Physical Chemistry 2 nd Edition Thomas Engel, Philip Reid Chapter 18 A Quantum Mechanical Model for the Vibration and Rotation of Molecules

© 2010 Pearson Education South Asia Pte Ltd Physical Chemistry 2 nd Edition Chapter 18: A Quantum Mechanical Model for the Vibration and Rotation of Molecules Objectives Solving Schrödinger Equation Introducing Angular Momentum Introducing Spherical Harmonic Functions

© 2010 Pearson Education South Asia Pte Ltd Physical Chemistry 2 nd Edition Chapter 18: A Quantum Mechanical Model for the Vibration and Rotation of Molecules Outline 1.Solving the Schrödinger Equation for the Quantum Mechanical Harmonic Oscillator 2.Solving the Schrödinger Equation for Rotation in Two Dimensions 3.Solving the Schrödinger Equation for Rotation in Three Dimensions 4.The Quantization of Angular Momentum 5.The Spherical Harmonic Functions

© 2010 Pearson Education South Asia Pte Ltd Physical Chemistry 2 nd Edition Chapter 18: A Quantum Mechanical Model for the Vibration and Rotation of Molecules 18.1 Solving the Schrödinger Equation for the Quantum Mechanical Harmonic Oscillator Translational motion in various potentials is described in the context of wave-particle duality. In applying quantum mechanics to molecules, there are 2 motions for molecules to undergo: vibration and rotation. For vibration, the harmonic potential is where k = force constant

© 2010 Pearson Education South Asia Pte Ltd Physical Chemistry 2 nd Edition Chapter 18: A Quantum Mechanical Model for the Vibration and Rotation of Molecules 18.1 Solving the Schrödinger Equation for the Quantum Mechanical Harmonic Oscillator The normalized wave functions are 18.1 The Classical Harmonic Oscillator

© 2010 Pearson Education South Asia Pte Ltd Physical Chemistry 2 nd Edition Chapter 18: A Quantum Mechanical Model for the Vibration and Rotation of Molecules Example 18.1 Show that the function satisfies the Schrödinger equation for the quantum harmonic oscillator. What conditions does this place on ? What is E?

© 2010 Pearson Education South Asia Pte Ltd Physical Chemistry 2 nd Edition Chapter 18: A Quantum Mechanical Model for the Vibration and Rotation of Molecules Solution We have

© 2010 Pearson Education South Asia Pte Ltd Physical Chemistry 2 nd Edition Chapter 18: A Quantum Mechanical Model for the Vibration and Rotation of Molecules Solution The function is an eigenfunction of the total energy operator only if the last two terms cancel: Finally,

© 2010 Pearson Education South Asia Pte Ltd Physical Chemistry 2 nd Edition Chapter 18: A Quantum Mechanical Model for the Vibration and Rotation of Molecules 18.1 Solving the Schrödinger Equation for the Quantum Mechanical Harmonic Oscillator Hermite polynomials states that

© 2010 Pearson Education South Asia Pte Ltd Physical Chemistry 2 nd Edition Chapter 18: A Quantum Mechanical Model for the Vibration and Rotation of Molecules 18.1 Solving the Schrödinger Equation for the Quantum Mechanical Harmonic Oscillator The amplitude of the wave functions approaches zero for large x values only when The frequency of oscillation is given by 18.2 Energy Levels and Eigenfunctions for the Harmonic Oscillator

© 2010 Pearson Education South Asia Pte Ltd Physical Chemistry 2 nd Edition Chapter 18: A Quantum Mechanical Model for the Vibration and Rotation of Molecules Example 18.2 a. Is an eigenfunction of the kinetic energy operator? Is it an eigenfunction of the potential energy operator? b. What are the average values of the kinetic and potential energies for a quantum mechanical oscillator in this state?

© 2010 Pearson Education South Asia Pte Ltd Physical Chemistry 2 nd Edition Chapter 18: A Quantum Mechanical Model for the Vibration and Rotation of Molecules Solution a. Neither the potential energy operator nor the kinetic energy operator commutes with the total energy operator. Therefore, because is an eigenfunction of the total energy operator, it is not an eigenfunction of the potential or kinetic energy operators.

© 2010 Pearson Education South Asia Pte Ltd Physical Chemistry 2 nd Edition Chapter 18: A Quantum Mechanical Model for the Vibration and Rotation of Molecules Solution b. The fourth postulate states how the average value of an observable can be calculated. Because then

© 2010 Pearson Education South Asia Pte Ltd Physical Chemistry 2 nd Edition Chapter 18: A Quantum Mechanical Model for the Vibration and Rotation of Molecules Solution The limits can be changed as indicated in the last integral because the integrand is an even function of x. To obtain the solution, the following standard integral is used: The calculated values for the average potential and kinetic energy are

© 2010 Pearson Education South Asia Pte Ltd Physical Chemistry 2 nd Edition Chapter 18: A Quantum Mechanical Model for the Vibration and Rotation of Molecules Solution Thus

© 2010 Pearson Education South Asia Pte Ltd Physical Chemistry 2 nd Edition Chapter 18: A Quantum Mechanical Model for the Vibration and Rotation of Molecules Solution In general, we find that for the nth state,

© 2010 Pearson Education South Asia Pte Ltd Physical Chemistry 2 nd Edition Chapter 18: A Quantum Mechanical Model for the Vibration and Rotation of Molecules 18.1 Solving the Schrödinger Equation for the Quantum Mechanical Harmonic Oscillator 18.3 Probability of Finding the Oscillator in the Classically Forbidden Region

© 2010 Pearson Education South Asia Pte Ltd Physical Chemistry 2 nd Edition Chapter 18: A Quantum Mechanical Model for the Vibration and Rotation of Molecules 18.2 Solving the Schrödinger Equation for Rotation in Two Dimensions Consider rotation, the total energy operator can be written as a sum of individual operators for the molecule: Also the system wave function is a product of the eigenfunctions for the three degrees of freedom:

© 2010 Pearson Education South Asia Pte Ltd Physical Chemistry 2 nd Edition Chapter 18: A Quantum Mechanical Model for the Vibration and Rotation of Molecules Example 18.3 The bond length for H 19 F is × m. Where does the axis of rotation intersect the molecular axis?

