1 MELTING AND BOILING SEC 3 PHYSICS

2 Melting Let us recall; Melting is a change of state from solid to liquid. Melting occurs at a fixed temperature. This temperature is known as the melting point of the substance. Eg. Melting point of water is 0 o C or 273 K

3 Melting Let us remove an ice cube from the freezer and place it under the hot sun which is about 35 o C. Assuming that original temperature of ice cube is about -20 o C. What will you observe after sometime? It is obvious that after sometime, the ice cube will start to melt and eventually solid ice cube will turn into water totally.

4 Melting If you were to measure the temperature of the ice cube as it slowly turns from a solid state to a liquid state, which would be the situation that you would observe? Graph A or B? -20 o C Temperature Time Graph A 0oC0oC 35 o C P Q R Temperature Time Graph B -20 o C 0oC0oC 35 o C P QR S

5 Melting The result that one would observe is that of Graph B! Interpreting the Graph: P-Q: Temperature of ice cube increases from -20  0 o C. Ice cube remains a solid. Q-R: Ice cube starts to melt. Solid changing to liquid. During this stage, substance is both in solid-liquid state. No change in temperature. R-S: Solid ice cube has changed totally to liquid water. Temperature of water increases from 0  35 o C. Temperature Time Graph B -20 o C 0oC0oC 35 o C P QR S Graph B is known as the Heating Curve

6 Melting This observation is TRUE for almost ALL pure solid substance during melting. During melting, temperature of the substance remains constant (fixed) at the melting point for some time; until all solid has changed to liquid, before its temperature increases again. WHY? Temperature Time Graph B -20 o C 0oC0oC 35 o C P QR S

7 Melting To explain this phenomena, we have to look at it from the kinetic theory of matter. P-Q: 1.Ice is at a low temperature compared to hot air. So thermal energy from surrounding will move into ice. 2.This thermal energy absorbed by ice, is changed to KE. The result we see is particles of ice vibrating faster. 3.When particles vibrate faster, it results in a change (increase) in temperature. 4.Thermal energy will be continually absorbed as long as there is a temperature difference btw ice and surrounding. Temp Time P QR S

8 Melting Q-R: 5.The amount absorbed will reach a level such that the KE of particles are enough to break the particles from the inter-molecular forces of attraction holding them together. 6.During this stage, whatever thermal energy absorbed will not change into KE, but is used to break the forces of attraction. 7.This is why the temperature during melting is constant. Temp Time P QR S

9 Melting R-S: 8.Once all solid ice has turned into liquid state, energy is no longer needed to break the attractive forces. 9.Since liquid water is at a lower temperature compared to surrounding, it will still absorb thermal energy from hotter surrounding. 10.This thermal energy is changed into KE and as a result, particles move faster, causing an increase in temperature. 11.When the temperature of liquid water has reached that of the surrounding, no more thermal energy transfer will happen. Its temperature will be equal to the surrounding. Temp Time P QR S

10 Melting – molecular level Temp Time P QR S Temp Time P QR S Temp Time P QR S KE increases Particles vibrate faster Temperature increases KE constant Thermal energy used to break attractive forces btw particles Temperature constant KE increases Particles vibrate faster Temperature increases MELTINGLIQUIDSOLID

11 Freezing The reverse to melting is freezing or solidification Freezing is the process of change from liquid to solid state. Freezing occurs at a fixed temperature. This temperature is known as the freezing point. A pure substance freezes at a temperature equal to its melting point. This means that for the same pure substance, its freezing point is the same as its melting point.

