Molecular Shape Section 9.4

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Presentation transcript:

Molecular Shape Section 9.4 Chemistry

Objectives Discuss the VSEPR bonding theory Predict the shape of and the bond angles in a molecule Define hybridization

The Shape of Molecules The shape of molecules determines reaction ability The model we use is the VSEPR model Valence Shell Electron Pair Repulsion

VSEPR Model Minimizes the repulsion of shared and unshared pairs of electrons around the central atom 7 key shapes you will need to be able to draw and identify

Linear Molecular Shape Example: BeCl2 Total Pairs of Electrons: 2 Shared Pairs of Electrons: 2 Lone Pairs: 0 Bond Angle: 180° Hybrid Orbitals: sp

Trigonal Planar Example: AlCl3 Total Pairs of Electrons: 3 Shared Pairs of Electrons: 3 Lone Pairs of Electrons: 0 Bond Angle: 120° Hybrid Orbitals: sp²

Tetrahedral Example: CH4 Total Pairs of Electrons: 4 Shared Pairs of Electrons: 4 Lone Pairs of Electrons: 0 Bond Angle: 109.5° Hybrid Orbitals: sp³

Trigonal Pyramidal Example: PH3 Total Pairs of Electrons: 4 Shared Pairs of Electrons: 3 Lone Pairs of Electrons: 1 Bond Angle: 107.3° Hybrid Orbitals: sp³

Bent Example: H2O Total Pairs of Electrons: 4 Shared Pairs of Electrons: 2 Lone Pairs of Electrons: 2 Bond Angle: 104.5° Hybrid Orbitals: sp³

Trigonal Bipyramidal Example: NbBr5 Total Pairs of Electrons: 5 Shared Pairs of Electrons: 5 Lone Pairs of Electrons:0 Bond Angle: 90°, 120° Hybrid Orbitals: sp³d

Octahedral Example: SF6 Total Pairs of Electrons: 6 Shared Pairs of Electrons: 6 Lone Pairs of Electrons: 0 Bond Angle: 90° Hybrid Orbitals: sp³d²

Hybridization Hybridization: A process in which atomic orbitals are mixed to form new, identical hybrid orbitals Carbon is the most common The number of hybrid orbitals = the number of total pairs of electrons

Homework 54-59 on page 262