Completion Common-Ion Effect Chapter 18 Section 2 Shifting Equilibrium.
CHEMICAL EQUILIBRIUM REVIEW. REVIEW Look at the review objectives and your notes. 1. Describe a reversible reaction.  Be sure you can describe what a.
Reaction Rates & Equilibrium Unit 13 - Chapter 18.
Kinetics and Equilibrium Unit VI. I Kinetics A. Kinetics is the study of the rates of reactions and reaction mechanisms  Rate  Speed of a reaction 
Equilibrium Systems and Stress. Phase Equilibrium Liquid to Gas: When water vapor evaporates at the same rate it condenses in a closed container, dynamic.
Part 2 Objectives – Explain and describe equilibrium in terms of molecular motion (when forward and reverse reaction rates are equal) – Be able to write.
Kinetics and Equilibrium Review. The stability of a compound is dependent on the amount of energy absorbed or released during the formation of the compound.
Equilibrium Most reactions are REVERSIBLE. They go in BOTH direction at the same time.
Factors which Affect Chemical Equilibrium Le Chateliers Principle –Projects Direction of Change N 2 (g) + 3H 2 (g) ↔ 2NH 3 (g)
Chemical Equilibrium Reactants Products Reactants Products As the time increases… [Reactants] decrease, so the rate of forward reaction decreases; [Products]
Reaction Rates and Le Chatelier’s Principle
Bell Question: What is the general format for the equation used to calculate equilibrium constants? What does the equilibrium constant tell you about a.
Chemical Equilibrium Unit 11. My Chemistry Presentation Chemical Reactions We usually think of chemical reactions as having a beginning and an end. reactants.
Collision Theory In order for a reaction to occur, the particles of the reactant must have enough energy, and must collide at the correct angles (proper.
Chemical Equilibrium Collision theory Rates of reactions
LeChatelier’s Principle
DO NOW Pick up exam review..
Writing Equilibrium Constant Expressions
Le chÂtelier’s principle
Unit Equilibrium Lundquist
2 NH3 (g) + H2SO4 à (NH4)2SO4 (aq)
Basic Equilibrium Principles 18.1
CHEM 121 Chapter 6.
Le Chatelier's Principle
Writing Equilibrium Constant Expressions
Equilibrium.
EQUILIBRIUM.
Trilogy – Chemistry – CHAPTER 6 – The rate & extent of chemical change H Draw a diagram to show how the rate of reaction changes with INCREASING concentration.
Energy and Equilibrium
18-2 Shifting Equilibrium
Chemistry 6: Rate and Extent of Chemical Change
Unit 13: Equilibrium 13.1 Equilibrium 13.2 Le Chatelier’s Principle
Presentation transcript:

Chemistry GT 6/9/15

 No Drill – drill Quiz  Take out a sheet of notebook paper. On it, write the Questions AND Answers for these drills:  5/5, 5/28  When done, please empty your folder (in the back)  HW: pg. 7 Potential Energy Diagrams & pg. 8 Reaction Rate Review

 Objectives  IWBAT  explain chemical equilibrium as a dynamic system.  use Le Chatelier’s Principle to predict the effects of changes to a chemical system.  Describe the factors that affect reaction rate.  Explain reaction rate using Collision Theory

  Drill  Finish Rxn Rate Notes  Practice with Energy Diagrams  More about K eq  Closure Agenda

Rxn Rates PPT

  Back of pg. 7 Practice

 Label each diagram with the following:  Endothermic or exothermic  Activation Energy   H (change in heat)  Energy of reactants  Energy of Products

  Explain the changes that happen when a catalyst is added.

Equilibrium Constant  Expresses the relative concentrations of reactants and products at equilibrium by using an “equilibrium constant” – K eq  a A + b B  c C + d D

 Equilibrium Constant Only include gases and aqueous solutions when writing equilibrium constants Solids and liquids are not included They can be represented with a [1] or left out entirely

 Types of Equilibrium Problems  Quantitative  K eq < 1, then the reaction is reactant-favored at equilibrium  COCl 2(g)  CO (g) + Cl 2(g)  K eq = 2.2 x  Reactant-favored

 Types of Equilibrium Problems  K eq > 1, then the reaction is product- favored at equilibrium  2 NO 2(g)  N 2 O 4(g)  K eq = 2.15 x 10 2  Product-favored

 K eq and Stresses on the system  K eq does not change with change in concentration  It will change based on change in temperature and change of pressure

  Quantitative (uses the K eq equation)  Write the equilibrium expression for the following reaction  2 SO 2(g) + O 2(g)  2 SO 3(g) Types of Equilibrium Problems [SO 3 ] 2 [SO 2 ] 2 [O 2 ] K eq = ____________

 Types of Equilibrium Problems  If.0172 M of O 2,.0250 M of SO 2 and M of SO 3 at equilibrium, calculate K eq [SO 3 ] 2 [SO 2 ] 2 [O 2 ] K eq = ___________ = [.00140] 2 [.0250] 2 [.0172] _______________ K eq =.18 (reactant favored)

 Exit Ticket  Given the following reaction:  Use Le Chatelier’s principle to determine what would happen if the following changes were made  Increase the concentration of N 2  Increase the concentration of NH 3  Remove NH 3 from the reaction after it is made