12 Freezing A typical cooling curve of a substance can be represented by the freezing of napthalene (moth balls) Again it can be observed that during the freezing stage, K  L, temperature remains constant at 78 o C. This means that 78 o C is the freezing point of napthalene. Temperature / o C Time/min J K L M

13 Freezing Again to understand this phenomena, we have to approach the problem from the kinetic theory of matter.

14 Freezing J  K: Napthalene is at a higher temp. compared to surrounding Thermal energy is being transferred out of napthalene Losing thermal energy means that KE of particles drops Particles are slowing down, resulting in temperature drop. Temperature / o C Time/min J K L M

15 Freezing K  L: KE of particles are at such a level that the particles are no longer able to ignore inter-molecular force of attraction As particles are being drawn into a fixed structured pattern, the average KE of all particles will remain the same until ALL napthalene changes to solid state Hence there is no change in temperature although thermal energy is still being released to the surroundings. This energy released comes from bond formation. Temperature / o C Time/min J K L M

16 Freezing L  M: Once all napthalene has changed into solid state, the continual release of thermal energy due to temperature difference btw napthalene and surrounding, causes KE of particles to drop further. The result of KE drop is that temperature of napthalene will also drop. Temperature will drop until temperature of both napthalene and surrounding are the same. Temperature / o C Time/min J K L M

17 Effect of Impurities on Freezing Point When impurities are added to a substance, it would lower its freezing point. Impurities are other foreign substances. Example: – I have 2 cups of water, A and B. – I add salt to B. When I try to freeze the water in both cups, A would freeze at 0 o C but B would freeze maybe at –10 o C. – This means B would stay as a liquid even at 0 o C or -2 o C or lower until the temperature reaches –10 o C. – When A becomes solid ice at 0 o C, B is still liquid.

18 Effect of Impurities on Freezing Point (*optional) Reason for this is that presence of impurities causes disruption to the formation of inter- molecular forces of attraction. The particles of original substance would need to be slower (this means the average KE has to be lower) before they can be drawn into a fixed structured pattern by the forces.

19 Effect of Impurities on Freezing Point Applications: – In cold countries, impurities are added to water in radiators of vehicles to prevent water from freezing – Salt are spread on roads during winter, so that water from melted snow will not form into ice easily. Ice is very slippery and is dangerous to traffic.

20 Effect of Pressure on Melting Point Melting point of ice is lowered by an increase in pressure and is increased by a drop in pressure. At higher pressure, an ice cube would melt at temperatures lower than 0 o C. At lower pressure (on the mountain), ice would only melt at temperatures higher than 0 o C. Which is why there can be snow on the mountain top even when surrounding temperatures are above 0 o C.

21 Effect of Pressure on Melting Point Try this at home. Press two ice cubes just newly removed from freezer together for sometime. Release the ice-cubes. Both ice-cubes are ‘stuck’ together. WHY?

22 Effect of Pressure on Melting Point (*optional) When a solid substance is subjected to high pressure, this pressure helps particles to overcome the inter- molecular forces holding them together. As a result, it is not necessary for KE of particles to reach a high level before they are able to break free. When pressure is lower, substance is more stable. Hence these particles would need more KE before they can break free from the forces of attraction. Result is that its melting point would be higher.

23 Boiling Boiling is a change of state from liquid to gas. Boiling occurs at a fixed temperature. During boiling, temperature remains constant. Heat is taken in / absorbed during this process. This temperature is known as the boiling point of the substance. Liquid will remain at boiling point until all the liquid has changed to gas. (phenomena is pretty similar to melting)

24 Boiling A typical boiling curve; for this instance, for water. Q  R; where the temperature remains constant is the boiling stage. Temperature/ o C Time/ min P QR S 30

25 Boiling P  Q: Water absorbs thermal energy, causing its particles to increase in speed (KE increases) The result of KE increase is the rise in temperature Temperature/ o C Time/ min P QR S 30

26 Boiling Q  R: When KE of particles reach a certain level, it is strong enough to overcome the inter-molecular forces holding them together At this stage, all thermal energy absorbed goes towards breaking the attractive forces Particles are all now free to move freely and randomly Substance has changed from liquid to gas state completely Temperature/ o C Time/ min P QR S 30

27 Boiling R  S: Once in gas state, particles will speed up as it absorbs more thermal energy (from heating) This results in temperature increase of substance Temperature/ o C Time/ min P QR S 30

28 Condensation The reverse of boiling is condensation. It is the process of change from gas to liquid. It occurs at a fixed temperature which is the boiling point of the substance. Heat is given off during this process.