© 2010 Pearson Education South Asia Pte Ltd Physical Chemistry 2 nd Edition Chapter 18: A Quantum Mechanical Model for the Vibration and Rotation of Molecules Solution If x H and x F are the distances from the axis of rotation to the H and F atoms, respectively, we can write and x H m H =x F m F. Substituting m F =19.00 amu and m H =1.008 amu, we find that x F =4.58×10-12 m and x H =87.10 × m. The axis of rotation is very close to the F atom. This is even more pronounced for HI or HCl.

© 2010 Pearson Education South Asia Pte Ltd Physical Chemistry 2 nd Edition Chapter 18: A Quantum Mechanical Model for the Vibration and Rotation of Molecules 18.2 Solving the Schrödinger Equation for Rotation in Two Dimensions The eigenfunction depends only on the angle Ф. The solutions above correspond to clockwise and counterclockwise rotation.

© 2010 Pearson Education South Asia Pte Ltd Physical Chemistry 2 nd Edition Chapter 18: A Quantum Mechanical Model for the Vibration and Rotation of Molecules Example 18.4 Determine the normalization constant in

© 2010 Pearson Education South Asia Pte Ltd Physical Chemistry 2 nd Edition Chapter 18: A Quantum Mechanical Model for the Vibration and Rotation of Molecules Solution The variable can take on values between 0 and 2π. The following result is obtained: Convince yourself that has the same value.

© 2010 Pearson Education South Asia Pte Ltd Physical Chemistry 2 nd Edition Chapter 18: A Quantum Mechanical Model for the Vibration and Rotation of Molecules 18.2 Solving the Schrödinger Equation for Rotation in Two Dimensions The energy-level spectrum is discrete and is given by where m l = quantum number We say that the energy levels with are twofold degenerate.

© 2010 Pearson Education South Asia Pte Ltd Physical Chemistry 2 nd Edition Chapter 18: A Quantum Mechanical Model for the Vibration and Rotation of Molecules 18.2 Solving the Schrödinger Equation for Rotation in Two Dimensions For rotation in the x-y plane, the angular momentum vector lies on the z axis. The angular momentum operator in these coordinates takes the simple form Applying this operator to an eigenfunction,

© 2010 Pearson Education South Asia Pte Ltd Physical Chemistry 2 nd Edition Chapter 18: A Quantum Mechanical Model for the Vibration and Rotation of Molecules 18.3 Solving the Schrödinger Equation for Rotation in Three Dimensions For molecule rotating in two dimensions: To make sure Y(θ,Ф) are single-valued functions and amplitude remains finite, the following conditions must be met.

© 2010 Pearson Education South Asia Pte Ltd Physical Chemistry 2 nd Edition Chapter 18: A Quantum Mechanical Model for the Vibration and Rotation of Molecules 18.3 Solving the Schrödinger Equation for Rotation in Three Dimensions Both l and m l must be integers and the spherical harmonic functions are written in the form The quantum number l is associated with the total energy observable,

© 2010 Pearson Education South Asia Pte Ltd Physical Chemistry 2 nd Edition Chapter 18: A Quantum Mechanical Model for the Vibration and Rotation of Molecules 18.4 The Quantization of Angular Momentum The spherical harmonic functions, are eigenfunctions of the total energy operator for a molecule that rotates freely in three dimensions. The eigenvalue equation for the operator can be written as

© 2010 Pearson Education South Asia Pte Ltd Physical Chemistry 2 nd Edition Chapter 18: A Quantum Mechanical Model for the Vibration and Rotation of Molecules 18.4 The Quantization of Angular Momentum The operators have the following form in Cartesian coordinates:

© 2010 Pearson Education South Asia Pte Ltd Physical Chemistry 2 nd Edition Chapter 18: A Quantum Mechanical Model for the Vibration and Rotation of Molecules 18.4 The Quantization of Angular Momentum The operators have the following form in spherical coordinates:

© 2010 Pearson Education South Asia Pte Ltd Physical Chemistry 2 nd Edition Chapter 18: A Quantum Mechanical Model for the Vibration and Rotation of Molecules 18.4 The Quantization of Angular Momentum For the operators in Cartesian coordinates, the commutators relating the operators are given by Thus the spherical harmonics is as

© 2010 Pearson Education South Asia Pte Ltd Physical Chemistry 2 nd Edition Chapter 18: A Quantum Mechanical Model for the Vibration and Rotation of Molecules 18.5 The Spherical Harmonic Functions For spherical harmonic functions, these are the first few values of l and m l :

© 2010 Pearson Education South Asia Pte Ltd Physical Chemistry 2 nd Edition Chapter 18: A Quantum Mechanical Model for the Vibration and Rotation of Molecules 18.5 The Spherical Harmonic Functions The functions which form an orthonormal set are given in the following equations:

© 2010 Pearson Education South Asia Pte Ltd Physical Chemistry 2 nd Edition Chapter 18: A Quantum Mechanical Model for the Vibration and Rotation of Molecules 18.5 The Spherical Harmonic Functions 3D perspective plots of the p and d linear combinations of the spherical harmonics.