C. Johannesson Ch. 10 & 11 - Gases Gas Stoichiometry at Non- STP Conditions.

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C. Johannesson Ch. 10 & 11 - Gases Gas Stoichiometry at Non- STP Conditions

C. Johannesson A. Gas Stoichiometry b Moles  Liters of a Gas: STP - use 22.4 L/mol Non-STP - use ideal gas law b Non- STP Given liters of gas?  start with ideal gas law Looking for liters of gas?  start with stoichiometry conv.

C. Johannesson 1 mol CaCO g CaCO 3 B. Gas Stoichiometry Problem b What volume of CO 2 forms from 5.25 g of CaCO 3 at 103 kPa & 25ºC? 5.25 g CaCO 3 = 1.26 mol CO 2 CaCO 3  CaO + CO 2 1 mol CO 2 1 mol CaCO g? L non-STP Looking for liters: Start with stoich and calculate moles of CO 2. Plug this into the Ideal Gas Law to find liters.

C. Johannesson WORK: PV = nRT V = B. Gas Stoichiometry Problem b What volume of CO 2 forms from 5.25 g of CaCO 3 at 103 kPa & 25ºC? GIVEN: P = 103 kPa = ? atm V = ? n = 1.26 mol T = 25°C = 298 K R =.0821 L atm/mol K

C. Johannesson WORK: PV = nRT ( atm) (15.0 L) = n (.0821) (294K) n = mol O 2 B. Gas Stoichiometry Problem b How many grams of Al 2 O 3 are formed from 15.0 L of O 2 at 97.3 kPa & 21°C? GIVEN: P = 97.3 kPa V = 15.0 L n = ? T = 21°C = 294 K R = Al + 3 O 2  2 Al 2 O L non-STP ? g Given liters: Start with Ideal Gas Law and calculate moles of O 2. NEXT 

C. Johannesson 2 mol Al 2 O 3 3 mol O 2 B. Gas Stoichiometry Problem b How many grams of Al 2 O 3 are formed from 15.0 L of O 2 at 97.3 kPa & 21°C? mol O 2 = 40.6 g Al 2 O 3 4 Al + 3 O 2  2 Al 2 O g Al 2 O 3 1 mol Al 2 O L non-STP ? g Use stoich to convert moles of O 2 to grams Al 2 O 3.