29 Condensation A typical cooling curve for condensation A  B: Thermal energy is being transferred out of water Losing thermal energy means that KE of particles drops Particles are slowing down, resulting in temperature drop Temperature/ o C Time/ min A B C D 30

Condensation B  C: KE of particles are at such a level that the particles are no longer able to ignore inter-molecular force of attraction As particles are being drawn into a structured pattern, the average KE of all particles will remain the same until ALL water vapour changes to liquid state Hence there is no change in temperature although thermal energy is still being released to the surroundings. This energy released comes from bond formation. Temperature/ o C Time/ min A B C D 30

31 Condensation C  D: Once all water vapour has changed into liquid state, the continual release of thermal energy due to temperature difference, causes KE of particles to drop further. The result of KE drop is that temperature of liquid water will also drop. Temperature will drop until temperature of both liquid water and surrounding are the same. Temperature/ o C Time/ min A B C D 30

32 Melting and Boiling Curve of a Substance A typical melting and boiling curve of a substance is as shown. Note the following: Temperature ( o C) Time (min) Melting point Boiling point Substance in single state Substance in mixed state Solid state only Mixture of solid and liquid state Liquid state only Mixture of liquid and gas state Gas state only

33 Heating and Cooling Curve From a heating or cooling curve, we can determine the melting (or freezing) and boiling (or condensation) points of a substance. All we need to do is to look for horizontal straight line.

34 Effect of Impurities on Boiling Point Adding impurities will raise the boiling point of an object. That means to say the liquid will now boil at a higher temperature.

35 Effect of Pressure On Boiling Point Lower pressure would lower the boiling point of water. Water will boil very quickly on the mountain top but the temperature reached is lower than 100 o C. Increasing pressure would raise the boiling point of water. Water will boil at a higher temperature above 100 o C. Can we boil water at room temperature, 30 o C?

36 Evaporation Evaporation is the change of state from liquid to gas at any temperature. Note that evaporation is not the same as boiling.

37 Differences BoilingEvaporation Occurs at fixed temperatureOccurs at any temperature Quick processSlow process Takes places within liquidTakes places only on surface Bubbles are formedNo bubbles are seen Temperature remains constantTemperature may change Heat supply by energy sourceHeat supplied by surroundings

38 Kinetic Theory of Evaporation Molecules at surface of liquid have higher energy than the average kinetic energy of the other molecules when these molecules absorb energy from the surrounding air and objects. These molecules gain energy and move faster and are thus able to overcome forces of attraction between the molecules and hence leaving behind less energetic ones. When energy is lost for evaporation to take place, the remaining molecules have lower kinetic energy. Since temperature is directly proportional to average kinetic energy, the temperature of the remaining liquid decreases. (slightly) As a result, the surface where evaporation has taken place feels cooler. Conclusion: Evaporation causes cooling.

39 Some everyday effects and uses of evaporation. Cooling effect on skin upon application of cologne Evaporation of perspiration cools the body. Wet clothes or puddles of water dries up in the open air. Sponging someone who is having fever will cause the temperature to drop as the evaporation of the water from the person’s skin will cause cooling.

40 Factors affecting evaporation Temperature – A liquid with a higher temperature will evaporate faster than one at a lower temperature. So heating will increase rate of evaporation Humidity of surrounding air – Humidity refers to presence of water vapour in the air. The rate of evaporation decreases with increasing humidity. Rate of evaporation increases with decreasing humidity. Surface area of liquid – Rate of evaporation increases with increasing surface area. The bigger the surface area, the faster the evaporation.

41 Factors affecting evaporation Presence of wind – Rate of evaporation increases in the presence of wind. Pressure – Rate of evaporation increases with decreasing atmospheric pressure. Wet objects dry faster at higher altitudes. Nature of liquid – A liquid with a low boiling point has a higher rate of evaporation than a liquid with high boiling point.